scholarly journals Fatty acid composition as a parameter of using vegetable oils for biofuel production

2017 ◽  
Vol 169 (2) ◽  
pp. 38-42
Author(s):  
Marta AMBROSEWICZ-WALACIK ◽  
Małgorzata TAŃSKA ◽  
Marek WALACIK

The aim of the study was to show the validity of determining the quality of oils intendent for the biofuels production. One of the main discriminant that should be used to assess the suitability of oil raw materials for the fuel purposes is the composition of fatty acids. The research was conducted on 13 different samples of vegetable oils, that were cold-pressed from the seeds of various species, including rape, camelina, flax (light and dark), mustard, milk thistle, hemp, evening primrose oil, amaranth, sunflower, soybean, and cumin. The analysis of the fatty acid composition showed significant differences between the analysed oil samples, both within the species and varieties of oilseeds. The results indicate the need for continuous quality control of oils and fats led to the production of biodiesel in the small households and large commercial enterprises, because as it was indicated by the analysis of fatty acids composition rape seeds of different varieties are characterized by the diverse quality.

2021 ◽  
Vol 30 (11) ◽  
pp. 34-39
Author(s):  
G.V. Posnova ◽  
◽  
N.G. Ivanova ◽  
I.A. Nikitin ◽  
G.A. Shinov ◽  
...  

The article presents the results of research on the development of the technology of biscuits using non-traditional plant raw materials. In the course of the work, the replacement of a part of the premium wheat flour in the dairy crust recipe with a mixture of rice (17%) and sesame (11%) and the replacement of butter with camelina butter in an amount of 5% by weight of the product was justified. It was found that the introduction of functional raw materials gives the products a moderately sweet milk taste with a pleasant nutty aftertaste and orange color. The resulting products are characterized by a balanced fatty acid composition of ω-3 and ω-6, enriched with minerals and vitamins. Calculation of the nutritional value showed that the consumption of 100 g of the developed biscuits covers the daily need of an adult for polyunsaturated fatty acids of the ω-3 and ω-6 families by 37–75% and 19,4–31,5, respectively. The protein content rises by 1,5 times, and the carbohydrate content decreases by 1,16 times. At the same time, the degree of satisfaction of the daily requirement for potassium increases – by 2,3%, in calcium – by 7–7,5%, in phosphorus – by 12,6%, in magnesium – by 16,3%, in iron – by 7,3–13,3%. The degree of satisfaction of the daily requirement for vitamins B1 also increases – by 19,7–20,9%, B2 – by 2,2–2,3%, PP – by 8,1–9,3%, E – by 1,6–1,7% compared to the control sample of dairy cakes. The developed products can be recommended for preventive nutrition, people adhering to a healthy lifestyle, as well as school-age children, pregnant and lactating women who have a deficiency of ω-3 and ω-6 fatty acids in the diet


2021 ◽  
Vol 34 (1) ◽  
pp. 34-41
Author(s):  
Viktoriia O. Pinkevych ◽  
Moeen F. Dababneh ◽  
Nadiia Ye. Burda ◽  
Iryna O. Zhuravel

Abstract Introduction. With due consideration of the properties of fatty acids, as well as their importance for normal life activity and human development, research into the fatty acid composition of poorly studied plants and the search for new domestic plant sources of polyunsaturated fatty acids is a mainstream trend in modern pharmacy. Aim. Aim of research – determination of fatty acid qualitative composition and content in threshed grass, stalks, roots and seeds of Night-scented stock ‘Queen of Night’ and ‘Evening Scent’ cultivars as grown in Ukraine. Methods. Gas chromatography. Results. Both cultivars of Night-scented stock taken for analysis had similar fatty acid composition – 5 saturated, 5 (4 for seeds) monounsaturated and 2 polyunsaturated fatty acids, Quantitatively, in all tested parts of the herb polyunsaturated and monounsaturated fatty acid dominated, making in total 88.92% and 88.62% in the seeds of Queen of Night and Evening Scent cultivars, respectively, and averaging 65% in other parts of the tested cultivars. Linolenic and linoleic acids prevailed among the polyunsaturated fatty acids, whereas oleic acid prevailed among the monounsaturated. Conclusion. Night-scented stock can be utilized as a source of polyunsaturated fatty acids for the development of drugs and for standardization of tested raw materials.


2021 ◽  
Vol 72 (3) ◽  
pp. e415 ◽  
Author(s):  
M. De Wit ◽  
V.K. Motsamai ◽  
A. Hugo

Cold-pressed seed oil from twelve commercially produced cactus pear cultivars was assessed for oil yield, fatty acid composition, physicochemical properties, quality and stability. Large differences in oil content, fatty acid composition and physicochemical properties (IV, PV, RI, tocopherols, ORAC, % FFA, OSI and induction time) were observed. Oil content ranged between 2.51% and 5.96% (Meyers and American Giant). The important fatty acids detected were C16:0, C18:0, C18:1c9 and C18:2c9,12, with C18:2c9,12, the dominating fatty acid, ranging from 58.56-65.73%, followed by C18:1c9, ranging between 13.18-16.07%, C16:0, which ranged between 10.97 - 15.07% and C18:0, which ranged between 2.62-3.18%. Other fatty acids such as C14:0, C16:1c9, C17:0, C17:1c10, C20:0, C18:3c9,12,15 and C20:3c8,11,14 were detected in small amounts. The quality parameters of the oils were strongly influenced by oil content, fatty acid composition and physicochemical properties. Oil content, PV, % FFA, RI, IV, tocopherols, ORAC and ρ-anisidine value were negatively correlated with OSI. C18:0; C18:1c9; C18:2c9,12; MUFA; PUFA; n-6 and PUFA/SFA were also negatively correlated with OSI. Among all the cultivars, American Giant was identified as the paramount cultivar with good quality traits (oil content and oxidative stability).


2021 ◽  
pp. 56-59
Author(s):  
Лев Арсенович Оганесянц ◽  
Александр Львович Панасюк ◽  
Елена Ивановна Кузьмина ◽  
Дмитрий Александрович Свиридов ◽  
Михаил Юрьевич Ганин

Продукты масложировой промышленности играют важную роль в формировании рациона питания человека. При этом особое внимание отводится растительным маслам ввиду их высокой физиологической ценности. На сегодняшний день достаточно остро стоит вопрос о способах их идентификации. В связи с тем, что стоимость растительного масла в значительной степени обуславливается выбором сырья, наиболее распространенным видом фальсификации является внесение недобросовестными производителями в готовую продукцию более дешевых видов масел. Приведен анализ современных способов идентификации растительных масел из различного сырья. До настоящего времени метод газожидкостной хроматографии являлся основным при выявлении примесей посторонних жиров в продукции по ее жирнокислотному составу. Также для выявления фальсификатов могут быть использованы такие инструментальные методы, как ЯМР-спектроскопия, ИК-спектроскопия, а также метод изотопной масс-спектрометрии, который является наиболее перспективным. Особый научный интерес представляет идентификация растительных масел по их географическому месту происхождения. Основываясь на анализе литературы, показано, что наибольшее распространение при установлении региональной принадлежности масел получили исследования, направленные на изучение изотопных характеристик углерода (13С/12С), кислорода (18O/16O) и водорода (2H/1H) элементов, входящих в состав продукта, а также его жирнокислотного состава. Описаны преимущества комплексного подхода исследований, включающего в себя создание массива данных, состоящего из значений различных показателей, и его глубокий анализ с использованием статистических методов анализа. Математическая модель может быть усилена данными элементного профиля масла, изотопных характеристик отдельно взятых жирных кислот или содержанием фенольных соединений. Products of the fat and oil industry play an important role in shaping human diet. At the same time, special attention is paid to vegetable oils in view of their high physiological value. Today, the question of how to identify them is quite acute. Due to the fact that the cost of vegetable oil is largely determined by the choice of raw materials, the most common falsification type is the introduction of cheaper oils types into finished products by unscrupulous manufacturers. The authors provide an analysis of modern methods for identifying vegetable oils from various raw materials. It has been shown that the gas-liquid chromatography method is the main one in identifying products by their fatty acid composition and makes it possible to establish the presence of foreign fats impurities. Also, methods of isotope mass spectrometry, NMR spectroscopy, IR spectroscopy and electrophysical methods of analysis can be used to detect counterfeits. Of particular scientific interest is the vegetable oils identification by their geographical place of origin, which is very important for some countries of the European Union. Based on the analysis of literature, it has been shown that the most widespread in the regional oils affiliation establishing are researches aimed at researching the isotopic characteristics of carbon (13C/12C), oxygen (18O/16O) and hydrogen (2H/1H) of the elements that make up the product, and also its fatty acid composition. The advantages of an integrated research approach are described, including the creation of a data array consisting of the values of various indicators and its in-depth analysis using statistical analysis methods. The mathematical model can be strengthened by data on the elemental profile of the oil, isotopic characteristics of individual fatty acids, or the content of phenolic compounds.


2016 ◽  
Vol 4 ◽  
pp. 57-66
Author(s):  
Tatiana Belemets ◽  
Natalia Yushchenko ◽  
Alexei Lobok ◽  
Irina Radzievskaya ◽  
Tatiana Polonskaya

The method of solution of the problem of polyunsaturated fatty acids (PUFA) lack in milk products is offered in the work. It is offered to create the milk-containing products (sour cream product) with adjusted fatty acid composition. The possibility of replacement of the mass part of milk fat (50 %) by the blend of natural vegetable oils was studied. For the solution of this problem the program within MatLab mathematical package was elaborated. The recommended fatty acids (FA) ratio [3] is selected as optimization parameter. The optimized blend was created using the elaborated program. The data, received by mathematical calculations, were experimentally proved using the method of gas-liquid chromatography [7]. On the based of the results, received at the studies, it can be stated, that 50 % replacement of mass part of fat (m.p.f.) in milk products (sour cream product) by elaborated blend, allows partially adjust its FA composition.


Author(s):  
Munevera Begić ◽  
Enisa Nezirević-Nizić ◽  
Selma Čorbo ◽  
Sedina Podrug ◽  
Zilha Ašimović ◽  
...  

Vestnik MGTU ◽  
2020 ◽  
Vol 23 (3) ◽  
pp. 260-267
Author(s):  
A. A. Efremova ◽  
V. S. Lyulkovich ◽  
N. L. Naumova

The triglyceride composition of the fat base of margarine used in the technology of flour confectionery products (FCP) includes up to 70 % monounsaturated acids, up to 25 % saturated ones. It has been established that for a more complete assimilation of FCP, a fat-intensive product should contain these fatty acids in equal proportions and should not contain trans-isomers of fatty acids, the main source of which are partially hydrogenated vegetable oils. Trans fats contained in margarines can cause the development of many diseases. It is known that the fat of sunflower flour is represented by unsaturated acids: linoleic (≈70 %) and oleic (≈18 %), which are of great physiological importance. The aim of the research was to optimize the fatty acid composition of cottage cheese bagel through the use of flour from sunflower seeds. The nutritional value of raw materials has been investigated. Tests of several variants of modification of cottage cheese bagel recipe in the process of baking laboratory samples have shown the advantage of sunflower flour in comparison with wheat flour in terms of the amount of fat, proteins, dietary fiber. The possibility of replacing 15 % of wheat flour with flour from sunflower seeds with a decrease in margarine by 19.8 % in bagel technology has been established. The product of the modified prescription composition contain more polyunsaturated fatty acids (by 28.4 %), of which linoleic - by 29.9 %, γ-linolenic - by 50 %, docosahexaenoic - by 20 %, eicosatrienic - by 35 %; less saturated fatty acids (by 6.2 %), of which caprylic - by 14.0 %, lauric - by 13.9 %, capric - by 10.7 %, myristic - by 9.6 %, butyric - by 9.1 %, palmitic - by 6.7 %; fewer transisomers of fatty acids (by 8.7 %), of which transisomers of oleic acid - by 9.6 %, linolenic - by 33.3 %. The proposed development has good consumer properties, and is characterized by a high content of protein (by 11.6 %) and dietary fiber (by 7.2 %).


2019 ◽  
Vol 13 (3) ◽  
Author(s):  
S. Lehnert ◽  
О. Khomenko ◽  
A. Dubinina ◽  
V. Vinnikova ◽  
L. Tatar

The article characterizes the peanut (Arachis hypogaea) as an oilseed crop widely spread in the world. It describes its biological value as well as the chemical and fatty acid composition. The study proves the practical importance of developing and introducing new blended functional purpose oils for Ukrainian people. It has been shown that blended oils contain significant amounts of monounsaturated and polyunsaturated fatty acids. The use of blended oils will correct the deficiency of essential fatty acids in the diet of our country’s population. It has been pointed out how promising it is to create new types of blended oils, with a balanced fatty acid composition, by combining peanut and linseed oils. The article describes the characteristics of the new blended peanut-linseed oils with additives made from vegetable raw materials. The evaluated parameters are the quality and safety of the new blended peanut-linseed oils with a garlic extract, rosehip extract, sorrel leaf extract, and black currant leaf extract. The fatty acid composition of the fat in the new blended oils has been studied to determine their quality. The safety assessment of the new oils with the additives from vegetable raw materials has been determined by the content of pesticides (HCH-gamma isomer, heptachlor, and DDT), mycotoxins (aflotoxin B1 and zearalenone), toxic elements (lead, cadmium, arsenic, mercury, and zinc), iron, and radionuclides (cesium-137 and strontium-90). The results obtained confirm that the new blended oils are safe. The blended oils have a high biological value when the ratio of w-6 to w-3 fatty acids is 4.9:1, and the ratio of monounsaturated fatty acids to polyunsaturated fatty acids is 1:1, which meets the standards of healthy nutrition. In terms of chemical and radiation safety, the new oils do not exceed the maximum permissible concentrations, confirming the safety of the newly developed oils.


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