scholarly journals Ultrasonic-Assisted Removal of Eriochrome Black T onto Vermicompost: Characterization, Isotherm and Kinetic Modelling

2021 ◽  
pp. 1251-1262
Author(s):  
Zeynep CİGEROGLU ◽  
Eyüp YILDIRIR
Keyword(s):  
Kinetic Modelling ◽  
Eriochrome Black T ◽  
Ultrasonic Assisted

Kinetic modelling of degradation of phenolic compounds in leachate

2011 ◽  
Author(s):  
E. Sekman ◽  
G. Varank ◽  
A. Demir ◽  
S. Top ◽  
M. S. Bilgili
Keyword(s):  
Phenolic Compounds ◽  
Kinetic Modelling

Kinetic Modelling and Equilibrium of Amphoteric Collector Adsorption on Silica and Hematite

2009 ◽  
Vol 46 (2) ◽  
pp. 85-91
Author(s):  
K. A. Selim ◽  
F. H. Abd El-Rahiem ◽  
A. A. El-Midany
Keyword(s):  
Kinetic Modelling

Ultrasonic-Assisted Surface- Modification of Nanosilica Chloride and its Use for Synthesis of 3,4- Dihydropyrimidinones

2014 ◽  
Vol 11 (5) ◽  
pp. 361-367 ◽  
Author(s):  
Mahgol Tajbakhsh ◽  
Yousef Ranjbar ◽  
Abdolhosein Masuodi ◽  
Parizad Rezaee ◽  
Mahmood Tajbakhsh ◽  
...  
Keyword(s):  
Surface Modification ◽  
Ultrasonic Assisted

Kinetic Modelling of Anionic Polymerization Involving a Dynamic Equilibrium between Two Growth Centres with Different Growth Rates

1993 ◽  
Vol 58 (10) ◽  
pp. 2349-2361 ◽  
Author(s):  
Jaromír Jakeš
Keyword(s):  
Molecular Weight ◽  
Growth Rates ◽  
Anionic Polymerization ◽  
Dynamic Equilibrium ◽  
Kinetic Modelling ◽  
Polymerization Time ◽  
Fast State ◽  
Growth State ◽  
In The Beginning ◽  
Growth Centres

Kinetic modelling of the molecular weight distribution (MWD) of polymer obtained by an anionic polymerization with two types of growth centres in a dynamic equilibrium, having different growth rates and lifetimes comparable to the polymerization time, was made for low monomer conversions. On the basis of distribution of the growth centres according to the total time spent in the fast growth state, it was shown that MWD of the resulting polymer are mostly bimodal at the beginning of the polymerization and change to unimodal MWD at sufficiently high polymerization degrees depending on the equilibrization rate. When all centres are in the fast state in the beginning, MWD are essentially unimodal throughout. A hint of trimodality is observed in some cases, in an extent hardly detectable in real chromatograms. Hence, a polymodal MWD can be explained only when more than two growth centres with different growth rates are assumed.

Pulse polarographic study of the behaviour of some o,o'-dihydroxyazo-compounds

1989 ◽  
Vol 54 (5) ◽  
pp. 1219-1226 ◽  
Author(s):  
Enric Casassas ◽  
Miquel Esteban ◽  
Santiago Alier
Keyword(s):  
Carboxylic Acid ◽  
Reaction Mechanisms ◽  
Sulphonic Acid ◽  
Base Catalysis ◽  
Polarographic Study ◽  
Acid Base ◽  
Eriochrome Black T ◽  
Naphthoic Acid ◽  
Calcon Carboxylic Acid

The reduction of several o,o'-dihydroxyazo-compounds is studied by means of pulse polarographic techniques (DPP, NPP and RPP). The compounds studied are the following: 2-(2'-hydroxyphenylazo)-phenol (o,o'-dihydroxyazobenzene), 1-(2'-hydroxy-1'-naphthylazo)-2-naphthol-4-sulphonic acid (calcon or Eriochrome Blue Black R), 1-(2'-hydroxy-4'-sulpho-1'-naphthylazo)-2-hydroxy-3-naphthoic acid (calcon carboxylic acid), and 1-(1'-hydroxy-2'-naphthylazo)-6-nitro-2-naphthol-4-sulphonic acid (Eriochrome Black T). Correlations between Ip and Epand experimental variables (pH, T, conc.) and instrumental parameters (dropping time, t, and pulse magnitude, ΔE) are established. Reaction mechanisms formerly proposed are discussed on the basis of the new obtained results, and the ranges are defined where adsorption and/or acid-base catalysis are operative.

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