scholarly journals Intercalation of Anthraquinone-2-Sulphonate into Magnesium- Aluminum Layered Double Hydroxide and its Calcined Products by Ion Exchange and Memory Effect Properties

2017 ◽  
Vol 4 (3) ◽  
pp. 175
Author(s):  
M.Z.b. Hussein ◽  
A.H. Yahaya ◽  
M. Ibrahim ◽  
M. Tahir ◽  
H. Sulimat
Keyword(s):  
Aqueous Solution ◽  
Ion Exchange ◽  
Layered Double Hydroxide ◽  
Memory Effect ◽  
Layered Structure ◽  
Exchange Process ◽  
Atmospheric Condition ◽  
Basal Spacing ◽  
Pxrd Pattern ◽  
Double Hydroxide

<p>Layered double hydroxide of Mg-Al-nitrate system (LDH) was prepared and its heat<strong>-</strong>treated products (LDHTs) were obtained by calcining the LDH at 250–750 °C, for 5 hours at atmospheric condition. The LDH and the LDHTs were used as an inorganic host for the intercalation of AQ2 via ion exchange or memory effect property by exposing the LDH and LDHTs in aqueous solution containing an anion, anthraquinone-2-sulfonate (AQ2) for the formation of an organic-inorganic layered nanohybrid materials. X-ray diffractograms showed that the layered structure of LDH collapsed when it was heated at around 350 °C, and an oxide phase, MgAl<sub>2</sub>O<sub>4</sub> appeared. Due to the memory effect property, the regeneration of LDH from LDHT was observed and at the same time the AQ2 was intercalated when LDHT was treated with the aqueous solution containing AQ2. As a result, formation of an organic-inorganic layered nanohybrid material was also observed. Similarly, the same material can be formed by ion exchange of LDH with AQ2. The basal spacing of LDH was found expanded from 8.1 Å to around 20 Å in the resulting nanohybrid. This is to accommodate a bigger size of the AQ2 moiety with specific orientation inside the interlamella of the inorganic layered structure that warrants the layer expansion. Incomplete intercalation and ion exchange process resulted in a mixed LDH and a nanohybrid phase as observed in the PXRD pattern of the resulting material.</p>

scholarly journals RELEASE BEHAVIOR OF DICHLORPROP FROM ZN/AL-LDH-DICHLORPROP NANOCOMPOSITE INTO CHLORIDE, CARBONATE AND PHOSPHATE SOLUTIONS

2019 ◽  
Vol 81 (2) ◽  
Author(s):  
Norhayati Hashim ◽  
Sharifah Norain Mohd Sharif ◽  
Zuhailimuna Muda ◽  
Illyas Md Isa ◽  
Suriani Abu Bakar ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Sodium Chloride ◽  
Layered Double Hydroxide ◽  
Sodium Carbonate ◽  
Sodium Phosphate ◽  
Basal Spacing ◽  
Pxrd Pattern ◽  
Release Study ◽  
Double Hydroxide ◽  
Phosphate Solutions

A release study of dichlorprop phenoxyherbicides from the interlayer of a Zn/Al-layered double hydroxide-dichlorprop nanocomposite was performed with various concentrations of sodium chloride, sodium carbonate and sodium phosphate and a mixture of sodium chloride, sodium carbonate and sodium phosphate in aqueous solution. The release study of dichlorprop showed that release is dependent on the concentration of the aqueous solution. The accumulated release percentage of dichlorprop phenoxyherbicides into the solution was found to be higher in solutions containing carbonate, phosphate, and a mixture of carbonate or phosphate anions. Confirmation of the release process was confirmed by the PXRD pattern of the powder recovered from highly concentrated solutions of sodium chloride, sodium carbonate, and sodium phosphate with basal spacing of 7.8 Å, 7.6 Å and 7.4 Å, is due to chloride, carbonate, and phosphate intercalation, respectively. The kinetic study revealed that dichlorprop release into sodium carbonate and sodium phosphate solutions is governed by pseudo-second order kinetics, while release into sodium chloride solution is governed by parabolic diffusion. This study shows that a layered double hydroxide might be used as a host for the controlled release of the phenoxyherbicide dichlorprop.

scholarly journals Ion Exchange of Benzoate in Ni-Al-Benzoate Layered Double Hydroxide by Amoxicillin

2019 ◽  
Vol 17 (1) ◽  
pp. 1043-1049
Author(s):  
Dian Windy Dwiasi ◽  
Mudasir Mudasir ◽  
Roto Roto
Keyword(s):  
Ion Exchange ◽  
Anion Exchange ◽  
Layered Double Hydroxide ◽  
Exchange Process ◽  
X Ray ◽  
Batch Technique ◽  
Pseudo Second Order ◽  
Ft Ir ◽  
Double Hydroxide ◽  
Benzoate Anion

AbstractThe Ni-Al-NO3 layered double hydroxide (LDH) compound has been intercalated with benzoate anion through an anion exchange process for amoxicillin drug adsorption. The purpose of this research is to synthesize Ni-Al-NO3, ion exchange with benzoate anion to form Ni-Al-Benzoate, and then applying it as an adsorbent of amoxicillin. The adsorption process was carried out using the batch technique. The materials synthesized in this study were characterized by Fourier Transform Infrared Spectroscopy (FT-IR), X-ray ray diffraction (XRD), and Thermogravimetric Analysis/Differential Thermal Analysis (TGA/DTA). The exchange of benzoate in Ni-Al-Benzoate LDH by amoxicillin was followed by UV-Vis spectrophotometry. The pH, LDH amount, and contact time are optimized. The adsorption of amoxicillin by Ni-Al-Benzoate is fit to the pseudo-second-order kinetics model, with an adsorption capacity of 40 mg/ g. The results showed that anion exchange was successfully carried out between benzoate anion and amoxicillin.

scholarly journals Structural, Thermal and Surface Properties of a Formulated Sunscreen: Zn/Al-nitrate Layered Double Hydroxide Intercalated with 4-aminobenzoic Acid

2021 ◽  
Vol 18 (13) ◽  
Author(s):  
Fadhlin Sakina MOHD RAJIDI ◽  
Iman Nur Fathihah Abdul AZIZ ◽  
Mazlina MUSA ◽  
Rozita YAHAYA
Keyword(s):  
Benzoic Acid ◽  
Layered Double Hydroxide ◽  
Harmful Effect ◽  
Precipitation Method ◽  
Basal Spacing ◽  
Pxrd Pattern ◽  
Type Iv ◽  
Co Precipitation ◽  
Double Hydroxide ◽  
Amino Benzoic Acid

Intercalation of 4-amino benzoic acid (4-AB) into Zn/Al-nitrate layered double hydroxide (ZAL2) to form Zn/Al-4AB (ZALAB) compound was successfully synthesized from nitrate salt by using direct co-precipitation method. ZALAB compound was confirmed by Powder X-ray diffraction (PXRD) pattern with a basal spacing of 15.3 Å. The presence of COO- and C6H5NH2 functional groups of 4-AB at 1,517 and 1,178 cm–1 in Fourier transform infrared (FTIR) spectrum reinforced 4-AB intercalated into the resulting compound. Based on the thermal analysis, 4-AB in ZALAB compound was more stable compared to pure 4-AB. Breuneur, Emmet and Teller/Barret-Joyner-Halenda (BET/BJH) analyses demonstrated that ZALAB compound is a mesopores-type IV compound with 4.25 m2/g surface area. This material is an irregular shape with different sizes of particles. ZALAB is a potential sunscreen formulation that minimizes the harmful effect on the skin, improving pharmaceutical technology in the skincare treatment. HIGHLIGHTS 4-amino benzoic acid (4-AB) is a sunscreen composed of carboxylic and aromatic groups that potentially filter UV-B radiation Layered double hydroxide (LDH) is known as an ionic clay that is based on the brucite (Mg (OH)2) -like cations layers containing intercalated charge-balancing anions and water Intercalation of 4-amino benzoic acid (4-AB) into Zn/Al-nitrate layered double hydroxide (ZAL2) to form Zn/Al-4AB (ZALAB) was synthesized using direct co-precipitation method ZALAB material has a higher thermal stability compared to 4-AB in pure form GRAPHICAL ABSTRACT

Formation of Zinc-Aluminium Layered Double Hydroxide-2,4,5-Tricholorophenoxybutyrate Nanocomposites by Ion Exchange Method

2013 ◽  
Vol 832 ◽  
pp. 374-378
Author(s):  
Sheikh Ahmad Izaddin Sheikh Mohd Ghazali ◽  
Mohd Zobir Hussein ◽  
Ri Hanum Yahaya Subhan ◽  
Siti Halimah Sarijo
Keyword(s):  
Ion Exchange ◽  
Surface Area ◽  
Layered Double Hydroxide ◽  
Nitrogen Adsorption ◽  
Basal Spacing ◽  
Exchange Method ◽  
Type Iv ◽  
Ion Exchange Method ◽  
Double Hydroxide ◽  
Adsorption Desorption

The intercalation of herbicide, 2,4,5-tricholorophenoxybutyrate (TBA) , into zinc-aluminium-layered double hydroxide (ZAL) for the formation of a new nanocomposite ZAT, was accomplished via anion exchange method. Due to the intercalation of TBA with ZAL interlayer domain, basal spacing expanded from 8.9Å in the ZAL to 23.3 Å in the ZAT. The percentage loading of TBA in the ZAT is 45.5 % (w/w). The FTIR spectra of the nanocomposite shows resemblance peaks of the TBA and Zn-Al-layered double hydroxide indicating the inclusion of TBA into the layered double hydroxide. Surface area of the resulting nanocomposite increased from 1.3 to 15.6 m2g-1with the nitrogen adsorption-desorption of type IV, indicating the mesopore type of material.

Removal of Toxic Dyestuffs from Aqueous Solution by Amphoteric Bioadsorbent

2020 ◽  
Vol 16 ◽  
Author(s):  
Reda M. El-Shishtawy ◽  
Abdullah M. Asiri ◽  
Nahed S. E. Ahmed
Keyword(s):  
Aqueous Solution ◽  
Ion Exchange ◽  
Dye Removal ◽  
Exchange Process ◽  
Cationic Dyes ◽  
Carboxyl Groups ◽  
Maximum Adsorption Capacity ◽  
Equilibrium Isotherm ◽  
Ion Exchange Process ◽  
Dyes And Pigments

Background: Color effluents generated from the production industry of dyes and pigments and their use in different applications such as textile, paper, leather tanning, and food industries, are high in color and contaminants that damage the aquatic life. It is estimated that about 105 of various commercial dyes and pigments amounted to 7×105 tons are produced annually worldwide. Ultimately, about 10–15% is wasted into the effluents of the textile industry. Chitin is abundant in nature, and it is a linear biopolymer containing acetamido and hydroxyl groups amenable to render it atmospheric by introducing amino and carboxyl groups, hence able to remove different classes of toxic organic dyes from colored effluents. Methods: Chitin was chemically modified to render it amphoteric via the introduction of carboxyl and amino groups. The amphoteric chitin has been fully characterized by FTIR, TGA-DTG, elemental analysis, SEM, and point of zero charge. Adsorption optimization for both anionic and cationic dyes was made by batch adsorption method, and the conditions obtained were used for studying the kinetics and thermodynamics of adsorption. Results: The results of dye removal proved that the adsorbent was proven effective in removing both anionic and cationic dyes (Acid Red 1 and methylene blue (MB)), at their respective optimum pHs (2 for acid and 8 for cationic dye). The equilibrium isotherm at room temperature fitted the Freundlich model for MB, and the maximum adsorption capacity was 98.2 mg/g using 50 mg/l of MB, whereas the equilibrium isotherm fitted the Freundlich and Langmuir model for AR1 and the maximum adsorption capacity was 128.2 mg/g. Kinetic results indicate that the adsorption is a two-step diffusion process for both dyes as indicated by the values of the initial adsorption factor (Ri) and follows the pseudo-second-order kinetics. Also, thermodynamic calculations suggest that the adsorption of AR1 on the amphoteric chitin is an endothermic process from 294 to 303 K. The result indicated that the mechanism of adsorption is chemisorption via an ion-exchange process. Also, recycling of the adsorbent was easy, and its reuse for dye removal was effective. Conclusion: New amphoteric chitin has been successfully synthesized and characterized. This resin material, which contains amino and carboxyl groups, is novel as such chemical modification of chitin hasn’t been reported. The amphoteric chitin has proven effective in decolorizing aqueous solution from anionic and cationic dyes. The adsorption behavior of amphoteric chitin is believed to follow chemical adsorption with an ion-exchange process. The recycling process for few cycles indicated that the loaded adsorbent could be regenerated by simple treatment and retested for removing anionic and cationic dyes without any loss in the adsorbability. Therefore, the study introduces a new and easy approach for the development of amphoteric adsorbent for application in the removal of different dyes from aqueous solutions.

Investigation of layered double hydroxide/carbon dot nanocomposite on removal efficiency of Pb2+ from aqueous solution

2021 ◽  
pp. 116774
Author(s):  
Fataneh Vasheghani Farahani ◽  
Mohammad Hassan Amini ◽  
Seyed Hamid Ahmadi ◽  
Seyed Amirabbas Zakaria
Keyword(s):  
Aqueous Solution ◽  
Layered Double Hydroxide ◽  
Removal Efficiency ◽  
Carbon Dot ◽  
Double Hydroxide

Aqueous-phase synthesis of layered double hydroxide nanoplates as catalysts for the oxygen evolution reaction

2018 ◽  
Vol 47 (48) ◽  
pp. 17342-17348 ◽  
Author(s):  
Euiyoung Jung ◽  
Jae Kyeom Kim ◽  
Hyungsuk Choi ◽  
Min Hyung Lee ◽  
Taekyung Yu
Keyword(s):  
Aqueous Solution ◽  
Transition Metal ◽  
Oxygen Evolution ◽  
Layered Double Hydroxide ◽  
Aqueous Phase ◽  
Oxygen Evolution Reaction ◽  
Metal Salt ◽  
Catalytic Performance ◽  
Phase Synthesis ◽  
Double Hydroxide

Transition metal LDH nanoplates were synthesized by heating an aqueous solution containing a metal salt, PEG, and octylamine. The LDH nanoplates showed comparable electrochemical catalytic performance for the oxygen evolution reaction.

Removal efficiency of arsenate and phosphate from aqueous solution using layered double hydroxide materials: intercalation vs. precipitation

2010 ◽  
Vol 20 (22) ◽  
pp. 4684 ◽  
Author(s):  
Yunfeng Xu ◽  
Yingchun Dai ◽  
Jizhi Zhou ◽  
Zhi Ping Xu ◽  
Guangren Qian ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Layered Double Hydroxide ◽  
Removal Efficiency ◽  
Double Hydroxide
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