scholarly journals Determination of moisture diffusivity and activation energy in the convective drying of fish

2018 ◽  
Vol 36 (4) ◽  
pp. 1262-1267 ◽  
Author(s):  
Clement Adekunle Komolafe ◽  
Iyiola Olusola Oluwaleye ◽  
Akinfoye O. Daniel Adejumo ◽  
Mufutau Adekojo Waheed ◽  
Sidikat Ibiyemi Kuye
Keyword(s):  
Activation Energy ◽  
Moisture Diffusivity ◽  
Convective Drying

Modeling Thin Layer Drying Kinetics, Moisture Diffusivity and Activation Energy of Hazelnuts during Microwave-Convective Drying

2017 ◽  
Vol 14 (2) ◽  
Author(s):  
Narjes Malekjani ◽  
Zahra Emam-Djomeh ◽  
Seyed Hassan Hashemabadi ◽  
Gholam Reza Askari
Keyword(s):  
Activation Energy ◽  
Microwave Power ◽  
Moisture Diffusivity ◽  
Drying Kinetics ◽  
Convective Drying ◽  
Drying Method ◽  
Drying Process ◽  
Dominant Effect ◽  
Thin Layer Drying ◽  
Kinetics Of

AbstractThe effects of microwave-convective drying as an efficient drying method, on drying kinetics of hazelnuts were studied. Drying experiments were conducted at three temperature (40, 50 and 60°C) and microwave power (0, 450 and 900 W) levels. The moisture ratio and the temperature of the hazelnuts were recorded during the drying. The results showed that microwave power had a more dominant effect than drying air temperature. Mathematical modeling was performed in order to predict the moisture changes during drying process. It was concluded that two term and Midilli et al. models were the best models to predict the drying kinetics of hazelnut in different conditions. The effective moisture diffusivities varied from 3.80327×10‒8to 1.71233×10‒6m2/s and had an increasing polynomial relationship with temperature and microwave power. The activation energy was also between 15.61675 and 41.0053 kJ/mol with a second-order relationship with microwave power.

Determination of Moisture Diffusivity and Activation Energy in Thin Layer Drying of Olive Pomace

2012 ◽  
Vol 8 (3) ◽  
Author(s):  
Smail Meziane ◽  
Naima Mesbahi
Keyword(s):  
Activation Energy ◽  
Thin Layer ◽  
Moisture Diffusivity ◽  
Olive Pomace ◽  
Air Velocity ◽  
Drying Time ◽  
Effective Moisture ◽  
Air Temperatures ◽  
Thin Layer Drying

Abstract The thin layer drying of olive pomace was experimentally studied in a laboratory convective dryer. Drying experiments were performed under five air temperatures of 60, 70, 80 and 90ºC, two air velocities of 1.0 and 1.8 m s-1 and three thickness of thin layer of 6, 9 and 12 mm. The results show that the drying time decreased with increased in drying temperature and air velocity but increased with the decreasing of thin layer thickness of olive pomace. Over the experimental range studied, the values of effective moisture diffusivity and activation energy ranged from 1.25 • 10-9 to 6.30 • 10-9 m2 s-1 and 26.30 to 37.63 kJ mol-1, respectively. The dependence of these parameters on thickness of thin layer, and temperature and velocity of drying air has been investigated.

scholarly journals Determination of moisture diffusivity and activation energy on fixed bed drying of red pepper (Capsicum annum) on convective solar drying

2021 ◽  
Vol 4 (2) ◽  
pp. 110-116
Author(s):  
Siti Asmaniyah Mardiyani ◽  
Sumardi Hadi Sumarlan ◽  
Bambang Dwi Argo ◽  
Amin Setyo Leksono
Keyword(s):  
Activation Energy ◽  
Fixed Bed ◽  
Moisture Diffusivity ◽  
Effective Moisture Diffusivity ◽  
Red Pepper ◽  
Convective Drying ◽  
Energy Calculation ◽  
Solar Drying ◽  
Effective Moisture ◽  
Drying Behavior

Moisture diffusivity and activation energy are two important variables in a drying process to understand a certain product's drying behavior. This study aimed to determine the value of effective moisture diffusivity and the activation energy of red pepper in a conventional forced convective drying based on electricity (conventional convective drying/CCD) and forced convective drying based on solar energy (convective solar drying/CSD). The value of effective moisture diffusivity was determined using the equation, which refers to Fick’s second law. The Arrhenius equation determines the activation energy value as a model of the relationship of inverse temperature and the normal logarithmic value of effective moisture diffusivity. The results showed that the values of effective moisture diffusivity of CCD 70 °C were the highest. The regression analysis between the drying layers (X), and effective moisture diffusivity (Y) showed a polynomial pattern with a coefficient determination R2 value of 0.85 (CCD 70 °C), 0.81 (CCD 60 °C), 0.88 (CCD 50 °C), and 0.48 (CSD). (R2) The higher moisture diffusivity values in CCD indicated that the drying systems are more stable than CSD. The drying activation energy calculation showed that the value of CCD's activation energy was 36.36 kJ/mol.K, while the value of CSD's activation energy was 31.28 kJ/mol.K. Those results were consistent with the results of the previous studies.

Experimental Investigation to Evaluate the Effective Moisture Diffusivity and Activation Energy of Cassava (Manihot Esculenta) under Convective Drying

2021 ◽  
Author(s):  
Pathiwat Waramit ◽  
Bundit Krittakom ◽  
Ratinun Luampon
Keyword(s):  
Activation Energy ◽  
Type Equation ◽  
Moisture Diffusivity ◽  
Experimental Results ◽  
Effective Moisture Diffusivity ◽  
Convective Drying ◽  
Air Velocity ◽  
Drying Time ◽  
Hot Air ◽  
Effective Moisture

Investigation of effective moisture diffusivity (Deff) and activation energy (Ea) of cassava were conducted under convective drying at temperature and velocity of 60, 70 and 80 °C, and 1.0, 1.5 and 2.0 m/s, respectively. In the experiment, cassava was sliced into 3 mm-thickness and dried under given conditions until mass was saturated. Deff and Ea were described by Fick’s second law and Arrhenius-type equation, respectively. The experimental results indicated that the increase in Deff was significantly affected by increasing the hot air temperature and velocity. The slope method was used to calculate average Deff, and results were found to range from 3.83 × 10–9 – 9.86 × 10–9 m2/s. The Ea was found to decrease with an increase in hot air velocity, ranging from 21.23– 24.92 kJ/mol. Additionally, Moisture content (Mw) and Drying rate (DR) were also used to describe the drying kinetics. From the experimental results, Mw and DR decreased with an increase in drying time. DR increased with an increase in temperature and velocity causing Mw to rapidly decrease and drying time to reduce. The highest DR was found to be 0.55 gwater/min at temperature of 80 °C and velocity of 2.0 m/s.

Development of HPLC Method for the Purity Test by Design of Experiments and Determination of Activation Energy of Hydrolytic Degradation Reactions of Sofosbuvir

2020 ◽  
Vol 16 (7) ◽  
pp. 976-987
Author(s):  
Jakub Petřík ◽  
Jakub Heřt ◽  
Pavel Řezanka ◽  
Filip Vymyslický ◽  
Michal Douša
Keyword(s):  
Activation Energy ◽  
Design Of Experiments ◽  
Mobile Phase ◽  
Hydrolytic Degradation ◽  
Isoconversional Method ◽  
Hplc Method ◽  
Organic Modifier ◽  
Calculation Methods ◽  
Degradation Reactions

Background: The present study was focused on the development of HPLC method for purity testing of sofosbuvir by the Design of Experiments and determination of the activation energy of hydrolytic degradation reactions of sofosbuvir using HPLC based on the kinetics of sofosbuvir degradation. Methods: Following four factors for the Design of Experiments were selected, stationary phase, an organic modifier of the mobile phase, column temperature and pH of the mobile phase. These factors were examined in two or three level experimental design using Modde 11.0 (Umetrics) software. The chromatographic parameters like resolution, USP tailing and discrimination factor were calculated and analysed by partial least squares. The chromatography was performed based on Design of Experiments results with the mobile phase containing ammonium phosphate buffer pH 2.5 and methanol as an organic modifier. Separation was achieved using gradient elution on XBridge BEH C8 at 50 °C and a flow rate of 0.8 mL/min. UV detection was performed at 220 nm. The activation energy of hydrolytic degradation reactions of sofosbuvir was evaluated using two different calculation methods. The first method is based on the slope of dependence of natural logarithm of the rate constant on inverted thermodynamic temperature and the second approach is the isoconversional method. Results and Conclusion: Calculated activation energies were 77.9 ± 1.1 kJ/mol for the first method and 79.5 ± 3.2 kJ/mol for the isoconversional method. The results can be considered to be identical, therefore both calculation methods are suitable for the determination of the activation energy of degradation reactions.

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