Commercially Imported Bentonite Versus Locally Derived Bentonitic Clays: A Comparative Assessment Study of Mineralogy and Geochemical properties, Anambra Basin, Southeastern Nigeria

2021 ◽  
Vol 8 (2) ◽  
pp. 103-109
Author(s):  
Omonigho K. Egbo ◽  
Olugbenga A. Ehinola
Keyword(s):  
Amorphous Materials ◽  
Drilling Fluid ◽  
Significant Proportion ◽  
Chemical Properties ◽  
Chemical Compositions ◽  
Drilling Mud ◽  
X Ray Diffraction ◽  
Southeastern Nigeria ◽  
X Ray ◽  
Geochemical Properties

This study aimed to investigate the mineralogy and chemical properties of the bentonites from the Imo Shale and Ameki formations, vis-a-vis commercially imported bentonite (CIC), for its suitability in formulation of drilling mud. 50 suspected bentonitic clays were studied, and properties of starting materials were utilized during screening. The CIC and four samples that met the API specification for drilling mud were subjected to X-ray diffraction (XRD) and X-ray fluorescence (XRF) analyses. XRD revealed SPL15 consists: 55% kaolinite, 20% quartz, 15% K-feldspar, and 10% hematite, suggesting kaolinite-type; and SPL6, SPL8, and SPL11 consist: 28-47% kaolinite, 26-32% quartz, and 12-20% nontronite, indicating smectite-type with significant amount of kaolinite co-existing, while the CIC consists of 12% quartz, 10% K-feldspar, 12% calcite, 41% nontronite, and 25% amorphous materials. XRF, showed Al2O3 (15.77-25.49) wt%, Fe2O3 (6.61-10.01) wt%, SiO2 (51.67-59.11) wt%, and loss on ignition (7.57-11.22) wt%, indicating variable degrees of alterations. Significant proportion of the CIC exists in an amorphous phase, suspected to be additives. Thus, comparison with the CIC revealed compositional disparity/deficits in the local clays. Consequently, treatment/beneficiations may be necessary to achieve the desired compositions. Based on these results, the primary criteria for the formulation of drilling fluid, using mineralogy and chemical compositions, are achievable.

Quality assessment of some baryte ores in Benue state area, Nigeria for oilfield drilling

2021 ◽  
Vol 8 (4) ◽  
pp. 2861-2872
Author(s):  
Debrah Memshima Oahimire ◽  
Victor Uchechi Ukaegbu ◽  
Joel Friday Ogbonna
Keyword(s):  
Drilling Fluid ◽  
Field Studies ◽  
American Petroleum Institute ◽  
Chemical Compositions ◽  
X Ray Diffraction ◽  
Standard Requirement ◽  
X Ray ◽  
Weight Percentage ◽  
Exploration And Production ◽  
Drilling Operations

The massive exploration and production well drillings in Nigerian oilfield indicate the demand for drilling fluid supplements such as baryte, in managing over-pressured formations and preventing hazardous blowouts. The underdevelopment of Nigerian solid minerals has created a wide gap between the demand and supply of the local resource, whereas there exist some assertions that the Nigerian baryte quality is below the American Petroleum Institute, API, standard. This study aimed at testing and evaluating qualitatively, based on API standards, some baryte ores from the Benue area, Nigeria, to establish their usefulness or otherwise in oilfield drilling operations. General field studies and sampling with laboratory studies were done including flame tests, X-ray Diffraction and X-ray fluorescence, to confirm mineralogy and chemical compositions of the barytes respectively and very importantly, the API tests prescribed for drilling grade barytes were carried out. The results showed impressive quality barytes with a specific gravity range from 4.10 to 4.49 and concentration of alkaline earth metals as calcium, Ca, 20mg/kg to 48mg/kg, particle sizes processed within API standard requirement, and the weight percentage of BaSO4 composition of the ores ranged from 93.55% to 99.61%. There were no significant impurities of threat such as carbonates, iron ores, silicates and sulphides. The estimation of reserves and proper development of the resource is highly recommended as the quantity and quality might enhance the sustainability of local drilling grade baryte supply and save Nigeria the current huge capital flight and other plights

scholarly journals ENHANCEMENT OF GAMBE CLAY USING UN-FERMENTABLE POLYMERS FOR DRILLING MUD FORMULATION

2016 ◽  
Vol 36 (1) ◽  
pp. 119-126
Author(s):  
AO Ibrahim ◽  
OR Momoh ◽  
MT Isa
Keyword(s):  
Molecular Weight ◽  
Drilling Fluid ◽  
Average Molecular Weight ◽  
Chemical Properties ◽  
Methyl Cellulose ◽  
Carboxy Methyl Cellulose ◽  
Drilling Mud ◽  
X Ray ◽  
Gas Drilling ◽  
Carboxy Methyl

There is availability and large deposits of bentonite (700 million tons in North Eastern part) in Nigeria but the clays had not been abundantly harnessed and enhanced with polymer for drilling fluid formulation because they are mostly composed of calcium montmorillonite. This work was aimed at enhancing Gambe clay using un-fermentable polymers (three carboxy methyl cellulose (CMC) with different average molecular weight). The clay was obtained from Gambe town in Adamawa State, Nigeria, beneficiated for quartz removal, as well as enhancement with Na2CO3 (6 wt.%). The mineral and oxides composition of the clay was determined using X-ray diffraction and X-ray fluorescence analyses respectively, and finally used to formulate the drilling fluid. The effect of the polymer on the rheological and physico-chemical properties of the formulated drilling fluid was investigated employing FANN 35SA viscometer.  It was found that the carboxy methyl cellulose enhanced the plastic viscosity from 1.5 cP to 34 cP and the apparent viscosity from 2.25 cP to 44 cP. The higher the average molecular weight of the sodium carboxy methyl cellulose the higher the apparent and plastic viscosities of the formulated fluid. Similarly, the resultant viscosities compared well with that of commercial standard of 15 cP and 14 cP of apparent and plastic viscosities respectively. The sets of data generated from this work is going to be very useful for water and oil/gas drilling operations. http://dx.doi.org/10.4314/njt.v36i1.15

scholarly journals New Insights into the Crystal Chemistry of Elpidite, Na2Zr[Si6O15]·3H2O and (Na1+YCax□1−X−Y)Σ=2Zr[Si6O15]·(3−X)H2O, and Ab Initio Modeling of IR Spectra

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2160
Author(s):  
Alexander Bogdanov ◽  
Ekaterina Kaneva ◽  
Roman Shendrik
Keyword(s):  
Ir Spectra ◽  
Structural Models ◽  
Chemical Characterization ◽  
Chemical Compositions ◽  
X Ray Diffraction ◽  
Special Group ◽  
X Ray ◽  
Influence Of Water ◽  
Radioactive Species

Elpidite belongs to a special group of microporous zirconosilicates, which are of great interest due to their capability to uptake various molecules and ions, e.g., some radioactive species, in their structural voids. The results of a combined electron probe microanalysis and single-crystal X-ray diffraction study of the crystals of elpidite from Burpala (Russia) and Khan-Bogdo (Mongolia) deposits are reported. Some differences in the chemical compositions are observed and substitution at several structural positions within the structure of the compounds are noted. Based on the obtained results, a detailed crystal–chemical characterization of the elpidites under study was carried out. Three different structure models of elpidite were simulated: Na2ZrSi6O15·3H2O (related to the structure of Russian elpidite), partly Ca-replaced Na1.5Ca0.25ZrSi6O15·2.75H2O (close to elpidite from Mongolia), and a hypothetical CaZrSi6O15·2H2O. The vibration spectra of the models were obtained and compared with the experimental one, taken from the literature. The strong influence of water molecule vibrations on the shape of IR spectra of studied structural models of elpidite is discussed in the paper.

scholarly journals Born out of Fire and Ice: Polymorph Studies of the Antiviral Famciclovir

Crystals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 129
Author(s):  
Liana Vella-Zarb ◽  
Ulrich Baisch
Keyword(s):  
Variable Temperature ◽  
Chemical Properties ◽  
Crystal Form ◽  
X Ray Diffraction ◽  
Crystal Forms ◽  
X Ray ◽  
Physical Chemical ◽  
Diffraction Patterns ◽  
Crystalline Forms

There is much interest and focus on solid forms of famciclovir. However, in spite of the abundance of reported differences in oral bioavailability, compressibility, and other physical–chemical properties of the various crystal forms of this drug, very little precise structural analysis is available in the literature to date. The form used in the commercial formulation is the anhydrous form I. Patents and patent applications report three different anhydrous crystalline forms on the basis of unindexed powder diffraction patterns. Single-crystal and variable-temperature X-ray diffraction experiments using the commercially available anhydrous form of famciclovir were carried out and led not only to the crystal structure determination of the anhydrous form I, but also to discovery of a new crystal form of anhydrous famciclovir from powder data.

Monitoring of Fluctuations in the Physical and Chemical Properties of a High-Calcium Fly Ash

1987 ◽  
Vol 113 ◽  
Author(s):  
Scott Schlorholtz ◽  
Ken Bergeson ◽  
Turgut Demirel
Keyword(s):  
Fly Ash ◽  
Chemical Properties ◽  
Operating Conditions ◽  
Physical And Chemical Properties ◽  
X Ray Diffraction ◽  
X Ray ◽  
Morphological Studies ◽  
High Calcium ◽  
Physical And Chemical ◽  
And Chemical Properties

ABSTRACTThe physical and chemical properties of fly ash produced at Ottumwa Generating Station have been monitored since April, 1985. The fly ash is produced from burning a low sulfur, sub-bituminous coal obtained from the Powder River Basin near Gillette, Wyoming. One-hundred and sixty samples of fly ash were obtained during the two year period. All of the samples were subjected to physical testing as specified by ASTM C 311. About one-hundred of the samples were also subjected to a series of tests designed to monitor the self-cementing properties of the fly ash. Many of the fly ash samples were subjected to x-ray diffraction and fluorescence analysis to define the mineralogical and chemical composition of the bulk fly ash as a function of sampling date. Hydration products in selected hardened fly ash pastes, were studied by x-ray diffraction and scanning electron microscopy. The studies indicated that power plant operating conditions influenced the compressive strength of the fly ash paste specimens. Mineralogical and morphological studies of the fly ash pastes indicated that stratlingite formation occurred in the highstrength specimens, while ettringite was the major hydration product evident in the low-strength specimens.

Physico-Chemical and Morphological Changes of Sayong Kaolinite Clay Treated with Sulphuric Acid for Enzyme Immobilization

2013 ◽  
Vol 832 ◽  
pp. 589-595 ◽  
Author(s):  
N.A. Edama ◽  
A. Sulaiman ◽  
K.H. Ku Hamid ◽  
M.N. Muhd Rodhi ◽  
Mohibah Musa ◽  
...  
Keyword(s):  
Surface Area ◽  
Sulphuric Acid ◽  
Enzyme Immobilization ◽  
Morphological Changes ◽  
Chemical Properties ◽  
X Ray Diffraction ◽  
Kaolinite Clay ◽  
X Ray ◽  
Mineral Oxides ◽  
Physico Chemical

This study analyzed the effects of sulphuric acid (H2SO4) treatment on pysico-chemical properties and morphological changes of clay obtained from Sg. Sayong, Perak. The clay was ground and sieved to <150μm and treated with different concentrations of H2SO4. The treatment was completed by refluxing the clay with different concentration of H2SO4 (1M, 5M and 10M ) at 100 °C for 4 hours and followed by calcination at 500 °C for 1 hour. The physic-chemical properties and morphological changes of the untreated and treated clay were compared using Surface Area Analyser, X-Ray Diffraction (XRD), Field Emission Scanning Electron Micrograph (FESEM), X-Ray Diffraction (XRD) and Fourier Transformed Infrared Spectroscopy (FTIR). The results showed that acid treatment of 5M increased the surface area from 25 m2/g to 75 m2/g and the pore volume increased from 0.1518 cc/g to 0.3546 cc/g. The nanopore size of the clay decreased from 24.8 nm to 19.4 nm after treated with acid. This can be explained due to the elimination of the exchangeable cations and generation of microporosity. The results of XRF showed SiO2 increased from 58.34% to 74.52% and Al2O3 reduced from 34.6% to 18.31%. The mineral oxides such as Fe2O3, MgO, CaO, K2O and TiO2 also reduced. This concluded that H2SO4 treatment has led to significant removal of octahedral Al3+, Fe3+ cations and other impurities. In conclusion, this study showed the physico-chemical properties and morphology of Sayong clay were improved once treated with H2SO4 and therefore suggests better supporting material for enzyme immobilization.

Investigations of Actinide Metals and Compounds under Pressure Provide Important Insights into Bonding and Chemistry

2003 ◽  
Vol 802 ◽  
Author(s):  
R. G. Haire ◽  
S. Heathman ◽  
T. Le Bihan ◽  
A. Lindbaum ◽  
M. Iridi
Keyword(s):  
Structural Changes ◽  
Chemical Properties ◽  
X Ray Diffraction ◽  
Interatomic Distances ◽  
X Ray ◽  
Effect Of Pressure ◽  
Electronic Configurations ◽  
5F Electrons ◽  
Actinide Series ◽  
Alloys And Compounds

ABSTRACTOne effect of pressure on elements and compounds is to decease their interatomic distances, which can bring about dramatic perturbations in their electronic nature and bonding, which can be reflected in changes in physical and/or chemical properties. One important issue in the actinide series of elements is the effect of pressure on the 5f-electrons. We have probed changes in electronic behavior with pressure by monitoring structure by X-ray diffraction, and have studied several actinide metals and compounds from thorium through einsteinium. These studies have employed angle dispersive diffraction using synchrotron radiation, and energy dispersive techniques via conventional X-ray sources. The 5f-electrons of actinide metals and their alloys are often affected significantly by pressure, while with compounds, the structural changes are often not linked to the involvement of 5 f-electron. We shall present some of our more recent findings from studies of selected actinide metals, alloys and compounds under pressure. A discussion of the results in terms of the changes in electronic configurations and bonding with regard to the element's position in the series is also addressed.

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