A study of mineral coal physical and mechanical properties changes in thermal modification process

2016 ◽  
pp. 3-8
Author(s):  
V. A. Arsentyev ◽  
◽  
A. M. Gerasimov ◽  
S. V. Dmitriev ◽  
A. D. Samukov ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Physical And Mechanical Properties ◽  
Thermal Modification ◽  
Modification Process

scholarly journals New Perspective on Wood Thermal Modification: Relevance between the Evolution of Chemical Structure and Physical-Mechanical Properties, and Online Analysis of Release of VOCs

Polymers ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1145 ◽  
Author(s):  
Jiajia Xu ◽  
Yu Zhang ◽  
Yunfang Shen ◽  
Cong Li ◽  
Yanwei Wang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Dimensional Stability ◽  
Chemical Structure ◽  
Low Cost ◽  
Physical And Mechanical Properties ◽  
Decay Resistance ◽  
Thermal Modification ◽  
Infrared Spectrometry ◽  
Dominant Component ◽  
New Perspective

Thermal modification (TM) is an ecological and low-cost pretreated method to improve the dimensional stability and decay resistance of wood. This study systematically investigates the relevance between the evolution of chemical structure and the physical and mechanical properties during wood thermal modification processes. Moreover, the volatility of compounds (VOCs) was analyzed using a thermogravimetric analyzer coupled with Fourier transform infrared spectrometry (TGA-FTIR) and a pyrolizer coupled with gas chromatography/mass spectrometer (Py-GC/MS). With an increase of TM temperature, the anti-shrink efficiency and contact angle increased, while the equilibrium moisture content decreased. This result indicates that the dimensional stability improved markedly due to the reduction of hydrophilic hydroxyl (–OH). However, a slight decrease of the moduli of elasticity and of rupture was observed after TM due to the thermal degradation of hemicellulose and cellulose. Based on a TGA-FTIR analysis, the small molecular gaseous components were composed of H2O, CH4, CO2, and CO, where H2O was the dominant component with the highest absorbance intensity, i.e., 0.008 at 200 °C. Based on the Py-GC/MS analysis, the VOCs were shown to be mainly composed of acids, aldehydes, ketones, phenols, furans, alcohols, sugars, and esters, where acids were the dominant compounds, with a relative content of 37.05−42.77%.

scholarly journals INFLUENCE OF THERMAL MODIFICATION ON THE PHYSICAL AND MECHANICAL PROPERTIES OF Eucalyptus badjensis MIXED PARTICLEBOARD / OSB PANELS

FLORESTA ◽  
2021 ◽  
Vol 51 (2) ◽  
pp. 419
Author(s):  
Giuliano Ferreira Pereira ◽  
Setsuo Iwakiri ◽  
Rosilani Trianoski ◽  
Polliana D'angelo Rios ◽  
Renan Zunta Raia
Keyword(s):  
Mechanical Properties ◽  
Water Absorption ◽  
Phenol Formaldehyde ◽  
Physical And Mechanical Properties ◽  
Dry Mass ◽  
Thermal Modification ◽  
Modulus Of Rupture ◽  
Thickness Swelling ◽  
Swelling Properties ◽  
Different Temperatures

The objective of this research was to evaluate the effects of thermal modifications, at different temperatures and exposure times, on the technological properties of mixed particleboard / OSB panels made out of Eucalyptus badjensis. Using the wood of Eucalyptus badjensis, Particleboard, OSB and mixed Particleboard/OSB panels (control and thermally modified) were manufactured. The mixed panels’ thermal modification was carried out under three temperatures (180ºC, 200ºC and 220ºC) and two exposure times (10 minutes and 12 minutes). For the panels’ manufacturing, 6% of phenol-formaldehyde adhesive and 1% of paraffin were employed, which was calculated based on the particles’ dry mass. The water absorption and thickness swelling properties were evaluated after 2 and 24 hours of immersion, in addition to the panels’ modulus of elasticity, modulus of rupture and internal bond. Based on the results, we were able to conclude that the thermal modification affected most of the physical properties positively. From the different exposure times studied, the most effective one was the period of 12 minutes, especially for water absorption after 2 hours, which caused a reduction of 11.27%. In turn, the most effective temperature was of 220ºC, highlighting the thickness swelling after 24 hours, which caused a swelling decrease of 23.76% in comparison with the control panels. Regarding the mechanical properties, the thermal modification, in terms of the studied exposure times and temperatures, did not affect the results of the mixed particleboard /OSB panels. 

scholarly journals Mechanical properties changes in fir wood (abies sp.), linden wood (tilia sp.), and beech wood (fagus sp.) subjected to various thermal modification process conditions

2021 ◽  
Vol 1208 (1) ◽  
pp. 012025
Author(s):  
Redžo Hasanagić ◽  
Sauradipta Ganguly ◽  
Ermin Bajramović ◽  
Adem Hasanagić
Keyword(s):  
Mechanical Properties ◽  
Beech Wood ◽  
Construction Materials ◽  
Treated Wood ◽  
Thermal Modification ◽  
Process Conditions ◽  
Modification Process ◽  
Maximum Duration ◽  
Different Temperatures ◽  
Control Samples

Abstract Wood is one of the most important construction materials in Europe and its use in building applications has increased in the recent decades. To enable even more extensive and reliable use of wood, this article aimed to determine the effect of thermal modification on mechanical properties of fir wood (lat. Abies sp.), linden wood (lat. Tilia sp.), and beech wood (lat. Fagus sp.). The thermal modification was conducted in a laboratory oven at five different temperatures of 170, 180, 195, 210, 220 °C and processed with a different maximum duration of the process of 78, 120, 180, 240, 276 minutes. Mechanical properties of treated wood have shown statistically insignificant fluctuations at lower temperatures compared to control samples. On the other hand, raising the temperature to 210 °C significantly affected the strength of all the species. The results revealed that thermal modification at high temperatures and longer exposure causes a decrease in the maximum force of the three wood species.

scholarly journals Physical and Mechanical Properties of Thermally-Modified Beech Wood Impregnated with Silver Nano-Suspension and Their Relationship with the Crystallinity of Cellulose

Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1538 ◽  
Author(s):  
Siavash Bayani ◽  
Hamid R. Taghiyari ◽  
Antonios N. Papadopoulos
Keyword(s):  
Mechanical Properties ◽  
Physical Properties ◽  
Low Temperatures ◽  
Beech Wood ◽  
Treated Wood ◽  
Physical And Mechanical Properties ◽  
Thermal Modification ◽  
Crystalline Cellulose ◽  
Cross Linking ◽  
Amorphous Cellulose

The aim of this study was to investigate the physical and mechanical properties of thermally modified beech wood impregnated with silver nano-suspension and to examine their relationship with the crystallinity of cellulose. Specimens were impregnated with a 400 ppm nanosilver suspension (NS); at least, 90% of silver nano-particles ranged between 20 and 100 nano-meters. Heat treatment took place in a laboratory oven at three temperatures, namely 145, 165, and 185 °C. Physical properties and mechanical properties of treated wood demonstrated statistically insignificant fluctuations at low temperatures compared to control specimens. On the other hand, an increase of temperature to 185 °C had a significant effect on all properties. Physical properties (volumetric swelling and water absorption) and mechanical properties (MOR and MOE) of treated wood demonstrated statistically insignificant fluctuations at low temperatures compared to control specimens. This degradation ultimately resulted in significant decrease in MOR, impact strength, and physical properties. However, thermal modification at 185 °C did not seem to cause significant fluctuations in MOE and compression strength parallel to grain. As a consequence of the thermal modification, part of amorphous cellulose was changed to crystalline cellulose. At low temperatures an increased crystallinity caused some of the properties to be improved. Crystallinity also demonstrated a decrease in NS-HT185 in comparison to HT185 treatment. TCr indices in specimens thermally treated at 145 °C revealed a significant increase as a result of impregnation with nanosilver suspension. This improvement in TCr index resulted in a noticeable increase in MOR and MOE values. Other properties did not show significant fluctuations, suggesting that the effect of the increased crystallinity and cross-linking in lignin was more than the negative effect of the low cell-wall polymer degradation caused by thermal modification. Change of amorphous cellulose to crystalline cellulose, as well as cross-linking in lignin, partially ameliorated the negative effects of thermal degradation at higher temperatures and therefore, compression parallel to grain and modulus of elasticity did not decrease significantly. Overall, it can be concluded that increased crystallinity and cross-linking in lignin can compensate for some decreased properties caused by thermal modification, but it would be significantly dependent on the temperature under which modification is carried out. Impregnating specimens with silver nano-suspension prior to thermal modification enhanced the effects of thermal modification as a result of improved thermal conductivity.

The toughness of hygrothermally modified wood

Holzforschung ◽  
2015 ◽  
Vol 69 (7) ◽  
pp. 851-862 ◽  
Author(s):  
Mark Hughes ◽  
Callum Hill ◽  
Alexander Pfriem
Keyword(s):  
Mechanical Properties ◽  
Coupling Agent ◽  
Thermal Modification ◽  
Point Of View ◽  
Interfacial Coupling ◽  
Modification Process ◽  
Thermally Modified Wood ◽  
Wall Components ◽  
Modified Wood

Abstract The mechanical properties of thermally modified wood are discussed with regard to toughness. The molecular origins of the mechanical properties and, in particular, the role of the hemicelluloses are considered. The important role of water and its interaction with the cell wall components is also examined. The properties are discussed from the point of view of composite theory, with the three main macromolecular components acting as reinforcement, matrix and interfacial coupling agent. The important role that hemicelluloses play as a coupling agent between the cellulosic microfibril reinforcement and the lignin-rich matrix is highlighted. Destruction of the hemicelluloses during the thermal modification process has a profound effect upon the mechanical behaviour.

scholarly journals Physical and Mechanical Properties of Heat Treated Daniella oliveri (Africa Balsam Tree) Wood

2019 ◽  
pp. 1-9 ◽  
Author(s):  
Ebenezer Adeyemi Iyiola ◽  
Babatola Olufemi ◽  
Victoria Olubukola Oyerinde ◽  
J. M. Owoyemi ◽  
Ayanleye Samuel
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Compressive Strength ◽  
Study Design ◽  
Dimensional Stability ◽  
Treated Wood ◽  
Physical And Mechanical Properties ◽  
Thermal Modification ◽  
Average Weight ◽  
Direction Parallel

Aims: This work investigated the effect of thermal modification on some of the physical properties and mechanical properties of Daniella oliveri wood. Study Design: The study design used for this experiment was 3 x4 Factorial experiment in Completely Randomized Design. Place and Duration of Study: The study was conducted at the Federal University of Technology, Akure wood laboratory and the study lasted for 6 months. Methodology: Wood samples were thermally treated at the temperature of 120, 140, 160 and 180°C, for different durations of 1, 1.5 and 2 hours in a muffle furnace. The planks were air-dried to reduce the moisture content and then machined into the required dimensions in the direction parallel to grain with a circular saw. Thirty-nine defect-free samples of dimensions 20 mm × 20 mm × 60 mm were prepared for dimensional stability and compression test, static bending tests and the hardness tests to make a total of 117 samples. Results: The result showed that the average weight loss of the treated wood samples varied from 3.79% at 120°C for 1 hour to 7.51% at 180°C for 2 hours. The treatment led to reduction in density from 528 to 459 kg/m3 at 180°C for 2 hours. The heat treatment also led to reduction in water absorption and volumetric swelling of the treated samples. The mean value for Modulus of elasticity (MOE) ranges from 2.17x103 N/mm2 to 2.96 x 103 N/mm2 for the treated samples while the untreated was 2.22x103 N/mm2. Heat treatment brought about improvement in the maximum compressive strength and the Janka hardness parallel to the grain of wood samples. The value of compressive strength increased from 26.58 N/mm2 to 41.71 N/mm2 and hardness from 69.24 N to 75.5 N. It can therefore be concluded that thermal modification greatly enhanced the dimensional stability and mechanical properties of wood samples.

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