Peculiar properties of abundances of some chemical elements in metal-rich field RR Lyrae variables

2021 ◽  
pp. 147-152
Author(s):  
M. L. GOZHA ◽  
V. A. MARSAKOV ◽  
V. V. KOVAL

On the data of the author's catalog of spectroscopic determinations of the chemical element abundances in the atmospheres of galactic field RR Lyrae variables, it has been shown that the relative abundances of scandium, titanium and yttrium in metal-rich RR Lyraes ([Fe/H > - 1.0) are less, outside the error limits, than in field stars of similar metallicity. It is noted that the abundances of europium, zirconium and lanthanum are not determined in any metal-rich RR Lyraes. Errors in determining the abundances of these chemical elements are discussed. The possible causes of the peculiarities of the observed chemical composition in metal-rich RR Lyraes are analyzed.

2016 ◽  
Vol 25 (1) ◽  
pp. 1-9
Author(s):  
V. A. Marsakov ◽  
V. V. Koval’ ◽  
M. L. Gozha ◽  
L. V. Shpigel’

AbstractOn the basis of the authors’ compiled catalog containing spectroscopic abundances of 14 chemical elements for 90 open star clusters of the Galaxy, we show that in the young clusters not only barium but also three other studied elements of slow neutron-capture, Y, La, and Ce, reveal higher relative abundances than those in the field stars, with differences beyond the error limits. We also find that, at high metallicity ([Fe/H]> −0.1), the relative abundances of the


Author(s):  
Radiy Kh. Gimaletdinov ◽  
Andrey A. Gulakov ◽  
Ildar Kh. Tukhvatulin

Problem Statement (Relevance): An urgent task of rolling mill operators includes minimizing the cost of manufactured products while ensuring the required quality. To accomplish the task, measures are being taken to optimize the rolling process aimed at increasing the duration of the rolling campaigns and reducing the number of roll regrinds. The performance of the rolls is influenced by the properties of the working layer material which determine wear resistance, formation and development of fire cracks, as well as resistance to metal sticking. Finishing mill rolls dictate the surface quality of the rolled steel. That is why it is important to make timely regrinds in order to completely remove the fire crack layer. The removal depth and the acceptable duration of the campaigns depend on the properties of the roll working layer material. To improve the properties of the rolls, the roll manufacturers need the actual roll operation data to be able to analyze how the chemical composition and the structure of the roll working layer is related to the roll performance. Such analysis will help improve the structure and properties of the materials used, as well as develop new ones. Objectives: The objective of this research is to understand how the chemical composition of the working layer of indefinite chilled cast iron rolls used in finishing mills dictates the roll performance, to evaluate the effect of each chemical element, and to determine what concentrations of the chemical elements could most effectively benefit the performance of indefinite chilled cast iron rolls. Methods Applied: The methods applied include building a database of the finishing mill indefinite chilled cast iron rolls and using artificial neural networks based on a dual-function algorithm. Originality: The authors built a neuromodel which can help understand the effect of the chemical composition of the roll working layer and predict the performance of indefinite chilled cast iron rolls. The authors studied the effect of carbon, silicon, manganese, chromium, nickel, molybdenum, vanadium, niobium and boron on the performance of indefinite chilled cast iron rolls. Findings: Graphic diagrams were built which demonstrate the effect of each chemical element on the performance of indefinite chilled cast iron rolls at constant concentrations of the remaining elements. The authors looked at the relationship between the chemical elements and the roll performance in terms of the impact of the former on the structure of indefinite chilled cast iron rolls. The effective concentrations of the chemical elements were also determined. Practical Relevance: The authors developed a new chemical composition of indefinite chilled cast iron to be used for the working layer of finishing mill rolls. As a result, a 12–14% increase in the roll performance was achieved.


2011 ◽  
Vol 20 (1) ◽  
Author(s):  
G. Barisevišius ◽  
G. Tautvaišienė ◽  
S. Berdyugina ◽  
Y. Chorniy ◽  
I. Ilyin

AbstractAbundances of 22 chemical elements, including the key elements and isotopes such as


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Rasa Zalakeviciute ◽  
Katiuska Alexandrino ◽  
Yves Rybarczyk ◽  
Alexis Debut ◽  
Karla Vizuete ◽  
...  

Abstract Particulate matter (PM) is one of the key pollutants causing health risks worldwide. While the preoccupation for increased concentrations of these particles mainly depends on their sources and thus chemical composition, some regions are yet not well investigated. In this work the composition of chemical elements of atmospheric PM10 (particles with aerodynamic diameters ≤ 10 µm), collected at the urban and suburban sites in high elevation tropical city, were chemically analysed during the dry and wet seasons of 2017–2018. A large fraction (~ 68%) of PM10 composition in Quito, Ecuador is accounted for by water-soluble ions and 16 elements analysed using UV/VIS spectrophotometer and Inductively Coupled Plasma—Optical Emission Spectroscopy (ICP-OES). Hierarchical clustering analysis was performed to study a correlation between the chemical composition of urban pollution and meteorological parameters. The suburban area displays an increase in PM10 concentrations and natural elemental markers during the dry (increased wind intensity, resuspension of soil dust) season. Meanwhile, densely urbanized area shows increased total PM10 concentrations and anthropogenic elemental markers during the wet season, which may point to the worsened combustion and traffic conditions. This might indicate the prevalence of cardiovascular and respiratory problems in motorized areas of the cities in the developing world.


1993 ◽  
Vol 138 ◽  
pp. 192-196
Author(s):  
L.S. Lyubimkov ◽  
T.M. Rachkovskaya

Duplicity is a very widespread phenomenon among Am-stars. For instance, Abt (1961) investigating 25 such stars found out that 22 of them are spectroscopic binaries. However this important phenomenon is ignored usually in chemical composition investigations of Am-stars. Consequently some “mean” element abundances are determined, which can noticeably differ from real abundances in atmospheres of components. Moreover false chemical anomalies can appear, as shown by the theoretical modelling of spectra of binary stars (Lyubimkov, 1989, 1992). Meanwhile accurate data on chemical composition of Am-stars must be considered as observational test for any hypothesis suggested for explanation of these objects.


1975 ◽  
Vol 67 ◽  
pp. 541-543
Author(s):  
A. V. Mironov ◽  
N. N. Samus'

The dependences of the numbers of variable stars in globular clusters on the chemical composition are studied. For given metallicity the numbers of RR Lyrae stars reduced to some definite total number of stars in the cluster are different for the two groups of globular clusters introduced by Mironov.


Molecules ◽  
2021 ◽  
Vol 26 (10) ◽  
pp. 2949
Author(s):  
Juan I. Burneo ◽  
Ángel Benítez ◽  
James Calva ◽  
Pablo Velastegui ◽  
Vladimir Morocho

Chemical compositions of plants are affected by the initial nutrient contents in the soil and climatic conditions; thus, we analyzed for the first time the effects of soil and leaf nutrients on the compositions of the essential oils (EOs) of Siparuna muricata in four different localities in Ecuador. EOs were obtained by hydrodistillation and analyzed by gas chromatography/mass spectrometry (GC/MS) and a gas chromatography/flame ionization detector (GC/FID). Enantiomeric distribution by GC/MS was determined, modifying the enantiomeric separation of β-pinene, limonene, δ-elemene, β-bourbonene, cis-cadina-1 (6), 4-diene and atractylone. A total of 44 compounds were identified. The most representative for L1 were guaiol, atractylone and 4-diene; for L2, cis-cadina-1(6),4-diene and myrcene; for L3, atractylone, myrcene and germacrene B; and finally, L4 germacrene B, myrcene and cis-cadina-1(6),4-diene. Correlations between soil- leaf chemical elements such as Al, Ca, Fe, Mg, Mn, N and Si in the different localities were significant with chemical composition of the essential oil of Siparuna muricata; however, correlations between soil and leaf K, P, and Na were not significant. Cluster and NMDS analysis showed high dissimilarity values of secondary metabolites between four localities related with changes in soil- leaf nutrients. Thus, the SIMPER routine revealed that not all secondary metabolites contribute equally to establishing the differences in the four localities, and the largest contributions are due to differences in guaiol, cis-cadina-1(6),4-diene, atractylone and germacrene. Our investigation showed for the first time the influences of altitude and soil- leaf chemical elements in the chemical composition of the EOs of S. muricata.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Ilse Valenzuela Matus ◽  
Jorge Lino Alves ◽  
Joaquim Góis ◽  
Augusto Barata da Rocha ◽  
Rui Neto ◽  
...  

Purpose The purpose of this paper is to prove and qualify the influence of textured surface substrates morphology and chemical composition on the growth and propagation of transplanted corals. Use additive manufacturing and silicone moulds for converting three-dimensional samples into limestone mortar with white Portland cement substrates for coral growth. Design/methodology/approach Tiles samples were designed and printed with different geometries and textures inspired by nature marine environment. Commercial coral frag tiles were analysed through scanning electron microscopy (SEM) to identify the main chemical elements. Raw materials and coral species were selected. New base substrates were manufactured and deployed into a closed-circuit aquarium to monitor the coral weekly evolution process and analyse the results obtained. Findings Experimental results provided positive statistical parameters for future implementation tests, concluding that the intensity of textured surface, interfered favourably in the coralline algae biofilm growth. The chemical composition and design of the substrates were determinant factors for successful coral propagation. Recesses and cavities mimic the natural rocks aspect and promoted the presence and interaction of other species that favour the richness of the ecosystem. Originality/value Additive manufacturing provided an innovative method of production for ecology restoration areas, allowing rapid prototyping of substrates with high complexity morphologies, a critical and fundamental attribute to guarantee coral growth and Crustose Coralline Algae. The result of this study showed the feasibility of this approach using three-dimensional printing technologies.


2021 ◽  
Vol 316 ◽  
pp. 521-526
Author(s):  
Vladimir A. Nosenko ◽  
Alexander V. Fetisov ◽  
Semen P. Kuznetsov

The article summarizes the results of the of the titanium alloy surface morphology and chemical composition study after grinding with a wheel of cubic boron nitride on a ceramic bond. The titanium alloy was treated using the method of cut-in grinding in the finishing mode using a synthetic water-soluble lubricant-cooling liquid that does not contain mineral oil. The research was carried out using the FEI Versa 3D LoVac electron microscope. Digital photos of the titanium alloy surface at different magnifications are given. Individual objects’ morphology allows us to identify them as wear products of abrasive tools. The chemical composition of the selected objects was studied by local x-ray spectral analysis. CBN crystals are partially or completely pressed into the treated surface and covered with a layer of the treated material. On the surface of CBN crystals, there are chemical elements that are part of the abrasive tool bond.


2021 ◽  
pp. 51-56
Author(s):  
Yu. B. Sazonov ◽  
D. Yu. Ozherelkov ◽  
R. Sh. Latypov ◽  
E. E. Gorshkov

Possibility of determination of the fragments and articles made of different grades of steel aluminium and copper alloys and their affiliation to the common melt was examined via the methods of photoelectric spectral analysis based on composition of micro-impurities. Chemical elements with micro-impurities were revealed; they allow to determine affiliation of metal fragments to one melt. Ultimately possible deviations of micro-impurities within one melt were obtained. The technique allowing to establish affiliation of fragments to the common melt based on their elementary composition of micro-impurities with minimal amount of measurements was suggested based on the obtained results. The minimal geometric size of a sample available for analysis was determined; it allows to classify the examined fragments to one melt based on the results of investigation of expanded elementary composition of micro-impurities. Practical opportunities of this technique were displayed on the example of the alloys with different chemical composition.


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