scholarly journals Catalytic Conversion of Methane: Carbon Dioxide Reforming and Oxidative Coupling

2012 ◽  
Vol 55 (1) ◽  
pp. 1-12 ◽  
Author(s):  
Kazuhiro Takanabe
Author(s):  
E. Busillo ◽  
V. I. Savchenko ◽  
V. S. Arutyunov

Abstract A detailed kinetic modeling of the noncatalytic processes of thermal pyrolysis and steam and carbon dioxide reforming of methane revealed almost completely identical kinetics of the methane conversion in these processes. This suggests that, in the temperature range 1400–1800 K, the initial stage of conversion of methane in all these processes is its thermal pyrolysis. The modeling results agree well with the experimental data on methane pyrolysis. For the temperature range examined, the Arrhenius expressions (pre-exponential factors and activation energy) were obtained in the first-order kinetics approximation for the rate of methane conversion in the processes studied. The expressions derived may be useful for making preliminary estimates and carrying out engineering calculations.


Fuel ◽  
2021 ◽  
Vol 284 ◽  
pp. 118909 ◽  
Author(s):  
Ruifeng Peng ◽  
Yumin Chen ◽  
Baoxu Zhang ◽  
Zhipeng Li ◽  
Xin Cui ◽  
...  

2008 ◽  
Vol 47 (14) ◽  
pp. 4617-4622 ◽  
Author(s):  
Cesar A. M. Abreu ◽  
Douglas A. Santos ◽  
José A. Pacífico ◽  
Nelson M. Lima Filho

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