Formation of Free Sulfur in Hydrodesulfurized Gas Oil—Precautions for Pilot Test of Ultra Deep Hydrodesulfurization Catalysts—

2005 ◽  
Vol 48 (5) ◽  
pp. 319-323 ◽  
Author(s):  
Ryuichiro Iwamoto ◽  
Hiromichi Koshika ◽  
Nobuyuki Takahashi ◽  
Kazuhiro Inamura
1995 ◽  
Vol 60 (4) ◽  
pp. 568-575
Author(s):  
Karel Sporka ◽  
Jiří Hanika ◽  
Vladimír Jůn

Preparation of skeletal Co-Mo catalysts by controlled impregnation of aluminosilicate skeletons containing deposited gamma-alumina with aqueous solutions of active component precursors has been investigated. The activity of the laboratory catalysts in gas oil hydrodesulfurization has been determined. Kinetics of impregnation of skeletal supports, the effect of their type, and the dependence of catalyst activity on the content of cobalt and molybdenum sulfides are reported. HDS skeletal catalysts prepared were compared with the extruded types. It was found that skeletal HDS catalysts show the higher activity (related to the content of alumina and Co-Mo sulfides) than the extruded ones due to the less significant effect of internal diffusion. However, if the activity is related to the same volume of catalyst bed, the activity of skeletal catalysts is only one fourth of that of the extruded types.


2012 ◽  
Vol 26 (6) ◽  
pp. 3856-3863 ◽  
Author(s):  
A. Vonortas ◽  
Ch. Templis ◽  
N. Papayannakos

1992 ◽  
Vol 57 (12) ◽  
pp. 2501-2508 ◽  
Author(s):  
Karel Sporka ◽  
Jiří Hanika

The Co-Mo catalysts have been prepared on laboratory scale by controlled impregnation of extruded γ-alumina with aqueous solutions of suitable active components, and their activity has been tested in the hydrodesulfurization and hydrogenation of aromatic compounds in gas oil. The kinetics of impregnation of the carrier, the effect of its nature, the order of impregnation of precursors of the individual active components, and the effect of their nature on the activity of the catalyst prepared have been studied. The samples prepared have been compared with selected commercial catalysts.


1999 ◽  
Vol 61 (1-2) ◽  
pp. 89-101 ◽  
Author(s):  
W.R.A.M Robinson ◽  
J.A.R van Veen ◽  
V.H.J de Beer ◽  
R.A van Santen

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