scholarly journals Synthesis, structure and electrical properties of Li+-doped pyrochlore Gd2Zr2O7

2020 ◽  
Vol 7 (2) ◽  
pp. 51-60
Author(s):  
Irina A. Anokhina ◽  
Irina E. Animitsa ◽  
Anastasia F. Buzina ◽  
Vladimir I. Voronin ◽  
Vladimir B. Vykhodets ◽  
...  

The pyrochlore Gd1.55Li0.45Zr2O6.55 was prepared by the solution and solid-state methods. The introduction of lithium in the Gd-sublattice led to decrease in the lattice parameter a = 10.4830(8) Å in comparison with Gd2Zr2O7 (a =10.5346(2) Å). Monitoring of the lithium content in the sample during heat treatments showed a loss of lithium at temperatures above 1100 °C, so, to maintain the stoichiometry of lithium the low temperature sintering methods are required. The sample Gd1.55Li0.45Zr2O6.55 exhibited a predominant oxygen-ion transport over a wide range of temperatures.  Although doping did not lead to an increase in the oxygen-ion conductivity compared to Gd2Zr2O7, it caused the suppression of the hole conductivity.

2019 ◽  
Vol 17 (2) ◽  
pp. 722-727
Author(s):  
Yongcheng Lu ◽  
Yuanxun Li ◽  
Rui Peng ◽  
Hua Su ◽  
Zhihua Tao ◽  
...  

2014 ◽  
Vol 979 ◽  
pp. 302-306 ◽  
Author(s):  
Chalermpol Rudradawong ◽  
Aree Wichainchai ◽  
Aparporn Sakulkalavek ◽  
Yuttana Hongaromkid ◽  
Chesta Ruttanapun

In this paper, the CuFeO2compound were prepared by classical solid state reaction (CSSR) and direct powder dissolved solution (DPDS) method from starting material metal oxides and metal powders. Preparation of two methods shows that, direct powder dissolved solution faster recover phases than classical solid state reaction method. The fastest method gets from starting materials Cu and Fe metal powders, the electrical conductivity, Seebeck coefficient, carrier concentration and mobility are 10.68 S/cm, 244.59 μV/K, 12.86×1016cm-3and 494.96 cm2/V.s, respectively. In addition, each CuFeO2compounds were investigated on crystal structure and electrical properties. From XRD and SEM results, all samples have a crystal structure delafossite-typeand a large grain boundary more than 15 μm by electrical conductivity corresponds to grain boundary and lattice parameter: a increases. Within this paper, from above results exhibit that preparation CuFeO2from Cu and Fe by direct powder dissolved solution method most appropriate for thermoelectric oxide materials due to high active for preparation else high lattice strain and high power factor are 0.00052 and 0.64×10-4W/mK2, respectively.


1993 ◽  
Vol 320 ◽  
Author(s):  
A. Lauwers ◽  
A. Vercaemst ◽  
M. Van Hove ◽  
K. Kyllesbech Larsen ◽  
R. Verbeeck ◽  
...  

ABSTRACTIn this paper the electrical properties of epitaxial CoSi2 on Si obtained by solid-state reaction of a Ti/Co bimetallic layer are investigated. Low temperature resistivity, magnetoresistance and Hall data are presented. The CoSi2ISi Schottky diodes are characterised by current - voltage and capacitance - voltage measurements at temperatures varying between - 100°C and 60°C.


2016 ◽  
Vol 28 (2) ◽  
pp. 1909-1913
Author(s):  
Xiao Qu ◽  
Wei-Jie Sun ◽  
Mao-Hua Wang ◽  
Yong Chen ◽  
Han-Ping Zhang

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