Structure/Property Relationships and Applications of Rapidly Solidified Aluminum Alloys

1981 ◽  
Vol 8 ◽  
Author(s):  
C. M. Adam

ABSTRACTDuring the last five years Pratt & Whitney Aircraft has developed rapid solidification powder metallurgy and consolidation techniques to produce advanced aluminum alloys. A centrifugal rotary atomization device with forced high velocity helium convective cooling has been developed to pilot-plant stage, to produce aluminum alloys of novel compositions for advanced gas turbine engine applications. Rapidly solidified aluminum alloys solidify as spherical droplets up to 100 μm diameter with cooling rates of 105 — 106 K/sec, and demonstrate new microstructural features which have been exploited to develop elevated temperature mechanical properties. Alloys have been developed for 400 — 500°F fan and compressor applications that have traditionally used titanium alloys, and this paper reviews the microstructural evolution of rapidly solidified structures during thermomechanical processing.

1985 ◽  
Vol 58 ◽  
Author(s):  
A. Brown ◽  
D. Raybould

ABSTRACTIn recent years, interest in high temperature aluminum alloys has increased. However, nearly all the data available is for simple extrusions. This paper looks at the properties of sheet made from a rapidly solidified Al-10Fe-2.5V-2Si alloy. The sheet is made by direct forging followed by hot rolling, this is readily scalable, so allowing the production of large sheet. The room temperature strength and fracture toughness of the sheet are comparable to those of 2014-T6. The high temperature strength, specific stiffness and corrosion resistance are excellent. Recently, improved thermomechanical processing and new alloys have allowed higher strengths and fracture toughness values to be obtained.


Author(s):  
S.V.S. Narayana Murty ◽  
Sushant K. Manwatkar ◽  
P. Ramesh Narayanan

Microstructure plays an important role in obtaining the desired properties in metallic materials in general and aluminum alloys in particular. Mechanical properties of aluminum alloys can be significantly altered by changing the microstructure. No other alloy system can boast of as many temper conditions as aluminum alloys. With the progress in the understanding of microstructure–mechanical property relationships in these materials, “tailor made” alloys to meet specific demands are being industrially developed. The broad spectrum of aluminum alloys in wide range of temper conditions offer materials with widely varying mechanical properties for structural designers. In order to select aluminum alloys with the desired properties for the intended application, it is essential to understand the role of microstructure under actual service conditions. It is in this context “Metallography of aluminum alloys” becomes very important. This chapter provides an insight in to the microstructural evolution of aluminum alloys from the as-cast condition to the final product. Typical examples of microstructural evolution in different aluminum alloys under various thermomechanical conditions are presented here. An atlas of microstructures of commercial and experimental wrought and cast aluminum alloys is presented in an appendix to this book. This appendix includes optical photomicrographs of both cast and wrought alloys and scanning electron micrographs of polished surfaces as well as fracture surfaces of various aluminum alloys as well as transmission electron micrographs as separate annexure. Readers are encouraged to go through the optical microstructures and fractographs along with this chapter for better understanding of the evolution of microstructure as a function of alloying additions, thermomechanical processing conditions, and fracture behavior under tension.


2014 ◽  
Vol 87 (2) ◽  
pp. 219-238 ◽  
Author(s):  
Roberto Todeschini ◽  
Viviana Consonni ◽  
Davide Ballabio ◽  
Andrea Mauri ◽  
Matteo Cassotti ◽  
...  

ABSTRACT In this preliminary study, mathematical models based on Quantitative Structure Property Relationships (QSPR) were applied in order to analyze how molecular structure of chloroprene rubber accelerators relates to their rheological and mechanical properties. QSPR models were developed in order to disclose which structural features mainly affect the mechanism of vulcanization. In such a way QSPR can help in a faster and more parsimonious design of new chloroprene rubber curative molecules. Regression mathematical models were calibrated on two rheological properties (scorch time and optimum cure time) and three mechanical properties (modulus 100%, hardness, and elongation at break). Models were calculated using experimental values of 14 accelerators belonging to diverse chemical classes and validated by means of different strategies. All the derived models gave a good degree of fitting (R2 values ranging from 84.5 to 98.7) and a satisfactory predictive power. Moreover, some hypotheses on the correlations between specific structural features and the analyzed rheological and mechanical properties were drawn. Owing to the relatively small set of accelerators used to calibrate the models, these hypotheses should be further investigated and proved.


Author(s):  
R. J. Kar ◽  
T. P. McHale ◽  
R. T. Kessler

Low-density and high strength-type rapidly solidified (RST) aluminum alloys offer promise for structural aerospace applications. At Northrop, as part of a continuing program to establish structure-property relationships in advanced materials, detailed transmission electron microscopy (TEM)/scanning transmission electron microscopy (STEM) of candidate RST aluminum-lithium (Al-Li) and high strength (7XXX-type) aluminum-copper-magnesium-zinc (Al-Cu-Mg-Zn) alloys is routinely performed. This paper describes typical microstructural features that we have observed in these alloys.Figure 1 illustrates the microstructure of an inert-gas atomized RST Al-Li-Cu-Mg-Zr alloy. Frequently the grain boundaries are decorated with continuous or semi-continuous stringers of oxide that are relatively opaque to the incident electron beam. These have been identified to be Al-,Mg-, and Li- containing oxides present on powder particle surfaces prior to consolidation, and which have not been adequately broken up and dispersed by post-consolidation processing. The microstructures of these alloys are generally characterized by unrecystallized grains and equiaxed sub-grains pinned by fine (0.2μm) precipitates. These have been identified to be Al3Zr dispersoids using a combination of selected area diffraction/energy-dispersive x-ray (SAD/EDX) methods.


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