Design Maps for the Tensile Yield Strength of Nanoscale Metallic Multilayers

2003 ◽  
Vol 795 ◽  
Author(s):  
Adrienne V. Lamm ◽  
Peter M. Anderson

ABSTRACTMetallic nanolayered composite materials can exhibit yield strengths one and a half to two times that of the constituents from which they are constructed. However, experimental data frequently show that there is a critical bi-layer period Λ below which the strength no longer increases with decreasing Λ To help understand the origins of this behavior and to guide future design of multilayers, maps of the internal stress and overall tensile macroyield stress are calculated as functions of the volume fractions of the two alternating constituents and bi-layer period, for a given lattice parameter ratio and elastic modulus ratio. Adopted here is a premise suggested by embedded atom simulations of Cu/Nb multilayers and recent experimental work on γ -Ni/γ-Ni3Al multilayers that the overall tensile strength is determined by the applied stress needed to eliminate the compressive bi-axial stress in the alternating layers. The results indicate that indeed, there is a critical bi-layer period below which the strength is independent of bi-layer period. In this regime, multilayer tensile strength is most effectively improved by increasing the stored compressive stress. This is achieved by decreasing the volume fraction of the compressively stressed phase. This manuscript extends previous work by providing closed-form expressions for the macroyield strength of free-standing multilayered thin films.

2014 ◽  
Vol 783-786 ◽  
pp. 619-623 ◽  
Author(s):  
Tomonrori Kitashima ◽  
K.S. Suresh ◽  
Y. Yamabe-Mitarai ◽  
S. Iwasaki

The present study aims to quantify the properties of Ga-bearing near-titanium alloys in order to aid the future design of new compositions with Ga addition. The effect of different amounts of Sn and Ga, with an almost constant value in the Al equivalent without the formation of 2 phase, on microstructure, tensile strength and Charpy impact toughness was investigated at room temperature and 650°C. The microstructures after forging, hot rolling and heat treatment showed a bimodal structure. Increasing Ga decreased the 0.2% proof stress at 650°C. However, these alloys showed similar impact value at room temperature which was about 40 J/cm2. Increasing the amount of Ga increased the volume fraction of the equiaxed phase. The amount of Ga had only a minor effect on grain size, misorientation angles and grain aspect ratios of the alloy. However, Ga addition had a strong influence on the evolution of texture. Formation of <10-10> and <10-11> || normal direction (ND) fibers were observed in the Ga added samples, in addition to <0001> || ND fiber with a weak <10-11> || ND fiber. The Ga-free sample contained a strong <0001> || ND fiber. Other fibers were not observed.


Crystals ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1228
Author(s):  
Honglin Zhang ◽  
Zhigang Xu ◽  
Laszlo J. Kecskes ◽  
Sergey Yarmolenko ◽  
Jagannathan Sankar

The present work mainly investigated the effect of extrusion temperatures on the microstructure and mechanical properties of Mg-1.3Zn-0.5Ca (wt.%) alloys. The alloys were subjected to extrusion at 300 °C, 350 °C, and 400 °C with an extrusion ratio of 9.37. The results demonstrated that both the average size and volume fraction of dynamic recrystallized (DRXed) grains increased with increasing extrusion temperature (DRXed fractions of 0.43, 0.61, and 0.97 for 300 °C, 350 °C, and 400 °C, respectively). Moreover, the as-extruded alloys exhibited a typical basal fiber texture. The alloy extruded at 300 °C had a microstructure composed of fine DRXed grains of ~1.54 µm and strongly textured elongated unDRXed grains. It also had an ultimate tensile strength (UTS) of 355 MPa, tensile yield strength (TYS) of 284 MPa, and an elongation (EL) of 5.7%. In contrast, after extrusion at 400 °C, the microstructure was almost completely DRXed with a greatly weakened texture, resulting in an improved EL of 15.1% and UTS of 274 MPa, TYS of 220 MPa. At the intermediate temperature of 350 °C, the alloy had a UTS of 298 MPa, TYS of 234 MPa, and EL of 12.8%.


1994 ◽  
Vol 362 ◽  
Author(s):  
S. I. Rao ◽  
P. M. Hazzledine ◽  
D. M. Dimiduk

AbstractExperimental results show that a nanolayered composite structure made of two kinds of metals strengthens dramatically as the layer thickness is reduced. In epitaxial systems, this strengthening has been attributed classically, to the modulus and lattice parameter mismatches between adjacent layers. The modulus mismatch introduces a force between a dislocation and its image in the interface. The lattice parameter mismatch generates stresses and mismatch dislocations which interact with mobile dislocations. In addition to these two interactions, there is the difficulty of operating a Frank-Read source in any very thin layer. However, the calculations suffer from the drawback that elasticity theory is being used at such short range from the dislocations that it is not strictly valid. In this paper the issues in strengthening of multilayer systems are defined within a simple analytical model. Additionally, a parametric approach using the atomistic embedded atom method (EAM), is developed to study, dislocation-interface interactions in metallic multilayers. Preliminary results of the atomistic calculations verify that Koehler strengthening is significant especially when the lamellae are very thin. For thicker lamellae the lattice parameter mismatch effects, which have been modelled within continuum theory, contribute increasingly to the strength. In Cu-Ni, the peak in the yield stress occurs when single dislocations must overcome both barriers. The yield stress drops in thicker lamellae as pile ups of increasing length form in the lamellae, finally conforming to the Hall-Petch equation.


Author(s):  
K. L. Merkle

The atomic structures of internal interfaces have recently received considerable attention, not only because of their importance in determining many materials properties, but also because the atomic structure of many interfaces has become accessible to direct atomic-scale observation by modem HREM instruments. In this communication, several interface structures are examined by HREM in terms of their structural periodicities along the interface.It is well known that heterophase boundaries are generally formed by two low-index planes. Often, as is the case in many fcc metal/metal and metal/metal-oxide systems, low energy boundaries form in the cube-on-cube orientation on (111). Since the lattice parameter ratio between the two materials generally is not a rational number, such boundaries are incommensurate. Therefore, even though periodic arrays of misfit dislocations have been observed by TEM techniques for numerous heterophase systems, such interfaces are quasiperiodic on an atomic scale. Interfaces with misfit dislocations are semicoherent, where atomically well-matched regions alternate with regions of misfit. When the misfit is large, misfit localization is often difficult to detect, and direct determination of the atomic structure of the interface from HREM alone, may not be possible.


Metals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1036
Author(s):  
Eduardo Colin García ◽  
Alejandro Cruz Ramírez ◽  
Guillermo Reyes Castellanos ◽  
José Federico Chávez Alcalá ◽  
Jaime Téllez Ramírez ◽  
...  

Ductile iron camshafts low alloyed with 0.2 and 0.3 wt % vanadium were produced by one of the largest manufacturers of the ductile iron camshafts in México “ARBOMEX S.A de C.V” by a phenolic urethane no-bake sand mold casting method. During functioning, camshafts are subject to bending and torsional stresses, and the lobe surfaces are highly loaded. Thus, high toughness and wear resistance are essential for this component. In this work, two austempering ductile iron heat treatments were evaluated to increase the mechanical properties of tensile strength, hardness, and toughness of the ductile iron camshaft low alloyed with vanadium. The austempering process was held at 265 and 305 °C and austempering times of 30, 60, 90, and 120 min. The volume fraction of high-carbon austenite was determined for the heat treatment conditions by XRD measurements. The ausferritic matrix was determined in 90 min for both austempering temperatures, having a good agreement with the microstructural and hardness evolution as the austempering time increased. The mechanical properties of tensile strength, hardness, and toughness were evaluated from samples obtained from the camshaft and the standard Keel block. The highest mechanical properties were obtained for the austempering heat treatment of 265 °C for 90 min for the ADI containing 0.3 wt % V. The tensile and yield strength were 1200 and 1051 MPa, respectively, while the hardness and the energy impact values were of 47 HRC and 26 J; these values are in the range expected for an ADI grade 3.


2006 ◽  
Vol 510-511 ◽  
pp. 358-361
Author(s):  
Won Yong Kim ◽  
Han Sol Kim ◽  
In Dong Yeo ◽  
Mok Soon Kim

We report on advanced Ni3Al based high temperature structural alloys with refractory alloying elements such as Zr and Mo to be apllied in the fields of die-casting and high temperature press forming as die materials. The duplex microstructure consisting of L12 structured Ni3Al phase and Ni5Zr intermetallic dispersoids was observed to display the microstructural feature for the present alloys investigated. Depending on alloying elements, the volume fraction of 2nd phase was measured to be different, indicating a difference in solid solubility of alloying elements in the matrix γ’ phase. Lattice parameter of matrix phase increased with increasing content of alloying elements. In the higher temperature region more than 973K, the present alloys appeared to show their higher strength compared to those obtained in conventional superalloys. On the basis of experimental results obtained, it is suggested that refractory alloying elements have an effective role to improve the high temperature strength in terms of enhanced thermal stability and solid solution hardening.


2011 ◽  
Vol 145 ◽  
pp. 1-5 ◽  
Author(s):  
K.W. Neoh ◽  
Kim Yeow Tshai ◽  
P.S. Khiew ◽  
Chin Hua Chia

Extensive environmental concern associated with the disposal of solid plastic wastes has stirred tremendous interest in the production and use of sustainable biodegradable polymers. Among the vast variety of available materials, Polylactic Acid (PLA) standout as the most commercially viable mass produced resin to date. However, its low thermal and mechanical stability, excessive brittleness, and relatively higher cost have led to numerous research efforts in producing biodegradable polymer composite filled with natural organic fibers. This paper describes the preparation and the mechanical characteristics of a compression molded biodegradable composite made entirely of renewable raw materials. The composites were reinforced with pulverized palm, kenaf and alkali (1M NaOH:fiber in ratio 2:1) treated kenaf fibers, at a fiber mass proportion of 20 to 60% blended PLA and processed in a custom-built compression mold. SEM microscan revealed that the kenaf fiber has a mean diameter of 40μm, length 1236.6μm, and aspect ratio of 31 while the measured values for palm fiber was 58.7μm, 1041.2μm, and 17.7, respectively. All resulting composites showed significant enhancement in tensile strength. At 20, 40 and 60% fiber loading, the palm/PLA composite recorded tensile strength increment of 46.9, 47.8 and 36.6%, respectively. For the kenaf/PLA composite, greatest improvement was achieved at 40% fiber loading with alkali treated kenaf, with approximately 54% higher than the neat PLA while only 12.6% was recorded for the non-treated kenaf/PLA composite, signifying that the surface modification greatly improved fiber-matrix adhesion. SEM observations on the fracture surface showed similar findings. Compared to commercially available palm/Polypropylene (palm/PP) composite at 50% fiber loading, our measured tensile strength for the PLA composite loaded with 40% alkali treated kenaf fiber was still about 20% lower. Further enhancement in the mechanical characteristic of the kenaf/PLA composite is required to push for its wider utilization in the polymer industry.


2005 ◽  
Vol 101-102 ◽  
pp. 123-130 ◽  
Author(s):  
Lyudmila N. Paritskaya ◽  
Yuri S. Kaganovsky ◽  
V.V. Bogdanov

The phenomenon of low-temperature homogenization (LTH) during interdiffusion is studied under condition a t Dv £ 2 / 1 ) ( (Dv is the bulk diffusion coefficient, a is the lattice parameter) using nano-objects of binary Cu-Ni and Cr-Ni systems compacted from nano-powders and produced by mechanical alloying. Two stages of LTH were detected: at the first stage (t £ 103 s) the volume fraction of solution rapidly grows; at the second stage (t > 103 s) the volume fraction of solutions grows slowly with practically constant average solution concentration. The first stage of LTH correlates with active grain growth caused by small size (l) of structural element and nonequilibrium structure of nano-objects. Obtained results are analyzed theoretically in terms of interdiffusion along migrating GBs due to grain growth at the first stage and DIGM mechanism at the second stage. It is shown that the GB concentration distribution during interdiffusion along migrating GBs and the kinetics of LTH depend on a parameter l/l where 2 / 1 ) / ( b b V sD d l= is the characteristic diffusion length. The mechanisms and criteria of LTH are proposed.


2016 ◽  
Vol 838-839 ◽  
pp. 546-551
Author(s):  
Junya Kobayashi ◽  
Yumenori Nakashima ◽  
Koh Ichi Sugimoto ◽  
Goroh Itoh

The substitution of Si with Al in 0.2%C-1.5%Si-1.25%Mn-0.2%Cr ultrahigh strength transformation-induced plasticity (TRIP)-aided martensitic (TM) sheet steel improves galvanization. The effect of Al content on the microstructure and formabilities of the TM steel was therefore investigated. Replacement of Si with Al maintained the high volume fraction of the retained austenite and the high stretch-formability and stretch-flangeability, whereas it decreased the tensile strength. Complex addition of Si and Al yielded the best formabilities with 1.5 GPa tensile strength grade. The superior formabilities of Si-Al bearing TM steel were attributed to the strain-induced transformation of the metastable retained austenite and the relatively soft lath-martensite structure matrix. The former leads to plastic relaxation of the localized stress concentrations, thus suppressing void formation.


Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 906
Author(s):  
Dong Han ◽  
Yongqing Zhao ◽  
Weidong Zeng

The present study focuses on the effect of 1% Zr addition on the microstructure, tensile properties and superplasticity of a forged SP700 alloy. The results demonstrated that Zr has a significant effect on inhibiting the microstructural segregation and increasing the volume fraction of β-phase in the forged SP700 alloy. After annealing at 820 °C for 1 h and aging at 500 °C for 6 h, the SP700 alloy with 1% Zr showed a completely globular and fine microstructure. The yield strength, ultimate tensile strength and tensile elongation of the alloy with optimized microstructure were 1185 MPa, 1296 MPa and 10%, respectively. The superplastic deformation was performed at 750 °C with an elongation of 1248%. The improvement of tensile properties and superplasticity of the forged SP700 alloy by Zr addition was mainly attributed to the uniform and fine globular microstructures.


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