X-ray Absorption Spectroscopy study of lithium insertion mechanism in Li1.2V3O8

2002 ◽  
Vol 756 ◽  
Author(s):  
N. Bourgeon ◽  
J. Gaubicher ◽  
D. Guyomard ◽  
G. Ouvrard

ABSTRACTX-ray absorption spectroscopy (XAS) measurements were performed to thoroughly understand lithium insertion mechanism in Li1.2V3O8. The evolution of the absorption pre-edge and edge corresponding to the local environment of the vanadium in the bulk has been examined by ex-si tu XAS measurement at the vanadium K edge, during the first discharge-charge cycle. The results show a regular and reversible evolution of the pre-edge intensity, the edge position and the vanadium environment toward nearly perfect VO6 octahedra.

2002 ◽  
Vol 47 (19) ◽  
pp. 3171-3178 ◽  
Author(s):  
A Ibarra-Palos ◽  
P Strobel ◽  
O Proux ◽  
J.L Hazemann ◽  
M Anne ◽  
...  

2008 ◽  
Vol 354 (52-54) ◽  
pp. 5542-5546 ◽  
Author(s):  
Dong Qiu ◽  
Robert M. Moss ◽  
Dave M. Pickup ◽  
Ifty Ahmed ◽  
Jonathan C. Knowles ◽  
...  

1986 ◽  
Vol 47 (C8) ◽  
pp. C8-237-C8-242 ◽  
Author(s):  
B. S. CLAUSEN ◽  
B. LENGELER ◽  
B. S. RASMUSSEN ◽  
W. NIEMANN ◽  
H. TOPSØE

2013 ◽  
Vol 204 ◽  
pp. 257-265 ◽  
Author(s):  
Natkrita Prasoetsopha ◽  
Supree Pinitsoontorn ◽  
Atipong Bootchanont ◽  
Pinit Kidkhunthod ◽  
Pornjuk Srepusharawoot ◽  
...  

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