Frequency Agile Optical Filters using Nanoscopic Polymer Dispersed Liquid Crystals

2001 ◽  
Vol 709 ◽  
Author(s):  
Keith Lewis ◽  
Gilbert Smith ◽  
Ian Mason ◽  
Kate Rochester

ABSTRACTThe ability to realise frequency agile filters has always been a major goal of materials and device scientists. Polymer dispersed liquid crystal materials (PDLCs), in which the droplets are deliberately produced with dimensions smaller than the Rayleigh limit for optical scatter, provide a means of realising this goal. At visible wavelengths the material has the appearance of a phase-homogeneous medium both with and without applied electric field. Refractive indices are an average of those of the liquid crystal and those of its host and can be described on the basis of effective medium approximations using orientationally averaged values for the randomly aligned LC material for the ambient state. On application of electric field, the individual liquid crystal molecules align with a resulting reduction in the effective index of the medium. Extensive studies of the variation of process parameters and their effect on the morphology of the composite have enabled field induced changes in refractive index in excess of 0.05 to be achieved without recourse to the use of polarisers and with little or no hysteresis effects. At wavelengths associated with WDM devices for telecommunication applications, the degree of scatter loss is negligible. Design trade-offs have been assessed for candidate tunable WDM filters based on resonant cavity devices.

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 732
Author(s):  
Anna P. Gardymova ◽  
Mikhail N. Krakhalev ◽  
Victor Ya. Zyryanov ◽  
Alexandra A. Gruzdenko ◽  
Andrey A. Alekseev ◽  
...  

The electro-optical properties of polymer dispersed liquid crystal (PDLC) films are highly dependent on the features of the contained liquid crystal (LC) droplets. Cholesteric LC droplets with homeotropic boundaries can form several topologically different orientational structures, including ones with single and more point defects, layer-like, and axisymmetric twisted toroidal structures. These structures are very sensitive to an applied electric field. In this work, we have demonstrated experimentally and by computer simulations that twisted toroidal droplets reveal strong structural response to the electric field. In turn, this leads to vivid changes in the optical texture in crossed polarizers. The response of droplets of different sizes were found to be equivalent in terms of dimensionless parameters. In addition, the explanation of this phenomenon showed a comparison of theoretical and experimental structural response curves aids to determine the shape of the droplet. Finally, we demonstrated that the addition of a dichroic dye allows such films to be used as optical filters with adjustable color even without polarizers.


1999 ◽  
Vol 559 ◽  
Author(s):  
L. V. Natarajan ◽  
R. L. Sutherland ◽  
V. P. Tondiglia ◽  
S. Siwecki ◽  
R. Pogue ◽  
...  

ABSTRACTElectrically switchable volume reflection holograms were written by inhomogeneous illumination of a prepolymer syrup containing a nematic liquid crystal and a multifunctional acrylate monomer. Switchable holograms are diffractive optics structures and the diffraction efficiency can be controlled by the application of an electric field. Reflection gratings with grating spacing varying between 0.16-0.27 µm were made during the phase separation of liquid crystals from the fast curing prepolymer syrup. The reflection efficiency of the holograms were electrically modulated with the applied field of ∼10-15V/µm. Real time study of the grating formation revealed that the maximum efficiency is reached in ∼15 seconds. The shrinkage of the host polymer during grating formation resulted in the blue shift of the reflection notch. The response time of the grating in an electric field is ∼50 µs. Low voltage scanning electron microscope studies showed the presence of discrete nematic droplet domains of sizes 30-60 nm in liquid crystal rich region.


Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3725
Author(s):  
Jorge Francés ◽  
Sergio Bleda ◽  
Daniel Puerto ◽  
Sergi Gallego ◽  
Andrés Márquez ◽  
...  

This work presents recent results derived from the rigorous modelling of holographic polymer-dispersed liquid crystal (H-PDLC) gratings. More precisely, the diffractive properties of transmission gratings are the focus of this research. This work extends previous analysis performed by the authors but includes new features and approaches. More precisely, full 3D numerical modelling was carried out in all analyses. Each H-PDLC sample was generated randomly by a set of ellipsoid geometry-based LC droplets. The liquid crystal (LC) director inside each droplet was computed by the minimisation of the Frank elastic free energy as a function of the applied electric field. The analysis carried out considered the effects of Frank elastic constants K11, K22 and K33; the anchoring strength W0; and even the saddle-splay constant K24. The external electric field induced an orientation of the LC director, modifying the optical anisotropy of the optical media. This effect was analysed using the 3D split-field finite-difference time-domain (SF-FDTD) method. In order to reduce the computational costs due to a full 3D tensorial analysis, a highly optimised method for high-performance computing solutions (HPC) was developed. The influences of the anchoring and voltage on the diffraction efficiencies were investigated, showing the potential of this approach.


2021 ◽  
Vol 2070 (1) ◽  
pp. 012038
Author(s):  
Vandna Sharma ◽  
Pankaj Kumar

Abstract The alignment of liquid crystal inside the droplets highly influences the electro-optical behaviour of polymer dispersed liquid crystals (PDLCs). In PDLCs with initial transparent state, LC droplets exhibit homeotropic boundary conditions with darker zone at the centre with ring shaped boundary. In the present work, the textures were observed under parallel and crossed polarizers. The captured information revealed that there are no changes in the central zone of the droplets due to the perfect homeotropic alignment of liquid crystals inside the droplet. The count of the droplets with different ranges was measured using ImageJ software. Further, the effect of electric field on textural variation inside the droplets, measuring the ratio of the size of darker zone to the size of droplet (a/d) was analysed by applying image processing. The response curve was obtained for different range of sizes of droplets from the plot of a/d ratio vs applied voltage and found supportive to the measure of the textural variation inside the LC droplets. Therefore, the a/d ratio can be the valuable parameter for optimizing the parameters such as droplet size, area of darker zone and required voltage for energy efficient PDLC devices.


2012 ◽  
Vol 584 ◽  
pp. 531-535 ◽  
Author(s):  
Rajendra Deshmukh ◽  
Sanmesh Parab ◽  
Manoj Malik

The effect on the electrical characteristics of poly (methyl methacrylate) (PMMA) and poly (methyl methacrylate – co – butyl acrylate) (PMMABA) containing liquid crystal (E8) as dispersed material, is investigated in terms of electro optical and dielectric relaxation spectroscopy (DRS) technique. This polymer dispersed liquid crystal (PDLC) composite film is sandwiched between two glass slides with a transparent conductive substrate such as indium tin oxide (ITO). The resulting assembly forms an electro-sensitive material that can be switched from a OFF state to a ON state by the application of an external electric field or thermal ramp. In the present investigation PMMA / E8, PMMABA / E8 and PMMA+PMMABA / E8 composite films of 30/70 wt / wt % were prepared by Solution Induced Phase Separation (SIPS) method. Morphological study showed that homogeneous LC phase is embedded in a spongy – like polymer matrix. Electro optical behavior was determined under the condition of an externally applied AC electric field (0-200Vp-p, 50-1000Hz). DRS has been carried out in the frequency range from 20 Hz to 20 MHz and over the temperature range from 24°C to 75°C.The interfacial charge layer effect and qualitative evaluation of distribution of relaxation time is characterized by Cole-Cole model.


Polymers ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 325 ◽  
Author(s):  
Sandra Fenoll ◽  
Francisco Brocal ◽  
José David Segura ◽  
Manuel Ortuño ◽  
Augusto Beléndez ◽  
...  

A holographic polymer dispersed liquid crystal (HPDLC) is used to record holographic diffraction gratings. Several mixtures of nematic liquid crystals (LC) are used as components of the HPDLC to evaluate their influence in static and dynamic basic properties. The diffraction efficiency obtained in the reconstruction of the holograms is evaluated to compare the influence of the different LC. Additionally, the samples are exposed to a variable electric field and the diffracted light intensity as a function of the applied voltage is measured to evaluate the influence of the LC. The results obtained show significant differences depending on the LC incorporated to the photopolymer.


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