Image Sensor Arrays with Organic Photoconductors

2001 ◽  
Vol 665 ◽  
Author(s):  
R. A. Street ◽  
J. Graham ◽  
Z. Popovic ◽  
A. Hor ◽  
M. Mulato ◽  
...  

ABSTRACTTwo-dimensional image sensor arrays incorporating an organic light sensor are reported, with potential application to digital cameras and x-ray imaging. The 512×512 element array has pixel size of 100 micron, and operates with active matrix addressing using amorphous silicon thin film transistors. The array design allows the use of a continuous layer of the organic sensor material without the need for pixel-level patterning. The sensor is a bilayer comprising a thin generator layer and a thicker hole transport layer. Generator materials benzimidazole perylene (BZP) and hydroxy gallium phthalocyanine (HOGaPc) have been studied, with a tetraphenyldiamine (TPD) transport layer. Both sensors give excellent imaging properties with low leakage current, good charge collection and high spatial resolution.

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Luis Lanzetta ◽  
Thomas Webb ◽  
Nourdine Zibouche ◽  
Xinxing Liang ◽  
Dong Ding ◽  
...  

AbstractTin perovskites have emerged as promising alternatives to toxic lead perovskites in next-generation photovoltaics, but their poor environmental stability remains an obstacle towards more competitive performances. Therefore, a full understanding of their decomposition processes is needed to address these stability issues. Herein, we elucidate the degradation mechanism of 2D/3D tin perovskite films based on (PEA)0.2(FA)0.8SnI3 (where PEA is phenylethylammonium and FA is formamidinium). We show that SnI4, a product of the oxygen-induced degradation of tin perovskite, quickly evolves into iodine via the combined action of moisture and oxygen. We identify iodine as a highly aggressive species that can further oxidise the perovskite to more SnI4, establishing a cyclic degradation mechanism. Perovskite stability is then observed to strongly depend on the hole transport layer chosen as the substrate, which is exploited to tackle film degradation. These key insights will enable the future design and optimisation of stable tin-based perovskite optoelectronics.


Author(s):  
Samed Halilov ◽  
Merid Belayneh ◽  
Md Anower Hossain ◽  
Bram Hoex ◽  
Amir Abdallah ◽  
...  

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