Technical Basis for Codisposal of Gasification and Combustion Ash from the Plants at Beulah, North Dakota

1985 ◽  
Vol 65 ◽  
Author(s):  
G. J. McCarthy ◽  
D. J. Hassett ◽  
O. E. Manz ◽  
G. H. Groenewold ◽  
R. J. Stevenson ◽  
...  

ABSTRACTThe technical hasis for codisposal of gasification ash from the Great Plains Gasification Associates plant, combined with cementitious “scrubber ash” and bottom ash from the adjoining Antelope Valley generating station, both located in Beulah, North Dakota, has been explored. Nine blends containing only the ashes and tap water were fabricated into cylinders and tested for compressive strength and other physical properties. A blend having the ash proportions of the two plants was tested for leachability with respect to several regulated and minor elements. Mineralogical characterization by XRD was performed on the individual waste solids and the cured mixes. Most of the blends had compressive strengths greater than 400 psi after 7-day/38 C and 28-day/21 C curing. The 7-day treatment led to better consolidated test cylinders. Leaching behavior, evaluated by the EPA-EP and ASTM tests, was determined for As, Se, B, V, Mo, Ba, Sr, and K. Average fixation factors (the ratio of leaching expected from a weighted average of its components to the actual leaching of the specimen) of 2 to 4 were observed for the 7-day cured specimens and 1 to 2 for the 28-day specimens. Not all elements had reduced leaching in the fabricated specimens; Se and V leaching increased in the fabricated specimens. In addition to ash proportions, curing conditions (T, pH2O, time) and water to solid ratio appear to key parameters in obtaining well-consolidated and lower leachability products. XRD indicated that ettringite and minor calcite were the only crystalline reaction products of the cementitious reactions in the cured codisposal mix.

1985 ◽  
Vol 65 ◽  
Author(s):  
G. J. McCarthy ◽  
O. E. Manz ◽  
R. J. Stevenson ◽  
D. J. Hassett ◽  
G. H. Groenewold

With financial support from utilities and ash brokers*, the Western Fly Ash Research, Development and Data Center was established under the aegis of the North Dakota Mining and Mineral Resources Research Institute in August of 1985. Research will be performed by the two North Dakota universities in Grand Forks and Fargo. The fundamental objective of the Center is to enhance the knowledge base of the properties (chemical, mineralogical and physical) and reactions of the coal by-products (principally fly ash, but including bottom ash and FGD waste) produced in the Midwestern and Great Plains regions of the US. Most of the study specimens will be high-calcium (ASTM Class C) ash derived from low-rank lignite and subbituminous coals mined in North Dakota, Montana and Wyoming, although ash from other regions and coals is also being studied. The enhanced knowledge base should lead to more widespread utilization of these by-products [1,2] or, where this is necessary, to their safe and cost-effective disposal [3].


2006 ◽  
Vol 21 (1) ◽  
pp. 68-73 ◽  
Author(s):  
Eric A. DeVuyst ◽  
Thomas Foissey ◽  
George O. Kegode

AbstractCurrent production practices in the Red River Valley of North Dakota and Minnesota involve use of extensive tillage and/or herbicides to control weeds. Given the erosion potential, environmental concerns associated with herbicides, and herbicide-resistant weeds, alternative cropping systems that mitigate these problems need to be assessed economically. Furthermore, the role that government commodity programs play in the adoption of more ecologically friendly cropping systems needs to be determined. We evaluated 8 years of yield data (1994–2001) from field plots near Fargo, North Dakota, to compare the economics of two alternative cropping systems, reduced-input (RI) and no-till (NT), to a conventional tillage (CT) cropping system. The RI system relies on a more diverse rotation of soybean (SB), spring wheat (SW), sweet clover (SC) and rye, and uses fewer herbicide and fertilizer inputs than CT or NT. Both NT and CT systems rotate SB and SW. We found that CT returns averaged over $47 ha−1more than NT during the study period. Because SC yield data were not available, the economic competitiveness of RI was calculated using break-even yields and returns for SC. Historical SC yields in Cass County, North Dakota were not statistically different from the break-even yields. However, when government program payments were considered, break-even returns for SC increased by about $15 and $18 ha−1and break-even yields by 0.44 and 0.52 MT ha−1for RI to compare with NT and CT, respectively. These results indicate that CT management offers greater economic return than either RI or NT and that government program payments impede adoption of more environmentally friendly cropping systems in the northern Great Plains.


Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5598
Author(s):  
Dongho Jeon ◽  
Woo Sung Yum ◽  
Haemin Song ◽  
Seyoon Yoon ◽  
Younghoon Bae ◽  
...  

This study investigated the use of coal bottom ash (bottom ash) and CaO-CaCl2-activated ground granulated blast furnace slag (GGBFS) binder in the manufacturing of artificial fine aggregates using cold-bonded pelletization. Mixture samples were prepared with varying added contents of bottom ash of varying added contents of bottom ash relative to the weight of the cementless binder (= GGBFS + quicklime (CaO) + calcium chloride (CaCl2)). In the system, the added bottom ash was not simply an inert filler but was dissolved at an early stage. As the ionic concentrations of Ca and Si increased due to dissolved bottom ash, calcium silicate hydrate (C-S-H) formed both earlier and at higher levels, which increased the strength of the earlier stages. However, the added bottom ash did not affect the total quantities of main reaction products, C-S-H and hydrocalumite, in later phases (e.g., 28 days), but simply accelerated the binder reaction until it had occurred for 14 days. After considering both the mechanical strength and the pelletizing formability of all the mixtures, the proportion with 40 relative weight of bottom ash was selected for the manufacturing of pilot samples of aggregates. The produced fine aggregates had a water absorption rate of 9.83% and demonstrated a much smaller amount of heavy metal leaching than the raw bottom ash.


Horticulturae ◽  
2020 ◽  
Vol 6 (1) ◽  
pp. 18 ◽  
Author(s):  
Andrew Aipperspach ◽  
James Hammond ◽  
Harlene Hatterman-Valenti

Experiments were conducted to evaluate the effects of three pruning levels (20, 30 and 40 nodes per vine) and three fruit-zone leaf removal levels (0%, 50%, and 100%) on the yield and fruit quality of Frontenac gris and Marquette wine grapes in a northern production region. The study was conducted at three North Dakota vineyards located near Buffalo, Clifford, and Wahpeton, North Dakota, in 2011 and 2012. Increasing the number of buds retained increased yields and reduced pruning weights in both cultivars. Frontenac gris and Marquette yields were greatest when vines had 50% of the fruit-zone leaves removed due to heavier clusters, suggesting that the 100% fruit-zone leaf removal level was too severe. Individual berries in clusters were also heavier when vines were pruned to retain 40 buds. Frontenac gris fruit quality was similar both years and was not influenced by pruning or leaf removal levels. Marquette fruit total soluble solids content was greater in 2012 due to the warmer and longer growing season. Marquette fruit titratable acidity was lower when 100% of the fruit-zone leaves were removed. These results suggest that for the two cold-hardy hybrid wine grapes used in this study, greater bud retention levels should be investigated. Results also warrant further research into cultivar adaptiveness to northern Great Plains conditions. With further research, it is anticipated that wine grape cultivars and management practices will be identified to produce acceptable yields and fruit quality for commercial wine grape production.


Author(s):  
Bülent Elitok

In this study, 20 Albino mice of the same daily age were used. All the animals were restrained in well-ventilated 50 ml tubes (plus 3 or 4 cm long middle tubes), which were slipped over the tail to restrict movement even more and left undisturbed under an opaque duration of the stress (30 min). After stress procedure was applied in all animals, 20 mice which have same alive weight average and constitute the study material were divided into two groups as control group (CG) (n=10) and study groups (SG) (n=10) for a 21-day treatment period equally and randomly. Normal tap water was added to the CG mice’ drinkers, while the hot spring water that was brought from the source each day as fresh added to SG mice’ drinkers and they were allowed to reach ad libitum. Clinical, hematological and blood biochemical parameters were measures on 1, 7, 14 and 21 days after treatment in all the animals. The results of this study showed that cortisol and glucose levels decreased in stressed mice treated with Süreyya I Hot Spring Water, while ALB, TP, T3 and T4 levels increased and these changes were statistically significant plessthan0.06) when compared to the control group.


2014 ◽  
Vol 128 (2) ◽  
pp. 204
Author(s):  
Paul Hendricks ◽  
Susan Lenard

Range maps for Pygmy Shrew (Sorex hoyi) show a large hiatus over much of the northern Great Plains between the Rocky Mountains and eastern North Dakota. We report a new record of the Pygmy Shrew in northeastern Montana, review previous records for the state and adjacent regions bordering Montana to the north and east, and suggest that the range boundary in the northern Great Plains be redrawn farther south to include all of Montana north of the Missouri River. This is consistent with the known range of the Pygmy Shrew in eastern North Dakota and South Dakota, where the species has been documented only north and east of the Missouri River, although records are still lacking from north of the Missouri River in northwestern North Dakota and adjacent regions of Canada. Pygmy Shrews will probably be found at additional localities in prairie regions of Canada adjacent to Montana, most likely in association with prairie pothole wetlands, river bottom riparian vegetation, and hardwood draws.


Minerals ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 838
Author(s):  
Sebastian Keber ◽  
Thomas Schirmer ◽  
Tobias Elwert ◽  
Daniel Goldmann

Municipal waste incinerator bottom ashes contain copper contents comparable to those of low-grade ores in addition to other valuable metals. While the processing of coarse fractions (>2 mm) is state of the art, the fines with their residual metal content are landfilled. This paper presents the results from a mineralogical characterization of fine fractions from the processing of municipal solid waste incinerator bottom ashes. From the results, possible approaches for a recovery of copper from the fine fraction are derived. Spatially resolved phase analysis reveals that the material contains a very heterogenic mixture of naturally occurring compounds as well as particles of alloys, metals, artificial oxides, and sulfides. The most interesting element to recover is copper. Copper can be found in the form of alloys, simple sulfides (XS), and oxides (XO). During the incineration process, new phases are generated that differ from natural ones and therefore can be called artificial minerals. Additionally, several components are partially altered due to oxidation, especially after the prolonged outside storage of the bottom ash. Crystalline silicate and glass particles are only sporadically enriched in Cu. Based on these results, different processing techniques are discussed. Due to the small particle size distribution and the physical and physico-chemical properties of the particles, flotation seems to be the most promising technique for the enrichment of copper from municipal solid waste incineration bottom ash (MSWI-BA) fine fractions.


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