The Use Of 222Rn as a Flow Path Monitor for Studies of Radionuclide Transport in Fissures

1981 ◽  
Vol 6 ◽  
Author(s):  
J. Hines ◽  
D. Cohen ◽  
S. Fried ◽  
A. M. Friedman
Keyword(s):  
Field Test ◽  
Flow Rate ◽  
Water Solution ◽  
Diffusion Profile ◽  
Breakthrough Curves ◽  
Flow Path ◽  
Radionuclide Transport ◽  
Radionuclide Concentration ◽  
Water Solutions ◽  
Flat Surfaces

ABSTRACTA technique has been developed using 222Rn as a flow path monitor. Its principle advantage over other radiotracers or dyes is that while the Kd of Rn gas in water solution is zero and hence follows the water path, its 210Pb daughter is retained strongly by rock. The immobilized 210Pb is not subject to diffusion, an important consideration in the proposed Nevada Field Test. To evaluate the technique, a series of laboratory scale experiments have been performed. Artificial fissures consisting of glass plates and prepared flat surfaces were coupled to insure well characterized fissures. Water solutions of radiotracer were metered through these fissures and the discharge monitored to produce breakthrough curves as a function of flow rate. The rock surfaces were analysed for radionuclide concentration and the rock sectioned for diffusion profile into the rock.

scholarly journals Control of Humidity in Small Controlled-environment Chambers using Glycerol-Water Solutions

1992 ◽  
Vol 2 (1) ◽  
pp. 52-54 ◽  
Author(s):  
Charles F. Forney ◽  
David G. Brandl
Keyword(s):  
Relative Humidity ◽  
Specific Gravity ◽  
Flow Rate ◽  
Water Solution ◽  
Solution Temperature ◽  
Controlled Environment ◽  
Glycerol Water ◽  
Water Solutions ◽  
Temperature And Pressure ◽  
The Relationship

Solutions of glycerol and water provide a convenient and inexpensive system to control the relative humidity (RH) in small controlled-environment chambers. The relationship between the specific gravity (SG) of a glycerol-water solution and its equilibrium RH is described by the equation SG = [-0.189 (RH) + 19.9]0.0806. Gas can be humidified by bubbling it through jars containing solutions of glycerol-water with the desired equilibrium RH. The effects of flow rate, volume of solution, temperature, and pressure on the equilibrium RH are discussed.

Kinetics and Equilibrium of Radioactive Metal Adsorption onto Sugarcane Bagasse Waste: Comparison of Batch and Column Adsorption Modes

2021 ◽  
Vol 235 (3) ◽  
pp. 281-294
Author(s):  
Abida Kausar ◽  
Haq Nawaz Bhatti ◽  
Munawar Iqbal
Keyword(s):  
Sugarcane Bagasse ◽  
Flow Rate ◽  
Breakthrough Curves ◽  
Quadratic Model ◽  
Waste Biomass ◽  
Initial Concentration ◽  
Bed Height ◽  
Column Adsorption ◽  
Central Composite ◽  
Bagasse Waste

Abstract Sugarcane bagasse waste biomass (SBWB) efficacy for the adsorption of Zr(IV) was investigated in batch and column modes. The process variables i.e. pH 1–4 (A), adsorbent dosage 0.0–0.3 g (B), and Zr(IV) ions initial concentration 25–200 mg/L (C) were studied. The experiments were run under central composite design (CCD) and data was analysed by response surface methodology (RSM) methodology. The factor A, B, C, AB interaction and square factor A2, C2 affected the Zr(IV) ions adsorption onto SBWB. The quadratic model fitted well to the adsorption data with high R2 values. The effect of bed height, flow rate and Zr(IV) ions initial concentration was also studied for column mode adsorption and efficiency was evaluated by breakthrough curves as well as Bed Depth Service and Thomas models. Bed height and Zr(IV) ions initial concentration enhanced the adsorption of capacity of Zr(IV) ions, whereas flow rate reduced the column efficiency.

Exploring chemistry features of favipiravir in octanol/water solutions

2021 ◽  
pp. 1-12
Author(s):  
Halimeh Rajabzadeh ◽  
Ayla Sharafat ◽  
Maryam Abbasi ◽  
Maryam Eslami Gharaati ◽  
Iraj Alipourfard
Keyword(s):  
Density Functional Theory ◽  
Gas Phase ◽  
Partition Coefficients ◽  
Density Functional ◽  
Water Solution ◽  
Peptide Group ◽  
Functional Theory ◽  
Water Solutions ◽  
Group Rotations ◽  
Heterocyclic Structure

Favipiravir (Fav) has become a well-known drug for medication of patients by appearance of COVID-19. Heterocyclic structure and connected peptide group could make changes for Fav yielding different features from those required features. Therefore, it is indeed a challenging task to prepare a Fav compound with specific features of desired function. In this work, existence of eight Fav structures by tautomeric formations and peptide group rotations were obtained using density functional theory (DFT) optimization calculations. Gas phase, octanol solution, and water solution were employed to show impact of solution on features of Fav besides obtaining partition coefficients (LogP) for Fav compounds. Significant impacts of solutions were seen on features of Fav with the obtained LogP order: Fav-7 >  Fav-8 >  Fav-4 >  Fav-3 >  Fav-2 >  Fav-5 >  Fav-1 >  Fav-6. As a consequence, internal changes yielded significant impacts on features of Fav affirming its carful medication of COVID-19 patients.

Effect of Blade Aspiration Slot Configuration on the Aerodynamic Performance of a Highly Loaded Aspirated Compressor Cascade

2017 ◽  
Author(s):  
Longxin Zhang ◽  
Le Cai ◽  
Bao Liu ◽  
Jun Ding ◽  
Songtao Wang
Keyword(s):  
Flow Control ◽  
Flow Rate ◽  
Control Method ◽  
Active Flow Control ◽  
Experimental Studies ◽  
Aerodynamic Performance ◽  
Flow Path ◽  
Compressor Cascade ◽  
Flow Loss ◽  
Highly Loaded

As a promising active flow control method, boundary layer suction (BLS) can be used to enhance the aerodynamic performance of the highly-loaded compressor effectively, and due to this reason, extensive studies have been carried out on it. However, contrast to those abundant studies focusing on the flow control effects of BLS, little attention has been paid on the design method of the aspiration flow path. This work presents a 3-D steady numerical simulation on a highly-loaded aspirated compressor cascade. The aspiration slot is implemented at its best location based on the previous experimental studies and the aspiration flow rate is fix to 1.5% of the inlet massflow. The plenum configuration follows the blade shape and remains unchanged. One-side-aspiration manner is adopted to simplify the aspiration devices. Two critical geometry parameters, slot angle and slot width, are varied to study the effects of blade aspiration slot configuration on the cascade loss, radial distribution of the aspiration flow rate and inner flow structures within the aspiration flow path. Results show that the slot configuration does affect the cascade performance. In comparison with the throughflow performance, it is especially true once the flow loss caused by the aspiration flow path is also taken into account, and higher flow loss will be generated within the aspiration flow path if an inappropriate scheme is adopted. In the present investigation, apart from the cases with larger negative slot angle, a wider slot is more preferable to a narrower one, since it could enhance the aspiration capacity near the endwall regions and lower the dissipation loss within the aspiration flow path. In terms of the slot angle, a larger negative value, i.e., the slot direction more aligned with the incoming flow, is not beneficial to improve the throughflow performance, while concerning the flow loss yield by the aspiration flow path, a proper negative slot angle is always optimal.

Heat Transfer and Pressure Drop in a Converging Pedestal Array With Exit Area Variation

2018 ◽  
Author(s):  
L. W. Soma ◽  
F. E. Ames ◽  
S. Acharya
Keyword(s):  
Heat Transfer ◽  
Pressure Drop ◽  
Flow Rate ◽  
Film Cooling ◽  
Reynolds Numbers ◽  
Flow Path ◽  
Internal Cooling ◽  
Channel Measurements ◽  
Trailing Edge ◽  
Cooling Air

The trailing edge of a vane is one of the most difficult areas to cool due to a narrowing flow path, high external heat transfer rates, and deteriorating external film cooling protection. Converging pedestal arrays are often used as a means to provide internal cooling in this region. The thermally induced stresses in the trailing edge region of these converging arrays have been known to cause failure in the pedestals of conventional solidity arrays. The present paper documents the heat transfer and pressure drop through two high solidity converging rounded diamond pedestal arrays. These arrays have a 45 percent pedestal solidity. One array which was tested has nine rows of pedestals with an exit area in the last row consistent with the convergence. The other array has eight rows with an expanded exit in the last row to enable a higher cooling air flow rate. The expanded exit of the eight row array allows a 30% increase in the coolant flow rate compared with the nine row array for the same pressure drop. Heat transfer levels correlate well based on local Reynolds numbers but fall slightly below non converging arrays. The pressure drop across the array naturally increases toward the trailing edge with the convergence of the flow passage. A portion of the cooling air pressure drop can be attributed to acceleration while a portion can be attributed to flow path losses. Detailed array static pressure measurements provide a means to develop a correlation for the prediction of pressure drop across the cooling channel. Measurements have been acquired over Reynolds numbers based on exit flow conditions and the characteristic pedestal length scale ranging from 5000 to over 70,000.

Breakthrough curves of oil adsorption on novel amorphous carbon thin film

2016 ◽  
Vol 73 (10) ◽  
pp. 2361-2369 ◽  
Author(s):  
M. El-Sayed ◽  
M. Ramzi ◽  
R. Hosny ◽  
M. Fathy ◽  
Th. Abdel Moghny
Keyword(s):  
Thin Film ◽  
Amorphous Carbon ◽  
Flow Rate ◽  
Produced Water ◽  
Breakthrough Curves ◽  
Operating Conditions ◽  
Bed Height ◽  
Carbon Thin Film ◽  
Oil Adsorption ◽  
Amorphous Carbon Thin Film

A novel amorphous carbon thin film (ACTF) was prepared by hydrolyzing wood sawdust and delignificating the residue to obtain cellulose mass that was subjected to react with cobalt silicate nanoparticle as a catalyst under the influence of sudden concentrated sulfuric acid addition at 23 °C. The novel ACTF was obtained in the form of thin films like graphene sheets having winding surface. The prepared ACTF was characterized by Fourier-transform infrared spectrometer, transmission electron microscope (TEM), and Brunauer–Emmett–Teller (BET). The adsorption capacity of ACTF to remove oil from synthetic produced water was evaluated using the incorporation of Thomas and Yoon–Nelson models. The performance study is described through the breakthrough curves concept under relevant operating conditions such as column bed heights (3.8, 5 and 11 mm) and flow rate (0.5, 1 and 1.5 mL.min−1). It was found that the oil uptake mechanism is favoring higher bed height. Also, the highest bed capacity of 700 mg oil/g ACTF was achieved at 5 mm bed height, and 0.5 mL.min−1 flow rate. The results of breakthrough curve for oil adsorption was best described using the Yoon–Nelson model. Finally, the results illustrate that ACTF could be utilized effectively for oil removal from synthetic produced water in a fixed-bed column system.

Analysis of adsorption of heavy metals from water solutions by wood of selected domestic species using X-Ray Fluorescence (XRF)

2020 ◽  
Vol 111 ◽  
pp. 73-82
Author(s):  
Adrianna Balicka ◽  
Jan Szadkowski
Keyword(s):  
Heavy Metals ◽  
Water Solution ◽  
Robinia Pseudoacacia ◽  
Cadmium Nitrate ◽  
X Ray ◽  
Water Solutions ◽  
Domestic Species ◽  
European Aspen ◽  
Robinia Pseudoacacia L ◽  
Standard Solutions

Analysis of adsorption of heavy metals from water solutions by wood of selected domestic species using X-Ray Fluorescence (XRF).The aim of this study was to analyze the absorption of three specific heavy metals from model water solution by wood species from domestic Polish forests. This paper focuses on XRF method to determine metal content in samples. European aspen (Populus tremula L.) and Black locust (Robinia pseudoacacia L.) have been chosen. Firstly, shavings were prepared and soaked with standard solutions of lead (II) nitrate, cadmium nitrate and mercury (II) chloride for 7 days. Then, the material was dried and reduced to ashes using muffle furnace. Finally, content of absorbed metal was marked (XRF) and analyzed with a view to initial contents of metal ions in standard solutions. It was established, that the higher the concentration of mercury in standard solution is, the higher impulse counts is obtained for European aspen. This reversal of the dependence is noticeable for second analyzed species.

scholarly journals Sorption of Ag+ and Cu2+ by Vermiculite in a Fixed-Bed Column: Design, Process Optimization and Dynamics Investigations

2018 ◽  
Vol 8 (11) ◽  
pp. 2221 ◽  
Author(s):  
Olga Długosz ◽  
Marcin Banach
Keyword(s):  
Flow Rate ◽  
Continuous Process ◽  
Fixed Bed ◽  
Copper Ion ◽  
Cost Effective ◽  
Breakthrough Curves ◽  
Fixed Bed Column ◽  
Column System ◽  
Total Percentage ◽  
Bed Height

Vermiculite has been used for the removal of Cu 2 + and Ag + from aqueous solutions in a fixed-bed column system. The effects of initial silver and copper ion concentrations, flow rate, and bed height of the adsorbent in a fixed-bed column system were investigated. Statistical analysis confirmed that breakthrough curves depended on all three factors. The highest inlet metal cation concentration (5000 mg/dm3), the lowest bed height (3 cm) and the lowest flow rate (2 and 3 cm3/min for Ag + and Cu 2 + , respectively) were optimal for the adsorption process. The maximum total percentage of metal ions removed was 60.4% and 68.7% for Ag+ and Cu2+, respectively. Adsorption data were fitted with four fixed-bed adsorption models, namely Clark, Bohart–Adams, Yoon–Nelson and Thomas models, to predict breakthrough curves and to determine the characteristic column parameters. The adsorbent was characterized by SEM, FTIR, EDS and BET techniques. The results showed that vermiculite could be applied as a cost-effective sorbent for the removal of Cu 2 + and Ag + from wastewater in a continuous process.

scholarly journals Effect of Flow Rate and Particle Concentration on the Transport and Deposition of Bare and Stabilized Zero-Valent Iron Nanoparticles in Sandy Soil

2019 ◽  
Vol 11 (23) ◽  
pp. 6608
Author(s):  
Ibrahim ◽  
Awad ◽  
Al-Farraj ◽  
Al-Turki
Keyword(s):  
Flow Rate ◽  
Sandy Soil ◽  
Particle Deposition ◽  
Particle Concentration ◽  
Soil Column ◽  
Relative Concentration ◽  
Methyl Cellulose ◽  
Maximum Flow ◽  
Breakthrough Curves ◽  
Zero Valent Iron

Efficient application of nanoscale zero-valent iron (nZVI) particles in remediation processes relies heavily on the ability to modify the surfaces of nZVI particles to enhance their stability and mobility in subsurface layers. We investigated the effect of sodium carboxy-methyl-cellulose (CMC) polymer stabilizer, pH, particle concentration, and flow rate on the transport of nZVI particles in sand columns. Breakthrough curves (BTCs) of nZVI particles indicated that the transport of nZVI particles was increased by the presence of CMC and by increasing the flow rate. The relative concentration (RC) of the eluted CMC–nZVI nanoparticles was larger at pH 9 as compared to RC at pH 7. This is mainly attributed to the increased nZVI particle stability at higher pH due to the increase in the electrostatic repulsion forces and the formation of larger energy barriers. nZVI particle deposition was larger at 0.1 cm min-1 flow due to the increased residence time, which increases the aggregation and settlement of particles. The amount of CMC–nZVI particles eluted from the sand columns was increased by 52% at the maximum flow rate of 1.0 cm min-1. Bare nZVI were mostly retained in the first millimeters of the soil column, and the amount eluted did not exceed 1.2% of the total amount added. Our results suggest that surface modification of nZVI particles was necessary to increase stability and enhance transport in sandy soil. Nevertheless, a proper flow rate, suitable for the intended remediation efforts, must be considered to minimize nZVI particle deposition and increase remediation efficiency.

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