Magnetic Anisotropy in Rare-Earth - Transition Metal Intermetallic Compounds

1999 ◽  
Vol 577 ◽  
Author(s):  
Nguyen Hoang Luong ◽  
Nguyen Phu Thuy ◽  
Pham Hong Quang ◽  
Pham Duc Thang

ABSTRACTIn this work the rare-earth anisotropy in the rare-earth - transition metal intermetallic compounds is investigated by studying the temperature-induced spin reorientation phenomena on aligned powder samples and by analyzing the temperature dependence of the magnetization measured along different principal axes of single crystals. From such investigations the crystalline-electric-field parameters of the rare-earth ions in these compounds have been derived. The results on different hard magnetic materials of the compositions R2Fe14B, RFe11 and their substituted compounds as well as R2Co17 are summarized.

1970 ◽  
Vol 24 (4) ◽  
pp. 436-445 ◽  
Author(s):  
G. V. Subba Rao ◽  
C. N. R. Rao ◽  
J. R. Ferraro

The electronic and ir spectra of rare earth perovskites of the general formula LnZO3, where Ln is the rare earth ion or yttrium and Z is Cr, Mn, or Fe, have been studied in detail. The results have been discussed in terms of crystallography, magnetic properties, covalency of Ln—O and Z—O bonds, and Goodenough's one electron energy diagrams. In all these compounds the rare earth ions do not markedly affect the electronic transitions of the transition metal ions; the 3 d electrons clearly exhibit localized behavior. Both the electronic and ir spectra of the LnZO3 perovskites are comparable to the spectra of the corresponding transition metal sesquioxides, Z2O3.


1991 ◽  
Vol 44 (5) ◽  
pp. 2182-2189 ◽  
Author(s):  
C. Christides ◽  
M. Anagnostou ◽  
Hong-Shuo Li ◽  
A. Kostikas ◽  
D. Niarchos

ChemInform ◽  
2010 ◽  
Vol 33 (52) ◽  
pp. no-no
Author(s):  
R. J. Radwanski ◽  
R. Michalski ◽  
Z. Ropka ◽  
A. Blaut

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