Bridged Polysilsesquioxanes with Improved Second Order Nonlinear Optical Properties and Stability

1999 ◽  
Vol 561 ◽  
Author(s):  
S. T. Hobson ◽  
J. Zieba ◽  
P. N. Prasad ◽  
K. J. Shea
Keyword(s):  
Spin Coating ◽  
Sol Gel ◽  
Temporal Stability ◽  
Optical Quality ◽  
Efficient Synthesis ◽  
Heating Period ◽  
Poling Field ◽  
Fringe Analysis ◽  
Maker Fringe ◽  
Butanol Solution

ABSTRACTWe report the synthesis and sol-gel polymerization of 4-nitro-N,N-bis[(3- triethoxysilyl)propyl]aniline 1. An efficient synthesis of the monomer was developed by the hydrosilylation of N, N-diallyl-4-nitroaniline. Optical quality thin films were synthesized by spin coating an n-butanol solution of 1 using formic acid as catalyst and source of water. We improved the temporal stability of the NLO signal from films prepared from 4-nitro-N,N-bis[(3-triethoxysilyl)propyl]aniline by increasing the intensity of the poling field and extending the heating period during the poling/curing stage. By Maker fringe analysis, a X(2) value of 9 × 10−8 esu was measured for these polysilsesquioxanes. If one assumes that the major component of the NLO effect is along the z-axis, the X(2) value corresponds to a d33 coefficient of 18.9 pm/V and a r33 value of 4.7 pm/V.

Improved Sol-Gel Materials for Efficient Solid State Dye Lasers

1993 ◽  
Vol 329 ◽  
Author(s):  
Michael Canva ◽  
Patrick Georges ◽  
Jean-Fran^ois Perelgritz ◽  
Alain Brun ◽  
Fréddric Chaput ◽  
...  
Keyword(s):  
Solid State ◽  
Physical Properties ◽  
Room Temperature ◽  
Sol Gel ◽  
Tunable Lasers ◽  
Optical Quality ◽  
Dye Lasers ◽  
Laser Dyes ◽  
Host Matrix ◽  
Host Matrices

AbstractPhotoresistant laser dyes were trapped in silica based xerogel host matrices to obtain solid state tunable lasers. For this purpose very dense xerogel samples with improved chemical and physical properties were prepared at room temperature by the sol-gel technology. The as-prepared materials were polished to obtain optical quality surfaces and were used as new lasing media.Lasing action of such different dyes as rhodamine, perylene and pyrromethene doping dense sol-gel matrices was demonstrated. Efficiencies of 30 % or lifetimes of more than 100,000 shots were achieved with different new ≤dye dopant/host matrix≥ couples. Their different performances are reviewed and discussed.

STRUCTURAL, OPTICAL PROPERTIES AND PHOTOCATALYTIC ACTIVITY OF NANOCRYSTALLINE TiO2 THIN FILMS DEPOSITED BY SOL-GEL SPIN COATING

2019 ◽  
Vol 7 (1) ◽  
pp. 28
Author(s):  
KOMARAIAH DURGAM ◽  
RADHA EPPA ◽  
REDDY M. V. RAMANA ◽  
KUMAR J. SIVA ◽  
R. SAYANNA ◽  
...  
Keyword(s):  
Thin Films ◽  
Optical Properties ◽  
Photocatalytic Activity ◽  
Spin Coating ◽  
Sol Gel ◽  
Tio2 Thin Films ◽  
Nanocrystalline Tio2

Sol-gel growth of Ni doped CdS on glass substrates: effect of spin coating speed and dopant concentration

2020 ◽  
Vol 10 ◽  
Author(s):  
Atefeh Nazari Setayesh ◽  
Hassan Sedghi
Keyword(s):  
Thin Films ◽  
Optical Properties ◽  
Spin Coating ◽  
Optical Band Gap ◽  
Dopant Concentration ◽  
Rotation Speed ◽  
Sol Gel ◽  
Band Gap Energy ◽  
Gap Energy ◽  
Glass Substrates

Background: In this work, CdS thin films were synthesized by sol-gel method (spin coating technique) on glass substrates to investigate the optical behavior of the film. Methods: Different substrate spin coating speeds of 2400, 3000, 3600 rpm and different Ni dopant concentrations of 0 wt.%, 2.5 wt.%, 5 wt.%) were investigated. The optical properties of thin films such as refraction index, extinction coefficient, dielectric constant and optical band gap energy of the layers were discussed using spectroscopic ellipsometry method in the wavelength range of 300 to 900 nm. Results: It can be deduced that substrate rotation speed and dopant concentration has influenced the optical properties of thin films. By decreasing rotation speed of the substrate which results in films with more thicknesses, more optical interferences were appeared in the results. Conclusion: The samples doped with Ni comparing to pure ones have had more optical band gap energy.

Valence state and magnetism of Mn-doped PbPdO 2 nanograin film synthesized by sol-gel spin-coating method

2017 ◽  
Vol 623 ◽  
pp. 14-18 ◽  
Author(s):  
Fenglin Tang ◽  
Chao Mei ◽  
Peiyu Chuang ◽  
Tingting Song ◽  
Hailin Su ◽  
...  
Keyword(s):  
Spin Coating ◽  
Valence State ◽  
Sol Gel ◽  
Spin Coating Method ◽  
Coating Method ◽  
Mn Doped

Mo-doped, Cr-Doped, and Mo–Cr codoped TiO2 thin-film photocatalysts by comparative sol-gel spin coating and ion implantation

2021 ◽  
Vol 46 (24) ◽  
pp. 12961-12980
Author(s):  
Amanda Chen ◽  
Wen-Fan Chen ◽  
Tina Majidi ◽  
Bernadette Pudadera ◽  
Armand Atanacio ◽  
...  
Keyword(s):  
Thin Film ◽  
Ion Implantation ◽  
Spin Coating ◽  
Tio2 Thin Film ◽  
Sol Gel ◽  
Codoped Tio2

Study on the Grain Size of Vanadium Dioxide Thin Films using Sol-gel Spin Coating Method

2018 ◽  
Author(s):  
Ibrahim Mohd Yazid ◽  
Muhammad Hazim Raselan ◽  
Shafinaz Sobihana Shariffudin ◽  
Puteri Sarah Mohamad Saad ◽  
Sukreen Hana ◽  
...  
Keyword(s):  
Thin Films ◽  
Grain Size ◽  
Vanadium Dioxide ◽  
Spin Coating ◽  
Sol Gel ◽  
Spin Coating Method ◽  
Coating Method ◽  
Vanadium Dioxide Thin Films

Acclimating the magnetic behavior of highly (117) oriented Bi4Ti 3-xMnxO12 thin films prepared sol-gel spin coating method

2020 ◽  
Author(s):  
A. Amali Roselin ◽  
N. Anandhan ◽  
I. Joseph Paneer Doss ◽  
G. Gopu ◽  
K. P. Ganesan ◽  
...  
Keyword(s):  
Thin Films ◽  
Spin Coating ◽  
Sol Gel ◽  
Magnetic Behavior ◽  
Spin Coating Method ◽  
Coating Method
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