Effect of Annealing on the Properties of thin Films of Free Base Phthalocyanine and Perylene-3,4,9,10-Tetracarboxylic Dianhydride Deposited by Organic Molecular Beam Deposition

1999 ◽  
Vol 560 ◽  
Author(s):  
S.M. Bayliss ◽  
S. Heutz ◽  
G. Rumbles ◽  
T.S. Jones

ABSTRACTOrganic molecular beam deposition (OMBD) has been used to deposit thin films of free base phthalocyanine (H2Pc) and perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA). The structural, optical and morphological properties of the films have been measured as a function of annealing temperature using x-ray diffraction (XRD), electronic absorption spectroscopy and atomic force microscopy (AFM). A phase transition, (α-β), is observed for H2Pc films which is accompanied by changes in the bulk film properties and surface morphology. In the case of PTCDA increasing temperature does not affect the structural and optical properties of the film, but different surface morphologies are observed.

2000 ◽  
Vol 620 ◽  
Author(s):  
Sandrine Heutz ◽  
Sallie M. Bayliss ◽  
Garry Rumbles ◽  
Tim S. Jones

ABSTRACTFree base phthalocyanine films have been grown on glass substrates by organic molecular beam deposition. In situ post-growth annealing of the samples leads to the α → β1 transformation. Different transition states have been identified and their morphological properties studied by atomic force and optical microscopy. The transition occurs via a discrete number of nucleations and is preceded by an elongation of the α crystallites. The β1 crystallites grow but are confined to domains of similar orientation. Increased thickness produces larger domains and better orientation, while only partial transformation occurs below 94 nm.


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Author(s):  
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S. Takahashi

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