Modelling UO2 and Simfuel Leaching Behaviour in Granite Groundwater Under Oxidizing Conditions

1999 ◽  
Vol 556 ◽  
Author(s):  
J. Quiñones ◽  
J. Garcia Serrano ◽  
J. A. Serrano ◽  
P. Diaz Arocas ◽  
J. L. Rodriguez ◽  
...  
Keyword(s):  
Groundwater Flow ◽  
Source Term ◽  
Solid Phase ◽  
Model Predictions ◽  
Different Types ◽  
Leaching Experiments ◽  
Leaching Behaviour ◽  
Loss Term ◽  
State Concentration ◽  
Good Agreement

AbstractThe Uranium concentration leaching behaviour for UO2 and SIMFUEL in granite groundwater under oxidizing conditions is modelled. The model contemplates two terms: a source term and a loss term. The source term represents the bulk dissolution process and its upper limit is controlled by the solubility of the thermodynamically stable solid phase. The loss term emulates the solute removed due to groundwater flow into the repository. It can forecast the uranium steady state concentration when groundwater flow is considered. The model has been tested with three different types of leaching experiments, performed with UO2 and SIMFUEL. Good agreement between experimental results and model predictions are found.

A possible modification of groundwater flow equation using coordinate transformations

2014 ◽  
Vol 15 (2) ◽  
pp. 278-287 ◽  
Author(s):  
Abdon Atangana ◽  
Ernestine Alabaraoye
Keyword(s):  
Groundwater Flow ◽  
Prolate Spheroid ◽  
Flow Equation ◽  
Time Space ◽  
Adomian Decomposition ◽  
Iteration Methods ◽  
Groundwater Flow Equation ◽  
Factor Α ◽  
Modified Equation ◽  
Good Agreement

We described a groundwater model with prolate spheroid coordinates, and introduced a new parameter, namely τ the silhouette influence of the geometric under which the water flows. At first, we supposed that the silhouette influence approaches zero; under this assumption, the modified equation collapsed to the ordinary groundwater flow equation. We proposed an analytical solution to the standard version of groundwater as a function of time, space and uncertainty factor α. Our proposed solution was in good agreement with experimental data. We presented a good approximation to the exponential integral. We obtained an asymptotic special solution to the modified equation by means of the Adomian decomposition and variational iteration methods.

scholarly journals Constitutive Modeling of the Densification Behavior in Open-Porous Cellular Solids

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2731
Author(s):  
Ameya Rege
Keyword(s):  
Constitutive Model ◽  
Cell Walls ◽  
Compressive Strain ◽  
Pore Collapse ◽  
Compressive Response ◽  
Linear Elastic ◽  
Nonlinear Springs ◽  
Different Types ◽  
Point Of Intersection ◽  
Good Agreement

The macroscopic mechanical behavior of open-porous cellular materials is dictated by the geometric and material properties of their microscopic cell walls. The overall compressive response of such materials is divided into three regimes, namely, the linear elastic, plateau and densification. In this paper, a constitutive model is presented, which captures not only the linear elastic regime and the subsequent pore-collapse, but is also shown to be capable of capturing the hardening upon the densification of the network. Here, the network is considered to be made up of idealized square-shaped cells, whose cell walls undergo bending and buckling under compression. Depending on the choice of damage criterion, viz. elastic buckling or irreversible bending, the cell walls collapse. These collapsed cells are then assumed to behave as nonlinear springs, acting as a foundation to the elastic network of active open cells. To this end, the network is decomposed into an active network and a collapsed one. The compressive strain at the onset of densification is then shown to be quantified by the point of intersection of the two network stress-strain curves. A parameter sensitivity analysis is presented to demonstrate the range of different material characteristics that the model is capable of capturing. The proposed constitutive model is further validated against two different types of nanoporous materials and shows good agreement.

Immunological Determined Plasminogen Groups And Its Possible Biological Relevance

1981 ◽  
Author(s):  
V Sachs ◽  
R Dörner ◽  
E Szirmai
Keyword(s):  
Human Plasma ◽  
Type I ◽  
Type Ii ◽  
Precipitation Line ◽  
Gene Frequencies ◽  
Type Iii ◽  
Different Types ◽  
Human Plasminogen ◽  
Gel Diffusion ◽  
Good Agreement

Anti human plasminogen sera of the rabbit precipitate human plasma in the agar gel diffusion test by means of intra-basin absorption with plasminogenfree human plasma with three different types: type I is represented by one strong precipitation line, type II by two lines, a big one and a small one, and type III by three slight but distinct lines. The following frequencies of the different types have been observed in a sample of 516 human plasmas: type I 65%, type II 33% and type III 2%. Suppose the types are phenotypical groups of a diallelic system where the types I and III represent the homozygous genotypes and the type II the heterozygous the estimated gene frequencies are in good agreement with the expected values. There is also a good agreement of the distribution of plasminogen groups determined by electrofocussing from RAUM et al. and HOBART. The plasminogen groups possibly may have also a biological meaning because the plasmas of type III always have a lesser fibrinolytic activity than the plasmas of the other types.

Optimization of Cold-Formed Channel Sections Using Imperialist Competitive Algorithm

2012 ◽  
Vol 166-169 ◽  
pp. 493-496
Author(s):  
Roya Kohandel ◽  
Behzad Abdi ◽  
Poi Ngian Shek ◽  
M.Md. Tahir ◽  
Ahmad Beng Hong Kueh
Keyword(s):  
Sequential Quadratic Programming ◽  
Optimization Problems ◽  
Imperialist Competitive Algorithm ◽  
Computational Method ◽  
Compression Force ◽  
Sqp Method ◽  
Competitive Algorithm ◽  
Different Types ◽  
Formed Channel ◽  
Good Agreement

The Imperialist Competitive Algorithm (ICA) is a novel computational method based on the concept of socio-political motivated strategy, which is usually used to solve different types of optimization problems. This paper presents the optimization of cold-formed channel section subjected to axial compression force utilizing the ICA method. The results are then compared to the Genetic Algorithm (GA) and Sequential Quadratic Programming (SQP) algorithm for validation purpose. The results obtained from the ICA method is in good agreement with the GA and SQP method in terms of weight but slightly different in the geometry shape.

Predicting the surface waviness of sheet moulding compound parts by simulating process-induced thermal stresses

2011 ◽  
Vol 31 (8-9) ◽  
Author(s):  
Walter Michaeli ◽  
Christoph Kremer
Keyword(s):  
Thermal Stresses ◽  
Surface Defects ◽  
Computation Method ◽  
Surface Waviness ◽  
Curing Reaction ◽  
Calculated Stress ◽  
Moulding Compound ◽  
Different Types ◽  
Sheet Moulding Compound ◽  
Good Agreement

Abstract This paper describes an opportunity to compute the surface waviness of compression moulded sheet moulding compound (SMC) parts by simulating residual stresses. First, different types of surface defects occurring on SMC parts are discussed. A method for calculating the surface waviness of the compression moulded part is presented, which combines the simulation of the production process and the structural computation. Modelling of the curing reaction and the development of mechanical properties are discussed and implemented. The potential of the computation method is shown for an automotive fender made of SMC. The results state that the curing reaction of SMC can be well described using the approach of Ng and Manas-Zloczower. The position of the measured waviness on the examined fender is in good agreement with the calculated stress distribution.

3D Numerical Simulation of Polydisperse Pressurized Gas-Solid Fluidized Bed

2011 ◽  
Author(s):  
P. Fede ◽  
O. Simonin ◽  
I. Ghouila
Keyword(s):  
Numerical Simulation ◽  
Fluidized Bed ◽  
Ethylene Polymerization ◽  
Solid Phase ◽  
Three Dimensional ◽  
Gas Velocity ◽  
Particle Segregation ◽  
3D Numerical Simulation ◽  
Model Predictions ◽  
The Mean

Three dimensional unsteady numerical simulations of dense pressurized polydisperse fluidized bed have been carried out. The geometry is a medium-scale industrial pilot for ethylene polymerization. The numerical simulation have been performed with a polydisperse collision model. The consistency of the polydisperse model predictions with the monodisperse ones is shown. The results show that the pressure distribution and the mean vertical gas velocity are not modified by polydispersion of the solid phase. In contrast, the solid particle species are not identically distributed in the fluidized bed indicating the presence of particle segregation.

Deceleration of sliding motorcycles (mainly scooters) in accident reconstructions

2017 ◽  
Vol 232 (7) ◽  
pp. 866-876 ◽  
Author(s):  
Carlo Cialdai ◽  
Dario Vangi ◽  
Antonio Virga
Keyword(s):  
Urban Areas ◽  
Test Session ◽  
Road Accidents ◽  
Factors Affecting ◽  
Different Types ◽  
Energy Dissipated ◽  
Comparison Of The Results ◽  
Two Wheeler ◽  
The Impact ◽  
Good Agreement

This paper presents an analysis of the situation in which a two-wheeler (i.e. a motorcycle, where the term motorcycles includes scooters) falls over to the side and then successively slides; this typically occurs in road accidents involving this type of vehicle. Knowing the deceleration rate of the sliding phase allows the kinetic energy dissipated and the speed of the motorcycle just before the fall to the ground to be calculated. These parameters are very important in the analysis and reconstruction of accidents. The work presented in this paper was developed in two experimental test sessions on fully faired motorcycles which are mainly of the scooter type and widely used in urban areas. In the first session, sliding tests were carried out, with the speed in the range 10–50 km/h, on three different types of road surface. Analysis of the evidence allowed the dissipative main phases of motion of the motorcycle (the impact with the ground, the rebounds and the stabilized swiping) to be identified and some factors affecting the phenomenon to be studied. The coefficient of average deceleration was calculated using two typical equations. The second test session consisted of drag tests. In these tests, the motorcycle, which had previously laid on its side, was dragged for a few metres at a constant speed of about 20 km/h, while the drag force was measured. A comparison of the results obtained in these tests with those obtained in the sliding tests yielded very good agreement in the coefficients of deceleration.

scholarly journals Statistics of Simulated Storm Waves over Bathymetry

2021 ◽  
Vol 9 (7) ◽  
pp. 784
Author(s):  
Arnida Lailatul Latifah ◽  
Durra Handri ◽  
Ayu Shabrina ◽  
Henokh Hariyanto ◽  
E. van Groesen
Keyword(s):  
Water Waves ◽  
Open Water ◽  
Storm Events ◽  
Extreme Waves ◽  
Marine Structures ◽  
Wave Statistics ◽  
Storm Waves ◽  
Different Types ◽  
Run Up ◽  
Good Agreement

This paper shows simulations of high waves over different bathymetries to collect statistical information, particularly kurtosis and crest exceedance, that quantifies the occurrence of exceptionally extreme waves. This knowledge is especially pertinent for the design and operation of marine structures, safe ship trafficking, and mooring strategies for ships near the coast. Taking advantage of the flexibility to perform numerical simulations with HAWASSI software, with the aim of investigating the physical and statistical properties for these cases, this paper investigates the change in wave statistics related to changes in depth, breaking and differences between long- and short-crested waves. Three different types of bathymetry are considered: run-up to the coast with slope 1/20, waves over a shoal, and deep open-water waves. Simulations show good agreement in the examined cases compared with the available experimental data and simulations. Then predictive simulations for cases with a higher significant wave height illustrate the changes that may occur during storm events.

Rigid-Plastic Impact of Single Angular Particles

2021 ◽  
Author(s):  
Sandeep Dhar
Keyword(s):  
Finite Element ◽  
Finite Element Model ◽  
Element Model ◽  
Orientation Dependence ◽  
Particle Orientation ◽  
Rigid Plastic ◽  
Plastic Model ◽  
Model Predictions ◽  
Good Agreement ◽  
Angular Particles

The trajectory of an angular particle as it cuts a ductile target is, in general, complicated because of its dependence not only on particle shape, but also on particle orientation at the initial instant of impact. This orientation dependence has also made experimental measurement of impact parameters of single angular particles very difficult, resulting in a relatively small amount of available experimental data in the literature. The current work is focused on obtaining measurements of particle kinematics for comparison to rigid plastic model developed by Papini and Spelt. Fundamental mechanisms of material removal are identified, and measurements of rebound parameters and corresponding crater dimensions of single hardened steel particles launched against flat aluminium alloy targets are presented. Also a 2-D finite element model is developed and a dynamic analysis is performed to predict the erosion mechanism. Overall, a good agreement was found among the experimental results, rigid-plastic model predictions and finite element model predictions.

Impact of sulfate on the solubility of Tc(IV) in acidic to hyperalkaline aqueous reducing systems

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Sarah B. Duckworth ◽  
Xavier Gaona ◽  
Alexander Baumann ◽  
Kathy Dardenne ◽  
Jörg Rothe ◽  
...  
Keyword(s):  
Solid Phase ◽  
Correction Factors ◽  
Mixed Salt ◽  
Ph Values ◽  
Reducing Conditions ◽  
Upper Limits ◽  
Salt Systems ◽  
Amorphous Character ◽  
Good Agreement

Abstract The solubility of 99Tc(IV) was investigated from undersaturation conditions in NaCl–Na2SO4 (0.3 M ≤ I ≤ 5.0 M), MgCl2–MgSO4 (I = 13.5 M) and CaCl2–CaSO4 (I = 13.5 M) systems with 0.001 M ≤ [SO4 2−]tot ≤ 1.0 M and 1 ≤ pH m  ≤ 12 (with pH m  = −log[H+], in molal units). Reducing conditions were set by either Sn(II) or Fe(0). Special efforts were dedicated to accurately characterize the correction factors A m required for the determination of pH m from the experimentally measured pH values in the mixed salt systems investigated, with pH m  = pHexp + A m . The combination of (pe + pH m ) measurements with Pourbaix diagrams of Tc suggests that technetium is present in its +IV redox state. This hypothesis is confirmed by XANES, which unambiguously shows the predominance of Tc(IV) both in the aqueous and solid phases of selected solubility samples. XRD and SEM–EDS support the amorphous character of the solid phase controlling the solubility of Tc(IV). EXAFS data confirm the predominance of TcO2(am, hyd) at pH m  > 1.5, whereas the formation of a Tc(IV)–O–Cl solid phase is hinted at lower pHm values in concentrated NaCl–Na2SO4 systems with ≈5 M NaCl. Solubility data collected in sulfate-containing systems are generally in good agreement with previous solubility studies conducted in sulfate-free NaCl, MgCl2 and CaCl2 solutions of analogous ionic strength. Although the complexation of Tc(IV) with sulfate cannot be completely ruled out, these results strongly support that, if occurring, complexation must be weak and has no significant impact on the solubility of Tc(IV) in dilute up to highly saline media. Solubility upper-limits determined in this work can be used for source term estimations including the effect of sulfate in a variety of geochemical conditions relevant in the context of nuclear waste disposal.

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