Optimization of immobilization of strontium and uranium by the solid matrix

1999 ◽  
Vol 556 ◽  
Author(s):  
S. Raicevic ◽  
I. Plecas ◽  
D. I. Lalovic ◽  
V. Veljkovic
Keyword(s):  
Interaction Potential ◽  
Solid Phase ◽  
Solid Matrix ◽  
Physical Parameters ◽  
Phosphate Rocks ◽  
Pseudopotential Theory ◽  
The Matrix ◽  
Impurity System ◽  
Matrix Stability ◽  
The Stability

AbstractOne of the basic physical parameters which defines: (1) the capacity of the solid matrix for the incorporation (sorption) of the impurity and (2) the stability of the solid matrix -impurity system, is the ion-ion interaction potential, representing the main term of the cohesive energy. Using this parameter determined in the frame of the pseudopotential theory and pseudoatomic approximation we have investigated the systems HAP-Sr and HAP-UO2. In analysis, the hydroxyapatite (HAP, Ca10(PO4)6(OH)2) was selected as a model solid matrix since insoluble phosphates, phosphate ceramic and apatite-like materials are candidates for the immobilization of radionuclides. The substitution of calcium atoms by different impurities in HAP can be presented by the formula: Ca10-xMx(PO4)6(OH)2, where 0 ≤ x ≤ 10 and M = Sr2+, UO22+. It has been shown that (1) Sr can be safely immobilized by HAP, natural apatites and phosphate rocks in the whole range of its concentrations, and (2) that HAP is not an appropriate solid-matrix for immobilization of UO22+ because its incorporation in the low concentration results in a decrease of the matrix stability, stimulating formation of the inhomogeneous structure containing isolated clusters of the UO2- apatite solid phase.

scholarly journals Coupled THM and Matrix Stability Modeling of Hydroshearing Stimulation in a Coupled Fracture-Matrix Hot Volcanic System

2018 ◽  
Vol 2018 ◽  
pp. 1-15 ◽  
Author(s):  
Yong Xiao ◽  
Jianchun Guo ◽  
Hehua Wang ◽  
Lize Lu ◽  
John McLennan ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Thermal Conduction ◽  
Dominant Role ◽  
Injection Well ◽  
Time Step ◽  
Volcanic System ◽  
Induced Stress ◽  
The Matrix ◽  
Matrix Stability ◽  
The Stability

A coupled thermal-hydraulic-mechanical (THM) model is developed to simulate the combined effect of fracture fluid flow, heat transfer from the matrix to injected fluid, and shearing dilation behaviors in a coupled fracture-matrix hot volcanic reservoir system. Fluid flows in the fracture are calculated based on the cubic law. Heat transfer within the fracture involved is thermal conduction, thermal advection, and thermal dispersion; within the reservoir matrix, thermal conduction is the only mode of heat transfer. In view of the expansion of the fracture network, deformation and thermal-induced stress model are added to the matrix node’s in situ stress environment in each time step to analyze the stability of the matrix. A series of results from the coupled THM model, induced stress, and matrix stability indicate that thermal-induced aperture plays a dominant role near the injection well to enhance the conductivity of the fracture. Away from the injection well, the conductivity of the fracture is contributed by shear dilation. The induced stress has the maximum value at the injection point; the deformation-induced stress has large value with smaller affected range; on the contrary, thermal-induced stress has small value with larger affected range. Matrix stability simulation results indicate that the stability of the matrix nodes may be destroyed; this mechanism is helpful to create complex fracture networks.

TEM characterization of Au/Polysilicon interactions

1990 ◽  
Vol 48 (4) ◽  
pp. 650-651
Author(s):  
N. David Theodore ◽  
Leslie H. Allen ◽  
C. Barry Carter ◽  
James W. Mayer
Keyword(s):  
Solid Phase ◽  
Single Crystal Silicon ◽  
Chemical Vapor ◽  
Electrical Contacts ◽  
Silicon Substrates ◽  
Crystal Silicon ◽  
Transmission Electron ◽  
Polysilicon Films ◽  
The Stability

Metal/polysilicon investigations contribute to an understanding of issues relevant to the stability of electrical contacts in semiconductor devices. These investigations also contribute to an understanding of Si lateral solid-phase epitactic growth. Metals such as Au, Al and Ag form eutectics with Si. reactions in these metal/polysilicon systems lead to the formation of large-grain silicon. Of these systems, the Al/polysilicon system has been most extensively studied. In this study, the behavior upon thermal annealing of Au/polysilicon bilayers is investigated using cross-section transmission electron microscopy (XTEM). The unique feature of this system is that silicon grain-growth occurs at particularly low temperatures ∽300°C).Gold/polysilicon bilayers were fabricated on thermally oxidized single-crystal silicon substrates. Lowpressure chemical vapor deposition (LPCVD) at 620°C was used to obtain 100 to 400 nm polysilicon films. The surface of the polysilicon was cleaned with a buffered hydrofluoric acid solution. Gold was then thermally evaporated onto the samples.

The influence of the Stokes and Archimedes forces on the stability of a two-phase flow

2003 ◽  
Vol 3 ◽  
pp. 266-270
Author(s):  
B.H. Khudjuyerov ◽  
I.A. Chuliev
Keyword(s):  
Spectral Method ◽  
Stability Region ◽  
Gas Flow ◽  
Two Phase Flow ◽  
Solid Phase ◽  
Stability Characteristic ◽  
Phase Flow ◽  
Two Phase ◽  
The Stability

The problem of the stability of a two-phase flow is considered. The solution of the stability equations is performed by the spectral method using polynomials of Chebyshev. A decrease in the stability region gas flow with the addition of particles of the solid phase. The analysis influence on the stability characteristic of Stokes and Archimedes forces.

scholarly journals Charge Transfer Complexes of Ketotifen with 2,3-Dichloro-5,6-dicyano-p-benzoquinone and 7,7,8,8-Tetracyanoquodimethane: Spectroscopic Characterization Studies

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 2039
Author(s):  
Gamal A. E. Mostafa ◽  
Ahmed Bakheit ◽  
Najla AlMasoud ◽  
Haitham AlRabiah
Keyword(s):  
Charge Transfer ◽  
Spectroscopic Characterization ◽  
Molar Ratio ◽  
Charge Transfer Complexes ◽  
Physical Parameters ◽  
Spectrophotometric Methods ◽  
Theoretical Approaches ◽  
The Stability ◽  
Ct Complexes

The reactions of ketotifen fumarate (KT) with 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) as π acceptors to form charge transfer (CT) complexes were evaluated in this study. Experimental and theoretical approaches, including density function theory (DFT), were used to obtain the comprehensive, reliable, and accurate structure elucidation of the developed CT complexes. The CT complexes (KT-DDQ and KT-TCNQ) were monitored at 485 and 843 nm, respectively, and the calibration curve ranged from 10 to 100 ppm for KT-DDQ and 2.5 to 40 ppm for KT-TCNQ. The spectrophotometric methods were validated for the determination of KT, and the stability of the CT complexes was assessed by studying the corresponding spectroscopic physical parameters. The molar ratio of KT:DDQ and KT:TCNQ was estimated at 1:1 using Job’s method, which was compatible with the results obtained using the Benesi–Hildebrand equation. Using these complexes, the quantitative determination of KT in its dosage form was successful.

scholarly journals Analytical angular solutions for the atom–diatom interaction potential in a basis set of products of two spherical harmonics: two approaches

2021 ◽  
Author(s):  
Mariusz Pawlak ◽  
Marcin Stachowiak
Keyword(s):  
Spherical Harmonics ◽  
Interaction Potential ◽  
Chem Phys ◽  
Basis Set ◽  
Matrix Elements ◽  
Trigonometric Functions ◽  
Variational Theory ◽  
Molecular Collision ◽  
The Matrix ◽  
Analytical Expressions

AbstractWe present general analytical expressions for the matrix elements of the atom–diatom interaction potential, expanded in terms of Legendre polynomials, in a basis set of products of two spherical harmonics, especially significant to the recently developed adiabatic variational theory for cold molecular collision experiments [J. Chem. Phys. 143, 074114 (2015); J. Phys. Chem. A 121, 2194 (2017)]. We used two approaches in our studies. The first involves the evaluation of the integral containing trigonometric functions with arbitrary powers. The second approach is based on the theorem of addition of spherical harmonics.

scholarly journals Numerical simulation of periodic MHD casson nanofluid flow through porous stretching sheet

2021 ◽  
Vol 3 (2) ◽  
Author(s):  
Abdullah Al-Mamun ◽  
S. M. Arifuzzaman ◽  
Sk. Reza-E-Rabbi ◽  
Umme Sara Alam ◽  
Saiful Islam ◽  
...  
Keyword(s):  
Fluid Flow ◽  
Lewis Number ◽  
Stability And Convergence ◽  
Radiation Absorption ◽  
Physical Parameters ◽  
Theoretical Idea ◽  
Prostate Cancer Therapy ◽  
Flow Through ◽  
Explicit Finite Difference ◽  
The Stability

AbstractThe perspective of this paper is to characterize a Casson type of Non-Newtonian fluid flow through heat as well as mass conduction towards a stretching surface with thermophoresis and radiation absorption impacts in association with periodic hydromagnetic effect. Here heat absorption is also integrated with the heat absorbing parameter. A time dependent fundamental set of equations, i.e. momentum, energy and concentration have been established to discuss the fluid flow system. Explicit finite difference technique is occupied here by executing a procedure in Compaq Visual Fortran 6.6a to elucidate the mathematical model of liquid flow. The stability and convergence inspection has been accomplished. It has observed that the present work converged at, Pr ≥ 0.447 indicates the value of Prandtl number and Le ≥ 0.163 indicates the value of Lewis number. Impact of useful physical parameters has been illustrated graphically on various flow fields. It has inspected that the periodic magnetic field has helped to increase the interaction of the nanoparticles in the velocity field significantly. The field has been depicted in a vibrating form which is also done newly in this work. Subsequently, the Lorentz force has also represented a great impact in the updated visualization (streamlines and isotherms) of the flow field. The respective fields appeared with more wave for the larger values of magnetic parameter. These results help to visualize a theoretical idea of the effect of modern electromagnetic induction use in industry instead of traditional energy sources. Moreover, it has a great application in lung and prostate cancer therapy.

Optimization of thermal conductivity in composites loaded with the solid-solid phase-change materials

2018 ◽  
Vol 25 (6) ◽  
pp. 1157-1165
Author(s):  
Taoufik Mnasri ◽  
Adel Abbessi ◽  
Rached Ben Younes ◽  
Atef Mazioud
Keyword(s):  
Thermal Conductivity ◽  
Phase Change ◽  
Phase Change Materials ◽  
Solid Phase ◽  
Spherical Inclusions ◽  
First Case ◽  
The Matrix ◽  
Composite Conductivity ◽  
First Time

AbstractThis work focuses on identifying the thermal conductivity of composites loaded with phase-change materials (PCMs). Three configurations are studied: (1) the PCMs are divided into identical spherical inclusions arranged in one plane, (2) the PCMs are inserted into the matrix as a plate on the level of the same plane of arrangement, and (3) the PCMs are divided into identical spherical inclusions arranged periodically in the whole matrix. The percentage PCM/matrix is fixed for all cases. A comparison among the various situations is made for the first time, thus providing a new idea on how to insert PCMs into composite matrices. The results show that the composite conductivity is the most important consideration in the first case, precisely when the arrangement plane is parallel with the flux and diagonal to the entry face. In the present work, we are interested in exploring the solid-solid PCMs. The PCM polyurethane and a wood matrix are particularly studied.

scholarly journals Stability of Nonlinear Autonomous Quadratic Discrete Systems in the Critical Case

2010 ◽  
Vol 2010 ◽  
pp. 1-23 ◽  
Author(s):  
Josef Diblík ◽  
Denys Ya. Khusainov ◽  
Irina V. Grytsay ◽  
Zdenĕk Šmarda
Keyword(s):  
Lyapunov Functions ◽  
Critical Case ◽  
Autonomous Systems ◽  
Discrete Systems ◽  
Simple Eigenvalue ◽  
Discrete Equations ◽  
The Matrix ◽  
The Stability ◽  
Important Characterization

Many processes are mathematically simulated by systems of discrete equations with quadratic right-hand sides. Their stability is thought of as a very important characterization of the process. In this paper, the method of Lyapunov functions is used to derive classes of stable quadratic discrete autonomous systems in a critical case in the presence of a simple eigenvalueλ=1of the matrix of linear terms. In addition to the stability investigation, we also estimate stability domains.

scholarly journals Determination of 77 Multiclass Pesticides and Their Metabolitesin Capsicum and Tomato Using GC-MS/MS and LC-MS/MS

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 1837
Author(s):  
Harischandra Naik Rathod ◽  
Bheemanna Mallappa ◽  
Pallavi Malenahalli Sidramappa ◽  
Chandra Sekhara Reddy Vennapusa ◽  
Pavankumar Kamin ◽  
...  
Keyword(s):  
Limit Of Detection ◽  
Solid Phase ◽  
Graphitized Carbon Black ◽  
Limit Of Quantification ◽  
Gas And Liquid Chromatography ◽  
Relative Standard ◽  
The Matrix ◽  
Liquid Chromatography Tandem Mass ◽  
Primary Secondary Amine

A quick, sensitive, and reproducible analytical method for the determination of 77 multiclass pesticides and their metabolites in Capsicum and tomato by gas and liquid chromatography tandem mass spectrometry was standardized and validated. The limit of detection of 0.19 to 10.91 and limit of quantification of 0.63 to 36.34 µg·kg−1 for Capsicum and 0.10 to 9.55 µg·kg−1 (LOD) and 0.35 to 33.43 µg·kg−1 (LOQ) for tomato. The method involves extraction of sample with acetonitrile, purification by dispersive solid phase extraction using primary secondary amine and graphitized carbon black. The recoveries of all pesticides were in the range of 75 to 110% with a relative standard deviation of less than 20%. Similarly, the method precision was evaluated interms of repeatability (RSDr) and reproducibility (RSDwR) by spiking of mixed pesticides standards at 100 µg·kg−1 recorded anRSD of less than 20%. The matrix effect was acceptable and no significant variation was observed in both the matrices except for few pesticides. The estimated measurement uncertainty found acceptable for all the pesticides. This method found suitable for analysis of vegetable samples drawn from market and farm gates.

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