Metal / Silicon Multilayers Produced by Low-Temperature MOCVD

1998 ◽  
Vol 555 ◽  
Author(s):  
F. Hamelmann ◽  
G. Haindl ◽  
A. Klipp ◽  
E. Majkova ◽  
U. Kleineberg ◽  
...  
Keyword(s):  
Low Temperature ◽  
Substrate Temperature ◽  
Layer Thickness ◽  
Silicon Substrates ◽  
Remote Plasma ◽  
Reflectivity Measurement ◽  
X Ray ◽  
Excellent Growth ◽  
Metal Layers

AbstractW/Si and Mo/Si multilayers with 20 periods (doublelayer spacing d = 24nm) were deposited on silicon substrates using (remote-) plasma-enhanced MOCVD. The substrate temperature was below 200°C, which is necessary to avoid interdiffusion of the layers. The layer thickness and growth was controlled by an in situ soft x-ray reflectivity measurement. The characterisation of the multilayers showed an excellent growth of the silicon layers, while the metal layers are rough with embedded crystallites.

Dimethyl-, Disilyl- and Digermylsulfide: Different Intermolecular Contacts in the Solid State

2004 ◽  
Vol 59 (6) ◽  
pp. 635-638 ◽  
Author(s):  
Norbert W. Mitzel ◽  
Udo Losehand
Keyword(s):  
Solid State ◽  
Low Temperature ◽  
Crystal Structures ◽  
X Ray Diffraction ◽  
X Ray ◽  
Intermolecular Contacts

The compounds (H3C)2S, (H3Si)2S and (H3Ge)2S have been crystallised in situ on a diffractometer and their crystal structures determined by low-temperature X-ray diffraction. The molecules are present as monomers in the crystals. The aggregation of the molecules through secondary intermolecular contacts in the crystal is different: (H3C)2S is weakly associated into dimers by S···S contacts, whereas (H3Si)2S and (H3Ge)2S form Si···S and Ge···S contacts in an ice-analogous aggregation motif. Important geometry parameters are (H3C)2S: C-S 1.794(av) Å , C-S-C 99.2(1)°; (H3Si)2S: Si- S 2.143(1) Å , Si-S-Si 98.4°; (H3Ge)2S Ge-S 2.223(2) and 2.230(2) Å , Ge-S-Ge 98.2(1)◦.

Low-temperature Si in-situ cleaning and homoepitaxy by remote plasma-enhanced chemical vapor deposition

1990 ◽  
Author(s):  
Ting-Chen Hsu ◽  
Brian G. Anthony ◽  
Louis H. Breaux ◽  
Rong Z. Qian ◽  
Sanjay K. Banerjee ◽  
...  
Keyword(s):  
Chemical Vapor Deposition ◽  
Low Temperature ◽  
Vapor Deposition ◽  
Chemical Vapor ◽  
Remote Plasma

Backbone Phosphonamide-Functionalized Imidazol-2-ylidene Complexes

2016 ◽  
Vol 69 (10) ◽  
pp. 1186
Author(s):  
Paresh Kumar Majhi ◽  
Gregor Schnakenburg ◽  
Anthony J. Arduengo ◽  
Rainer Streubel
Keyword(s):  
Low Temperature ◽  
Single Crystal ◽  
X Ray ◽  
Structure Determinations

The synthesis of M(CO)5 complexes bearing 4-phosphonamide and 4,5-bis(phosphonamide)-imidazol-2-ylidene ligands (NHCP = phosphonamide-based N-heterocyclic carbene) is reported. Deprotonation of respective imidazolium hydrogensulfate salts with potassium tert-butoxide (KOtBu) in the presence of [M(CO)5(CH3CN)] afforded complexes with the formula [M(CO)5(NHCP)]. In a similar fashion, reaction of in situ generated NHCP with [Rh(cod)Cl]2 (cod = 1,5-cyclooctadiene) afforded a complex with the formula [Rh(cod)Cl(NHCP)]. Low-temperature deprotonation of the imidazolium NHCP·H2SO4 with potassium hexamethyldisilazide (KHMDS) in the presence of [AuCl(SMe2)] furnished the corresponding AuI NHC complex. All complexes were characterized by various spectroscopic and spectrometric methods. In addition, further structural confirmation is provided by key single-crystal X-ray structure determinations for three of the new complexes.

High-pressure developments for resonant X-ray scattering experiments at I16

2020 ◽  
Vol 27 (2) ◽  
pp. 351-359
Author(s):  
I. Povedano ◽  
A. Bombardi ◽  
D. G. Porter ◽  
M. Burt ◽  
S. Green ◽  
...  
Keyword(s):  
High Pressure ◽  
Low Temperature ◽  
The Body ◽  
X Ray ◽  
X Ray Scattering ◽  
Scattering Geometry ◽  
Diamond Anvil ◽  
Membrane Cell ◽  
Ray Scattering

An experimental setup to perform high-pressure resonant X-ray scattering (RXS) experiments at low temperature on I16 at Diamond Light Source is presented. The setup consists of a membrane-driven diamond anvil cell, a panoramic dome and an optical system that allows pressure to be measured in situ using the ruby fluorescence method. The membrane cell, inspired by the Merrill–Bassett design, presents an asymmetric layout in order to operate in a back-scattering geometry, with a panoramic aperture of 100° in the top and a bottom half dedicated to the regulation and measurement of pressure. It is specially designed to be mounted on the cold finger of a 4 K closed-cycle cryostat and actuated at low-temperature by pumping helium into the gas membrane. The main parts of the body are machined from a CuBe alloy (BERYLCO 25) and, when assembled, it presents an approximate height of 20–21 mm and fits into a 57 mm diameter. This system allows different materials to be probed using RXS in a range of temperatures between 30 and 300 K and has been tested up to 20 GPa using anvils with a culet diameter of 500 µm under quasi-cryogenic conditions. Detailed descriptions of different parts of the setup, operation and the developed methodology are provided here, along with some preliminary experimental results.

Epitaxial Co-Cu Superlattices

1991 ◽  
Vol 231 ◽  
Author(s):  
Elizabeth Schuler ◽  
Sezai Elagoz ◽  
William Vavra ◽  
Frank Lamelas ◽  
Hui David He ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Molecular Beam Epitaxy ◽  
Layer Thickness ◽  
Molecular Beam ◽  
Antiferromagnetic Coupling ◽  
Competing Interactions ◽  
X Ray ◽  
X Ray Scattering ◽  
Complex Spin

AbstractWe describe measurements on the magnetic properties of Co-Cu superlattices in which the Co layer thickness was fixed at 20 Å and the Cu thickness was varied from 4 Å to 24 Å. The samples were grown on Ge-buffered (110) GaAs by molecular beam epitaxy. X-ray scattering and in-situ RHEED indicate that the multilayers are oriented in the (111) direction with the Co layers stacked in an fcc arrangement. Our interest in this series of samples lies in their unusual hysteresis curves which show distinct transitions. We have found that the appearance of these transitions is directly related to the Cu thickness, indicating the presence of complex spin configurations as a consequence of competing interactions. The results are not consistent with a simple RKKY antiferromagnetic coupling.

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