Synthesis and Characterization of Nickel and Manganese Vanadium Oxides

1998 ◽  
Vol 548 ◽  
Author(s):  
Fan Zhang ◽  
Peter Zavalij ◽  
M. Stanley Whittingham
Keyword(s):  
Electron Microprobe ◽  
Electrochemical Behavior ◽  
Vanadium Oxides ◽  
Synthesis And Characterization ◽  
Monoclinic Structure ◽  
Hydrothermal Reactions ◽  
Lithium Cells

ABSTRACTWe have synthesized novel nickel and manganese vanadium oxides using the hydrothermal reactions of vanadium(V) pentoxide, Ni(CH3COO)2, and MnSO4 with an organic templating cation at 165°C. The [NH2(CH2)2NH2]2NiV6O14 has a monoclinic structure. It has some disordered V and 0 atoms in the V6014 layer, which appear to be very close to each other with occupation factor around 0.5. The disordered model was decomposed for two ordered configurations, which differ in the stacking of the layers. The (Mn+2)6(Mn+3)l−2/3z(OH)3(1−Z)(VO4)3[(VO4)l−2z(v207)z] (Z≈0. 1) phase has a hexagonal pipe morphology. These compounds were also characterized by electron microprobe, FTIR and TGA. They reacted readily with lithium, and their electrochemical behavior in lithium cells was determined.

Synthesis and Characterization of Manganese Vanadium Oxides as Cathodes in Lithium Batteries

1999 ◽  
Vol 581 ◽  
Author(s):  
Fan Zhang ◽  
Peter Zavalij ◽  
M. Stanley Whittingham
Keyword(s):  
Hydrothermal Method ◽  
Electron Microprobe ◽  
Lithium Batteries ◽  
Electrochemical Behavior ◽  
Vanadium Oxides ◽  
Synthesis And Characterization ◽  
Nano Materials ◽  
Monoclinic Structure ◽  
Hydrothermal Reactions

ABSTRACTOur research on new cathode nano-materials for advanced lithium batteries has focused on the hydrothermal method for synthesis. We have synthesized two novel manganese vanadium oxides using the hydrothermal reactions of vanadium (V) pentoxide, [N(CH3)4]MnO4, and MnSO4 with an organic templating cation at 165°C. The 6-type [N(CH3)4]zMnyV2O5*nH2O has a monoclinic structure, a= 11.66(2)Å, b=3.610(9)Å, c= 13.91(4)Å, β= 108.8(2)°. It has a disordered V2O5 double layer and the Mn and N(CH3)4 ions reside between the layers. The γ-type MnV2O5 is orthorhombic, belongs to the space group Pnma, a=9.7585(2) Å, b=3.5825(l)Å, c= 11.2653(2) Å. These compounds were also characterized by electron microprobe, FTIR and TGA. They reacted readily with lithium, and their electrochemical behavior in lithium cells was determined.

Synthesis and Characterization of Star-Like Copper Oxide (CuO) with Submicrometer Sizes

2012 ◽  
Vol 465 ◽  
pp. 186-191
Author(s):  
Shou Long Gong ◽  
Fang Lin Du
Keyword(s):  
Electron Microscopy ◽  
Synthesis And Characterization ◽  
Simple Liquid ◽  
Liquid Phase Deposition ◽  
Monoclinic Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Scanning Electron

Star-like CuO with submicrometer sizes was fabricated via a simple liquid-phase deposition with the assistant of PVP and Na2MoO4. The as-prepared CuO have been characterized by X-ray diffraction(XRD) and scanning electron microscopy (SEM). The results showed that the as-prepared CuO owned monoclinic structure, the concentrations of PVP, Na2MoO4 and NaOH are very important to the morphology of CuO. The quality of PVP impacts the formation of thin flakes on the skeletons. Meanwhile, the growth of dendritic skeletons was depended on the addition of Na2MoO4, and the effect of NaOH is to control the dimension of CuO structure.

Prospects of Emerging Engineered oxide nanomaterials and their Applications

2016 ◽  
Vol 66 (4) ◽  
pp. 323 ◽  
Author(s):  
Jitendra Gangwar ◽  
Bipin Kumar Gupta ◽  
Avanish Kumar Srivastava
Keyword(s):  
Recent Progress ◽  
State Of The Art ◽  
Vanadium Oxides ◽  
Review Article ◽  
Synthesis And Characterization ◽  
Oxide Materials ◽  
Wide Range ◽  
Fundamental Understanding ◽  
Potential Applications

<p>This review article mainly focused on the recent progress on the synthesis and characterization of emerging artificially engineered nanostructures of oxide materials as well as their potential applications. A fundamental understanding about the state-of-the-art of the synthesis for different size, shape and morphology, which can be tuned to the desired properties of oxide nanomaterials have discussed in details in this review. The present review covers the a wide range of artificially engineered oxide nanomaterials such as cadmium-, cupric-, nickel-, magnesium-, zinc-, titanium-, tin-, aluminium-, and vanadium-oxides and their useful applications in sensors, optical displays, nanofluids and defence.</p>

ChemInform Abstract: SYNTHESIS AND CHARACTERIZATION OF VANADIUM OXIDES AND MAGNETITE CONTAINING OXYGEN-18

1980 ◽  
Vol 11 (33) ◽  
Author(s):  
W. REICHELT ◽  
H. OPPERMANN ◽  
H. WAGNER ◽  
E. I. TERUKOV ◽  
E. WOLF
Keyword(s):  
Vanadium Oxides ◽  
Synthesis And Characterization

ChemInform Abstract: Synthesis and Characterization of Supported Vanadium Oxides by Adsorption of the Acetylacetonate Complex.

ChemInform ◽  
2010 ◽  
Vol 28 (2) ◽  
pp. no-no
Author(s):  
P. VAN DER VOORT ◽  
I. V. BABITCH ◽  
P. J. GROBET ◽  
A. A. VERBERCKMOES ◽  
E. F. VANSANT
Keyword(s):  
Vanadium Oxides ◽  
Synthesis And Characterization ◽  
Acetylacetonate Complex

Hydrothermal Synthesis of Vanadium Oxides

1996 ◽  
Vol 453 ◽  
Author(s):  
Thomas Chirayil ◽  
Peter Zavalij ◽  
M. Stanley Whittingham
Keyword(s):  
Acetic Acid ◽  
Hydrothermal Synthesis ◽  
Critical Factor ◽  
Vanadium Oxides ◽  
Synthesis And Characterization ◽  
Cluster Compound ◽  
Soft Chemistry ◽  
Microwave Hydrothermal ◽  
Reaction Media

AbstractThe pH of the reaction media is a critical factor in the formation of new vanadium oxides with the tetramethylammonium (TMA) ion via the conventional hydrothermal method. New vanadium oxides; TMAV3O7, Li0.6V2−δO4−δ·H2O and Li0.6V2−δO4−δ, TMAV4O10, and two more new vanadium phases with d spacings of 11.5Å and 19.1Å are formed as the pH is varied with acetic acid. The synthesis and characterization of TMAV3O7, a new vanadium oxide with tetramethylammonium ions residing between its layers is discussed. The intercalation of alkylamines, DMSO, and water into Li0.6V2−δO4−δ·H2O is described. Microwave hydrothermal synthesis is a new and alternate soft chemistry technique used to accelerate the synthesis of TMAV4O10. This method also aided in the formation of a new cluster compound, [Li(H2O)4]2TMA(V10O28)·4H2O.

scholarly journals Synthesis and characterization of metal (M = Al or Ga) 2-phosphino(phenolate/benzenethiolate) complexes and their electrochemical behavior in the presence of CO2

2017 ◽  
Vol 16 (4) ◽  
pp. 307-319
Author(s):  
Jessica A. Bruggen ◽  
Keyton D. Feller ◽  
Henry I. Schickel ◽  
Nazym Tuleushova ◽  
Medet Zhukush ◽  
...  
Keyword(s):  
Electrochemical Behavior ◽  
Synthesis And Characterization

Synthesis and characterization of copper(II) complexes containing acetate and N,N-donor ligands, and their electrochemical behavior in dopamine detection

2017 ◽  
Vol 805 ◽  
pp. 60-67 ◽  
Author(s):  
Andrea P. Sandoval-Rojas ◽  
Laura Ibarra ◽  
María Teresa Cortés ◽  
Mario A. Macías ◽  
Leopoldo Suescun ◽  
...  
Keyword(s):  
Electrochemical Behavior ◽  
Donor Ligands ◽  
Synthesis And Characterization ◽  
Dopamine Detection
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