Strength and Fatigue of Modified Sol-Gel Clad Optical Fibers

1998 ◽  
Vol 531 ◽  
Author(s):  
Bolesh J. Skutnik ◽  
M. R Trumbull
Keyword(s):  
Optical Fiber ◽  
Optical Fibers ◽  
Fatigue Behavior ◽  
Sol Gel ◽  
Ambient Air ◽  
Boiling Water ◽  
Static Fatigue ◽  
Ambient Water ◽  
New Type ◽  
First Time

AbstractDynamic and static fatigue results are presented for the first time for a new type of optical fiber, whose modified sol-gel cladding is a fenestrated (micro porous) form of silica. Unjacketed fibers have mean Weibull strengths in bending of 6.5 to 7.6 GPa with Weibull slopes in the 40 to 60 range. The strength decrease with decreasing strain rate is similar for both jacketed and unjacketed fibers. Even the unjacketed fibers tested in ambient water or in boiling water retain a majority of their mean strength, 7.6 GPa (ambient air) versus 6.5 GPa (ambient water) versus 5.5 GPa (boiling water). Exposure to boiling water for 1 hour has no measurable affect on the strength of these fibers. Exposure to boiling water for 8 hours, however, does significantly broaden the low strength end for the unjacketed fiber. The dynamic fatigue and static fatigue parameters in ambient water are substantially the same, ND = 22±2 and Ns 21±4, for the jacketed and unjacketed fibers. Possible mechanisms are discussed to explain the strength and fatigue behavior of these fibers in light of their unique structure.

scholarly journals Novel Gd3+-doped silica-based optical fiber material for dosimetry in proton therapy

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
C. Hoehr ◽  
A. Morana ◽  
O. Duhamel ◽  
B. Capoen ◽  
M. Trinczek ◽  
...  
Keyword(s):  
Optical Fiber ◽  
Optical Fibers ◽  
Proton Therapy ◽  
Bragg Peak ◽  
Light Emission ◽  
Sol Gel ◽  
Fiber Material ◽  
Beam Current ◽  
Strong Luminescence ◽  
The University

Abstract Optical fibers hold promise for accurate dosimetry in small field proton therapy due to their superior spatial resolution and the lack of significant Cerenkov contamination in proton beams. One known drawback for most scintillation detectors is signal quenching in areas of high linear energy transfer, as is the case in the Bragg peak region of a proton beam. In this study, we investigated the potential of innovative optical fiber bulk materials using the sol-gel technique for dosimetry in proton therapy. This type of glass is made of amorphous silica (SiO$${}_{2}$$ 2 ) and is doped with Gd$${}^{3+}$$ 3 + ions and possesses very interesting light emission properties with a luminescence band around 314 nm when exposed to protons. The fibers were manufactured at the University of Lille and tested at the TRIUMF Proton Therapy facility with 8.2–62.9 MeV protons and 2–6 nA of extracted beam current. Dose-rate dependence and quenching were measured and compared to other silica-based fibers also made by sol-gel techniques and doped with Ce$${}^{3+}$$ 3 + and Cu$${}^{+}$$ + . The three fibers present strong luminescence in the UV (Gd) or visible (Cu,Ce) under irradiation, with the emission intensities related directly to the proton flux. In addition, the 0.5 mm diameter Gd$${}^{3+}$$ 3 + -doped fiber shows superior resolution of the Bragg peak, indicating significantly reduced quenching in comparison to the Ce$${}^{3+}$$ 3 + and Cu$${}^{+}$$ + fibers with a Birks’ constant, k$${}_{B}$$ B , of (0.0162 $$\pm $$ ± 0.0003) cm/MeV in comparison to (0.0333 $$\pm $$ ± 0.0006) cm/MeV and (0.0352 $$\pm $$ ± 0.0003) cm/MeV, respectively. To our knowledge, this is the first report of such an interesting k$${}_{B}$$ B for a silica-based optical fiber material, showing clearly that this fiber presents lower quenching than common plastic scintillators. This result demonstrates the high potential of this inorganic fiber material for proton therapy dosimetry.

Aging of Silica Optical Fiber in Static Fatigue Tests

2016 ◽  
Vol 859 ◽  
pp. 3-8
Author(s):  
Noella Evano ◽  
Rochdi El Abdi ◽  
Marcel Poulain
Keyword(s):  
Optical Fiber ◽  
Optical Fibers ◽  
Fatigue Tests ◽  
Hot Water ◽  
Static Fatigue ◽  
Time To Failure ◽  
Thermal Dependence ◽  
Arrhenius Model ◽  
Bending Stresses ◽  
Silica Optical Fiber

During their use, optical fibers are subject to harsh installation and environmental conditions. To evaluate more precisely the lifetime of an optical fiber, it is necessary to study the mechanical behavior of optical fibers under extreme conditions, in particular under mechanical and thermal stress.This paper presents the results of new silica optical fibers aged in hot water between 20°C and 70°C and subjected to mechanical static bending stresses from 3 GPa to 3.5 GPa. Thermal dependence of the time to failure was observed. This dependence can be described by the Arrhenius model, where the activation energy is one of the main physical characteristic.

Sol-gel derived porous silica as a constituent material for designing optical fiber chemical sensors

2004 ◽  
Vol 828 ◽  
Author(s):  
Shiquan Tao ◽  
Joseph C. Fanguy ◽  
Lina Xu
Keyword(s):  
High Temperature ◽  
Optical Fiber ◽  
Optical Fibers ◽  
Chemical Sensors ◽  
Fiber Optic ◽  
Sol Gel ◽  
Porous Silica ◽  
Fiber Optic Sensor ◽  
Spectrometric Method ◽  
Constituent Material

AbstractSol-gel processes were developed to prepare nano porous silica materials. The obtained porous sol-gel silica (PSGS) materials have been used as constituent materials in designing optical fiber chemical sensors. A PSGS membrane coated on the surface of an optical fiber was used as a transducer for sensing humidity level in air. A PSGS membrane doped with an ammonia indicator dye has been coated on an optical fiber to sense ammonia in air. Both of the coating based sensors are reversible and fast response. In the tested range, relative humidity (RH) in air down to 3% can be detected with the PSGS coated fiber optic sensor. The fiber optic ammonia sensor with ammonia indicator doped PSGS coating can be used to sense ammonia in air down to sub-ppm level. PSGS has also been used as a constituent material in preparing porous silica optical fibers. The obtained porous optical fibers have been used to design optical fiber chemical sensors for sensing humidity, ammonia and volatile organic compounds. A CuCl2 doped PSGS fiber has been tested for sensing ammonia in a high temperature gas sample. Ammonia in the high temperature air gas diffuses into the PSGS fiber, reversibly reacts with CuCl2 doped in the PSGS fiber to form a complex. The formed complex was detected with fiber optic spectrometric method. This sensor can detect ammonia in a high temperature (450 °C) air gas stream down 0.3 ppm. Techniques of preparing PSGS, coating PSGS on an optical fiber, making a porous optical fiber with PSGS as a constituent material will be presented. Examples of optical fiber sensors using PSGS coatings and a PSGS fiber as transducers for gas sensing are presented.

Heating and Burning of Optical Fibers and Cables by Light Scattered from Bubble Train Formed by Optical Fiber Fuse

2012 ◽  
Vol E95.B (8) ◽  
pp. 2638-2641 ◽  
Author(s):  
Makoto YAMADA ◽  
Akisumi TOMOE ◽  
Takahiro KINOSHITA ◽  
Osanori KOYAMA ◽  
Yutaka KATUYAMA ◽  
...  
Keyword(s):  
Optical Fiber ◽  
Optical Fibers

scholarly journals Synthesis of novel adsorbent based on tetrasulfide-functionalized fibrous silica KCC-1 for removal of Hg(II) cations

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Azam Marjani ◽  
Reza Khan Mohammadi
Keyword(s):  
Effective Interaction ◽  
Sol Gel ◽  
Aqueous Media ◽  
Synthesis Method ◽  
Mercury Ions ◽  
Toxic Heavy Metals ◽  
Uptake Capacity ◽  
Hydrothermal Preparation ◽  
Ultrasonic Assisted ◽  
First Time

AbstractHg(II) has been identified to be one of the extremely toxic heavy metals because of its hazardous effects and this fact that it is even more hazardous to animals than other pollutants such as Ag, Au, Cd, Ni, Pb, Co, Cu, and Zn. Accordingly, for the first time, tetrasulfide-functionalized fibrous silica KCC-1 (TS-KCC-1) spheres were synthesized by a facile, conventional ultrasonic-assisted, sol–gel-hydrothermal preparation approach to adsorb Hg(II) from aqueous solution. Tetrasulfide groups (–S–S–S–S–) were chosen as binding sites due to the strong and effective interaction of mercury ions (Hg(II)) with sulfur atoms. Hg(II) uptake onto TS-KCC-1 in a batch system has been carried out. Isotherm and kinetic results showed a very agreed agreement with Langmuir and pseudo-first-order models, respectively, with a Langmuir maximum uptake capacity of 132.55 mg g–1 (volume of the solution = 20.0 mL; adsorbent dose = 5.0 mg; pH = 5.0; temperature: 198 K; contact time = 40 min; shaking speed = 180 rpm). TS-KCC-1was shown to be a promising functional nanoporous material for the uptake of Hg(II) cations from aqueous media. To the best of our knowledge, there has been no report on the uptake of toxic Hg(II) cations by tetrasulfide-functionalized KCC-1 prepared by a conventional ultrasonic-assisted sol–gel-hydrothermal synthesis method.

scholarly journals The Impact of Ambient Atmospheric Mineral-Dust Particles on the Calcification of Lungs

Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 125
Author(s):  
Mariola Jabłońska ◽  
Janusz Janeczek ◽  
Beata Smieja-Król
Keyword(s):  
Mineral Dust ◽  
Smoking Habit ◽  
Lower Lobe ◽  
Ambient Air ◽  
Dust Particles ◽  
Masking Effect ◽  
Amorphous Calcium Carbonate ◽  
Calcium Salts ◽  
The Impact ◽  
First Time

For the first time, it is shown that inhaled ambient air-dust particles settled in the human lower respiratory tract induce lung calcification. Chemical and mineral compositions of pulmonary calcium precipitates in the lung right lower-lobe (RLL) tissues of 12 individuals who lived in the Upper Silesia conurbation in Poland and who had died from causes not related to a lung disorder were determined by transmission and scanning electron microscopy. Whereas calcium salts in lungs are usually reported as phosphates, calcium salts precipitated in the studied RLL tissue were almost exclusively carbonates, specifically Mg-calcite and calcite. These constituted 37% of the 1652 mineral particles examined. Mg-calcite predominated in the submicrometer size range, with a MgCO3 content up to 50 mol %. Magnesium plays a significant role in lung mineralization, a fact so far overlooked. The calcium phosphate (hydroxyapatite) content in the studied RLL tissue was negligible. The predominance of carbonates is explained by the increased CO2 fugacity in the RLL. Carbonates enveloped inhaled mineral-dust particles, including uranium-bearing oxides, quartz, aluminosilicates, and metal sulfides. Three possible pathways for the carbonates precipitation on the dust particles are postulated: (1) precipitation of amorphous calcium carbonate (ACC), followed by its transformation to calcite; (2) precipitation of Mg-ACC, followed by its transformation to Mg-calcite; (3) precipitation of Mg-free ACC, causing a localized relative enrichment in Mg ions and subsequent heterogeneous nucleation and crystal growth of Mg-calcite. The actual number of inhaled dust particles may be significantly greater than was observed because of the masking effect of the carbonate coatings. There is no simple correlation between smoking habit and lung calcification.

A Relationship Between the Factor Indivisibility and the Output Elasticity of the Indivisible Factor

2021 ◽  
pp. 232102222098516
Author(s):  
Dipankar Das
Keyword(s):  
Production Function ◽  
Limit Point ◽  
Mathematical Proof ◽  
Wage Equation ◽  
Marginal Value ◽  
Output Elasticity ◽  
New Type ◽  
First Time ◽  
Jel Classifications

The paper puts forth a notion and derives a special type of production function where labour is an indivisible factor and is in the integer space. Thus, Newtonian calculus is not an appropriate method of deriving the marginal value because limit point does not exist. This shows that indivisibility determines the output elasticity. In the first part, the paper propounds a notion regarding how indivisibility determines curvature of the production function. In the second part, the paper incorporates the findings within a production function and derives a new type accordingly. Moreover, it formally derives the standard wage equation considering all the entitlements of labour, namely (a) normal wages, (b) interest and (c) rent of ability. So far, no such mathematical proof is there to support this wage composition. This paper, for the first time, derives this wage equation considering indivisibility of labour. JEL Classifications: J23, J24, J31, D24, C61, E24, L8

scholarly journals Nano- and Micropatterning on Optical Fibers by Bottom-Up Approach: The Importance of Being Ordered

2021 ◽  
Vol 11 (7) ◽  
pp. 3254
Author(s):  
Marco Pisco ◽  
Francesco Galeotti
Keyword(s):  
Optical Fiber ◽  
Optical Fibers ◽  
Self Assembly ◽  
Ordered Structures ◽  
Bottom Up ◽  
Photonic Structures ◽  
Fiber Technology ◽  
Optical Fiber Probes ◽  
Fiber Probes ◽  
Self Assembled

The realization of advanced optical fiber probes demands the integration of materials and structures on optical fibers with micro- and nanoscale definition. Although researchers often choose complex nanofabrication tools to implement their designs, the migration from proof-of-principle devices to mass production lab-on-fiber devices requires the development of sustainable and reliable technology for cost-effective production. To make it possible, continuous efforts are devoted to applying bottom-up nanofabrication based on self-assembly to decorate the optical fiber with highly ordered photonic structures. The main challenges still pertain to “order” attainment and the limited number of implementable geometries. In this review, we try to shed light on the importance of self-assembled ordered patterns for lab-on-fiber technology. After a brief presentation of the light manipulation possibilities concerned with ordered structures, and of the new prospects offered by aperiodically ordered structures, we briefly recall how the bottom-up approach can be applied to create ordered patterns on the optical fiber. Then, we present un-attempted methodologies, which can enlarge the set of achievable structures, and can potentially improve the yielding rate in finely ordered self-assembled optical fiber probes by eliminating undesired defects and increasing the order by post-processing treatments. Finally, we discuss the available tools to quantify the degree of order in the obtained photonic structures, by suggesting the use of key performance figures of merit in order to systematically evaluate to what extent the pattern is really “ordered”. We hope such a collection of articles and discussion herein could inspire new directions and hint at best practices to fully exploit the benefits inherent to self-organization phenomena leading to ordered systems.

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