Determination of the thermodynamic factor for the B2 FeAl phase from X-ray diffuse scattering data

1998 ◽  
Vol 527 ◽  
Author(s):  
Vlad Liubich ◽  
Simon Dorfman ◽  
David Fuks ◽  
Helmut Mehrert

ABSTRACTThe interdiffusion coefficient is related via the modified Darken equation to the tracer diffusivities of the constituents. The thermodynamic factor Φ entering the Darken equation for the interdiffusion coefficient is expressed in terms of the energy parameters which describe the ordering process in the binary alloy. Our calculations for Fe-Al alloys yield the dependence of Φ on the long-range order parameter. These calculations are performed with the parameters extracted from diffuse X-ray scattering data on FeAl.

2003 ◽  
Vol 799 ◽  
Author(s):  
Rolf Köhler ◽  
Daniil Grigoriev ◽  
Michael Hanke ◽  
Martin Schmidbauer ◽  
Peter Schäfer ◽  
...  

ABSTRACTMulti-fold stacks of In0.6Ga0.4As quantum dots embedded into a GaAs matrix were investigated by means of x-ray diffuse scattering. The measurements were done with synchrotron radiation using different diffraction geometries. Data evaluation was based on comparison with simulated distributions of x-ray diffuse scattering. For the samples under consideration ((001) surface) there is no difference in dot extension along [110] and [-110] and no directional ordering. The measurements easily allow the determination of the average indium amount in the wetting layers. Data evaluation by simulation of x-ray diffuse scattering gives an increase of Incontent from the dot bottom to the dot top.


2007 ◽  
Vol 63 (4) ◽  
pp. 663-673 ◽  
Author(s):  
Lynne H. Thomas ◽  
T. Richard Welberry ◽  
Darren J. Goossens ◽  
Aidan P. Heerdegen ◽  
Matthias J. Gutmann ◽  
...  

Monte Carlo computer simulation has been used to interpret and model observed single-crystal diffuse X-ray scattering data for pentachloronitrobenzene, C6Cl5NO2. Each site in the crystal contains a molecule in one of six different basic orientations with equal probability. However, no short-range order amongst these different orientations has been detected. The strong, detailed and very distinctive diffraction patterns can be accounted for almost entirely on the assumption of random occupancy of each molecular site, but with very large local relaxation displacements that tend to increase the neighbouring distances for contacts involving NO2...NO2 and NO2...Cl with a corresponding reduction for those involving Cl...Cl. The results show that the mean NO2...NO2 distance is increased by ∼ 0.6 Å, compared with that given by the average structure determination.


2012 ◽  
Vol 41 (10) ◽  
pp. 875-890 ◽  
Author(s):  
Frederick A. Heberle ◽  
Jianjun Pan ◽  
Robert F. Standaert ◽  
Paul Drazba ◽  
Norbert Kučerka ◽  
...  

1990 ◽  
Vol 119 (2) ◽  
pp. 159-172 ◽  
Author(s):  
Yu.A. Babanov ◽  
R.Sh. Sadykova ◽  
V.R. Shvetsov ◽  
A.V. Serikov ◽  
A.L. Ageev ◽  
...  

1971 ◽  
Vol 4 (4) ◽  
pp. 317-318 ◽  
Author(s):  
I. Simon

A differential method is presented for the evaluation of small-angle X-ray scattering data. The direct determination of slight changes in the radius of gyration of colloid particles is rendered possible by the method proposed.


1998 ◽  
Vol 258 (1-2) ◽  
pp. 65-68 ◽  
Author(s):  
Vlad Liubich ◽  
Simon Dorfman ◽  
David Fuks ◽  
Helmut Mehrer

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