Measurement of the Temperature Dependence of Silicon Recombination Lifetimes

1998 ◽  
Vol 510 ◽  
Author(s):  
S. Johnston ◽  
R. K. Ahrenkiel

AbstractLifetime spectroscopy is a valuable tool in a number of silicon-based technologies. Currently, lifetime measurement is the most sensitive diagnostic for identification of lowlevel metal impurities in silicon by using the ratio of high-injection to low-injection lifetime. When a single impurity dominates recombination, the lifetime as a function of injection level provides a measure of the defect concentration. Another measurement parameter, that has not been commonly used, is the lifetime as a function of temperature. Temperaturedependent lifetime analysis leads to a better understanding of trapping-delayed recombination rates, trapping and recombination center energy levels and activation energies, temperaturedependent capture cross sections, and surface or grain boundary recombination or trapping effects. A contactless measurement technique has been developed that provides the sample's recombination lifetime over a temperature range from 80 K to 300 K. A sample is coupled to the measurement circuitry that is placed into a Dewar where it is cooled by liquid nitrogen. Lifetimes are then measured as the sample is allowed to warm to room temperature. Data will be shown on these variable-temperature lifetime measurements, which have been made on silicon wafer material ranging from high-quality float-zone-grown wafers to low-cost polycrystalline materials used in photovoltaics.

Processes ◽  
2021 ◽  
Vol 9 (1) ◽  
pp. 115
Author(s):  
Le Quynh Hoa ◽  
Ralph Bäßler ◽  
Dirk Bettge ◽  
Enrico Buggisch ◽  
Bernadette Nicole Schiller ◽  
...  

For reliability and safety issues of injection wells, corrosion resistance of materials used needs to be determined. Herein, representative low-cost materials, including carbon steel X70/1.8977 and low alloyed steel 1.7225, were embedded in mortar to mimic the realistic casing-mortar interface. Two types of cement were investigated: (1) Dyckerhoff Variodur commercial Portland cement, representing a highly acidic resistant cement and (2) Wollastonite, which can react with CO2 and become stable under a CO2 stream due to the carbonation process. Exposure tests were performed under 10 MPa and at 333 K in artificial aquifer fluid for up to 20 weeks, revealing crevice corrosion and uniform corrosion instead of expected pitting corrosion. To clarify the role of cement, simulated pore water was made by dispersing cement powder in aquifer fluid and used as a solution to expose steels. Surface analysis, accompanied by element mapping on exposed specimens and their cross-sections, was carried out to trace the chloride intrusion and corrosion process that followed.


1971 ◽  
Vol 2 ◽  
pp. 503-508
Author(s):  
M. J. Seaton

In the present review I will discuss certain rather general aspects of the theory, and will leave it to other speakers to describe the results of detailed calculations. Further references to recent work are given in the Report of IAU Commission 14.1. Atomic Wave Functions and Energy LevelsIn order to calculate data of importance for ultra-violet and X-ray astronomy - wavelengths, transition probabilities, collision cross-sections, ionization and recombination rates, and line-broadening parameters - it is necessary to begin with the calculation of atomic wave functions. The interest is mainly in highly ionized systems.


Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2091
Author(s):  
Angela Spoială ◽  
Cornelia-Ioana Ilie ◽  
Denisa Ficai ◽  
Anton Ficai ◽  
Ecaterina Andronescu

During the past few years, researchers have focused their attention on developing innovative nanocomposite polymeric membranes with applications in water purification. Natural and synthetic polymers were considered, and it was proven that chitosan-based materials presented important features. This review presents an overview regarding diverse materials used in developing innovative chitosan-based nanocomposite polymeric membranes for water purification. The first part of the review presents a detailed introduction about chitosan, highlighting the fact that is a biocompatible, biodegradable, low-cost, nontoxic biopolymer, having unique structure and interesting properties, and also antibacterial and antioxidant activities, reasons for using it in water treatment applications. To use chitosan-based materials for developing nanocomposite polymeric membranes for wastewater purification applications must enhance their performance by using different materials. In the second part of the review, the performance’s features will be presented as a consequence of adding different nanoparticles, also showing the effect that those nanoparticles could bring on other polymeric membranes. Among these features, pollutant’s retention and enhancing thermo-mechanical properties will be mentioned. The focus of the third section of the review will illustrate chitosan-based nanocomposite as polymeric membranes for water purification. Over the last few years, researchers have demonstrated that adsorbent nanocomposite polymeric membranes are powerful, important, and potential instruments in separation or removal of pollutants, such as heavy metals, dyes, and other toxic compounds presented in water systems. Lastly, we conclude this review with a summary of the most important applications of chitosan-based nanocomposite polymeric membranes and their perspectives in water purification.


2011 ◽  
Vol 301 (4) ◽  
pp. R916-R925 ◽  
Author(s):  
Krystyna Banas ◽  
Charlene Clow ◽  
Bernard J. Jasmin ◽  
Jean-Marc Renaud

It has long been suggested that in skeletal muscle, the ATP-sensitive K+ channel (KATP) channel is important in protecting energy levels and that abolishing its activity causes fiber damage and severely impairs function. The responses to a lack of KATP channel activity vary between muscles and fibers, with the severity of the impairment being the highest in the most glycolytic muscle fibers. Furthermore, glycolytic muscle fibers are also expected to face metabolic stress more often than oxidative ones. The objective of this study was to determine whether the t-tubular KATP channel content differs between muscles and fiber types. KATP channel content was estimated using a semiquantitative immunofluorescence approach by staining cross sections from soleus, extensor digitorum longus (EDL), and flexor digitorum brevis (FDB) muscles with anti-Kir6.2 antibody. Fiber types were determined using serial cross sections stained with specific antimyosin I, IIA, IIB, and IIX antibodies. Changes in Kir6.2 content were compared with changes in CaV1.1 content, as this Ca2+ channel is responsible for triggering Ca2+ release from sarcoplasmic reticulum. The Kir6.2 content was the lowest in the oxidative soleus and the highest in the glycolytic EDL and FDB. At the individual fiber level, the Kir6.2 content within a muscle was in the order of type IIB > IIX > IIA ≥ I. Interestingly, the Kir6.2 content for a given fiber type was significantly different between soleus, EDL, and FDB, and highest in FDB. Correlations of relative fluorescence intensities from the Kir6.2 and CaV1.1 antibodies were significant for all three muscles. However, the variability in content between the three muscles or individual fibers was much greater for Kir6.2 than for CaV1.1. It is suggested that the t-tubular KATP channel content increases as the glycolytic capacity increases and as the oxidative capacity decreases and that the expression of KATP channels may be linked to how often muscles/fibers face metabolic stress.


2015 ◽  
Vol 2015 ◽  
pp. 1-9
Author(s):  
Young-Doo Kwon ◽  
Seong-Hwa Jun ◽  
Ji-Min Song

Most machines and instruments constantly require elastomeric materials like rubber for the purposes of shock absorption, noise attenuation, and sealing. The material properties and accurate lifetime prediction of rubber are closely related to the quality of machines, especially their durability and reliability. The properties of rubber-like elastomers are influenced by ambient conditions, such as temperature, environment, and mechanical load. Moreover, the initial properties of rubber gaskets must be sustained under working conditions to satisfy their required function. Because of its technical merits, as well as its low cost, the highly accelerated life test (HALT) is used by many researchers to predict the long-term lifetime of rubber materials. Methyl vinyl silicone rubber (VMQ) has recently been adopted to improve the lifetime of automobile radiator gaskets. A four-parameter method of determining the recovery ability of the gaskets was recently published, and two revised methods of obtaining the recovery were proposed for polyacrylate (ACM) rubber. The recovery rate curves for VMQ were acquired using the successive zooming genetic algorithm (SZGA). The gasket lifetime for the target recovery (60%) of a compressed gasket was computed somewhat differently depending on the selected regression model.


2013 ◽  
Vol 17 (05) ◽  
pp. 351-358 ◽  
Author(s):  
Mohammad Janghouri ◽  
Ezeddin Mohajerani ◽  
Mostafa M. Amini ◽  
Naser Safari

A method for obtaining red emission from an organic-light emitting diode has been developed by dissolving red and yellow dyes in a common solvent and thermally evaporating the mixture in a single furnace. Dichlorido-bis(5,7-dichloroquinolin-8-olato)tin(IV) complex ( Q2SnCl2 , Q = 5,7-dichloro-8-hydroxyquinoline) has been synthesized for using as a fluorescent material in organic light-emitting diodes (OLEDs). The electronic states HOMO (Highest Occupied Molecular Orbital)/LUMO (Lowest Occupied Molecular Orbital) energy levels explored by means of cyclic voltammetry measurements. A device with fundamental structure of ITO/PEDOT:PSS (55nm)/PVK (90nm)/ Q2SnCl2/Al (180nm) was fabricated and its electroluminescence performance at various thicknesses of light emitting layer (LEL) of Q2SnCl2 is reported. By following this step, an optimal thickness for the doping effect was also identified and explained. Finally a device with fundamental structure of ITO/PEDOT:PSS (55nm)/PVK (90nm)/meso-tetraphenylporphyrin (TPP): Q2SnCl2 (75nm)/ Al (180nm) was fabricated and its electroluminescence performance at various concentrations of dye has been investigated. It is shown that this new method is promising candidate for fabrication of low cost OLEDs at more homogeneous layer.


Nanomaterials ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 2572
Author(s):  
Yanfei Fan ◽  
Yan Liu ◽  
Hongyu Cui ◽  
Wen Wang ◽  
Qiaoyan Shang ◽  
...  

Strontium Titanate has a typical perovskite structure with advantages of low cost and photochemical stability. However, the wide bandgap and rapid recombination of electrons and holes limited its application in photocatalysis. In this work, a SrTiO3 material with surface oxygen vacancies was synthesized via carbon reduction under a high temperature. It was successfully applied for photocatalytic overall water splitting to produce clean hydrogen energy under visible light irradiation without any sacrificial reagent for the first time. The photocatalytic overall water splitting ability of the as-prepared SrTiO3-C950 is attributed to the surface oxygen vacancies that can make suitable energy levels for visible light response, improving the separation and transfer efficiency of photogenerated carriers.


2002 ◽  
Vol 124 (3) ◽  
pp. 205-211 ◽  
Author(s):  
John H. Lau ◽  
S. W. Ricky Lee ◽  
Stephen H. Pan ◽  
Chris Chang

An elasto-plastic-creep analysis of a low-cost micro via-in-pad (VIP) substrate for supporting a solder bumped flip chip in a chip scale package (CSP) format which is soldered onto a printed circuit board (PCB) is presented in this study. Emphasis is placed on the design, materials, and reliability of the micro VIP substrate and of the micro VIP CSP solder joints on PCB. The solder is assumed to obey Norton’s creep law. Cross-sections of samples are examined for a better understanding of the solder bump, CSP substrate redistribution, micro VIP, and solder joint. Also, the thermal cycling test results of the micro VIP CSP PCB assembly is presented.


2015 ◽  
Vol 138 (1) ◽  
Author(s):  
Navaneetha Krishnan Rajan ◽  
Zeying Song ◽  
Kenneth R. Hoffmann ◽  
Marek Belohlavek ◽  
Eileen M. McMahon ◽  
...  

Two-dimensional echocardiography (echo) is the method of choice for noninvasive evaluation of the left ventricle (LV) function owing to its low cost, fast acquisition time, and high temporal resolution. However, it only provides the LV boundaries in discrete 2D planes, and the 3D LV geometry needs to be reconstructed from those planes to quantify LV wall motion, acceleration, and strain, or to carry out flow simulations. An automated method is developed for the reconstruction of the 3D LV endocardial surface using echo from a few standard cross sections, in contrast with the previous work that has used a series of 2D scans in a linear or rotational manner for 3D reconstruction. The concept is based on a generalized approach so that the number or type (long-axis (LA) or short-axis (SA)) of sectional data is not constrained. The location of the cross sections is optimized to minimize the difference between the reconstructed and measured cross sections, and the reconstructed LV surface is meshed in a standard format. Temporal smoothing is implemented to smooth the motion of the LV and the flow rate. This software tool can be used with existing clinical 2D echo systems to reconstruct the 3D LV geometry and motion to quantify the regional akinesis/dyskinesis, 3D strain, acceleration, and velocities, or to be used in ventricular flow simulations.


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