Analysis of Teos Silicon Dioxide: The Identification of Carbonatious Contaminants

1997 ◽  
Vol 500 ◽  
Author(s):  
M. L. Pereira Da Silva ◽  
A. Romanelli Cardoso ◽  
J. J. Santiago-Aviles

ABSTRACTThis work presents the analysis performed on a SiO2 film deposited from organometallic precursors with the aim of correlating their physico-chemical properties including electrical characteristics with processing variables. The characterization tools used in this study included SEM for film homogeneity; SIMS for the determination of total carbon content; FT-MS and Raman scattering spectroscopy for surface characterization. GC-MS was used to understand the electrochemical reactions taking place while performing I-V characteristics measurements.The use of these multiple characterization techniques pointed out to deposited films with reasonable deposition characteristics but poor electrical ones. Phase segregated heterogeneity's rich in carbonatious residues influenced the degradation of the electrical characteristics.

Agronomy ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 1084
Author(s):  
Vittoria Giannini ◽  
Eleonora Peruzzi ◽  
Grazia Masciandaro ◽  
Serena Doni ◽  
Cristina Macci ◽  
...  

In 2013, a pilot experimental field of about 15 ha was set up within the basin of Lake Massaciuccoli (Tuscany, Italy) in order to compare different management strategies—a paludicultural system (PCS), a constructed wetland system (CWS), a nearly-natural wetland system (NWS)—for peatland restoration after almost a century of drainage-based agricultural use (CS). After five years, changes in peat soil quality were investigated from a chemical, biochemical, and ecoenzymatic perspective. The soil in CS was mainly characterized by oxidant conditions, higher content of overall microbial activity, low levels of easily available phosphorus for vegetation, and medium total carbon content ranging from 25.0% to 30.7%. In PCS, the levels of total carbon and the content of bioavailable P were higher, while the oxidant conditions were lower compared to the other systems. As expected, the soils in CWS and NWS were characterized by the most reduced conditions and by the highest levels of arylsulphatase activity. It was noteworthy that soils in the NWS systems were characterized by the highest level of nonavailable P. Outputs from ecoenzymatic activity confirmed the physico-chemical and biochemical results.


2018 ◽  
Vol 122 ◽  
pp. 702-708 ◽  
Author(s):  
S. Sani ◽  
M.U. Kaisan ◽  
D.M. Kulla ◽  
A.I. Obi ◽  
A. Jibrin ◽  
...  

2013 ◽  
Vol 59 (No. 8) ◽  
pp. 372-377 ◽  
Author(s):  
W. Szulc ◽  
B. Rutkowska

The determination of a range of boron concentration in the soil solution, evaluation of the effect of physico-chemical soil properties on boron concentration in the soil solution as well verification whether boron quantity in the soil solution is sufficient for nutritional needs of selected plants cultivated in Poland were comprised. Average boron concentration in the soil solution of Poland&rsquo;s cultivated soils ranges from 0.59 to 5.07 &micro;mol/L and is differentiated by physico-chemical properties of soil. Taking into account decreasing effects of soil properties on the increase of boron concentration in the soil solution, the soil properties can be arranged as follows: organic C &gt;<br />soil abundance in available boron &gt; soil texture &gt; soil pH. The minimum boron quantity observed in the soil solution of Poland&rsquo;s cultivated soils was not sufficient to fulfil nutritional needs of the plants. The maximum boron quantity observed secured nutritional needs of cereals and potatoes but not those of rape plants and sugar beets. Based on the study it can be concluded that the measurement of the concentration of boron in the soil solution can be used in the diagnosis of deficiency of this element for crops.


2020 ◽  
Vol 20 (sup3) ◽  
pp. S1579-S1589
Author(s):  
Dinesh Chandra Naithani ◽  
J.M.S. Rawat ◽  
Bhupendra Singh ◽  
Vinod Prasad Khanduri ◽  
Manoj Kumar Riyal

1972 ◽  
Vol 11 (6) ◽  
pp. 509-511 ◽  
Author(s):  
S. A. Bibinov ◽  
G. T. Dzodziev ◽  
V. K. Vitryanyuk ◽  
V. D. Petrenko

Geoderma ◽  
2014 ◽  
Vol 232-234 ◽  
pp. 381-393 ◽  
Author(s):  
Rong-Jiang Yao ◽  
Jing-Song Yang ◽  
Tong-Juan Zhang ◽  
Peng Gao ◽  
Xiang-Ping Wang ◽  
...  

2016 ◽  
Vol 57 (4) ◽  
pp. 523-532
Author(s):  
Danijela Rajic ◽  
Dragan Toskovic ◽  
Ljubica Vasiljevic ◽  
Zeljko Ostojic

2020 ◽  
Vol 71 (2) ◽  
pp. 121-127
Author(s):  
Antonina Gritco-Todirascu ◽  
Dorina Emilia Creanga ◽  
Liliana Mihaela Ivan ◽  
Dana Ortansa Dorohoi ◽  
Anamaria Ciubara

The present paper is focused on determination of the main parameters of Chlortetracycline. Chlortetracycline belongs to one of the most used family of antibiotics worldwide, Tetracyclines. Because of the large spectrum of infections which can be treated with this category of antibiotics there are attempts to find new derivatives from this class. The compounds derived from the same basic structure exhibit same chemical properties, that is why knowing in detail the main physico-chemical properties of Chlortetracycline could be a real help in synthesize new efficient derivatives. In order to evaluate the reactivity and biological activity HyperChem was used to establish the optimized structure, the electro-optical, the energetic and QSAR parameters. The solvatochromic methods allowed determining the intermolecular interactions types and their contribution to the spectral shifts of measured electronic absorption bands. Based on computational and solvatochromic results, the excited state dipole moment of Chlortetracycline was established by variation method.


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