Diffusivities in Crystalline Rock Materials

1985 ◽  
Vol 50 ◽  
Author(s):  
Kristina Skagius ◽  
Ivars Neretnieks

AbstractThe diffusion of non-sorbing species in different crystalline rocks and fissure coating materials has been studied. The results show that the effective diffusivity of iodide, Uranine and Cr-EDTA in rock materials with fissure coating material is of the same magnitude or higher than in granites and gneisses. The results also show that it is not possible to assign one value to the diffusivity of a rock from a given area. The variations in properties are too large. The estimated effective diffusivity of iodide in rocks without fissure coating material was found to be in the range 1.10-14 m2/s to 70.10-14 m2/s.To simulate the stress that exists in the bedrock at large depths, diffusion experiments with iodide and electrical resistivity measurements in rock materials under mechanical stress have been performed. It was found that the diffusivity in rock samples at 300–350 bars stress was reduced to 20–70% of the value in samples under atmospheric pressure.

1983 ◽  
Vol 26 ◽  
Author(s):  
Kristina Skagius ◽  
Ivars Neretnieks

ABSTRACTThe diffusion of non-sorbing species in different rock materials and fissure coating materials have been studied. The results show that the effective diffusivity of iodide in granites with fissure coating materials is of the same magnitude or higher as the effective diffusivity for iodide in granites without fissure coating material. Also the porosities of the granites with fissure coating material were higher. The effective diffusivity for iodide in rock materials without fissure coating material was determined to be from 1.i0-14 m2/s to about 7.10-13 m2/s.To simulate the stress that exists in the bedrock at large depths diffusion experiments with iodide in rock materials under mechanical stress, and electrical resistivity measurements in salt-water-saturated rock cores under stress have been started. Electrical resistivity measurements is an indirect method to determine the diffusivity.Results from some initial measurements show that the effective diffusivity is reduced to about 40 % of the value for unstressed samples at pressures of 230-280 bar. This is the expected stress at repository depths.


Author(s):  
W. E. King

A side-entry type, helium-temperature specimen stage that has the capability of in-situ electrical-resistivity measurements has been designed and developed for use in the AEI-EM7 1200-kV electron microscope at Argonne National Laboratory. The electrical-resistivity measurements complement the high-voltage electron microscope (HVEM) to yield a unique opportunity to investigate defect production in metals by electron irradiation over a wide range of defect concentrations.A flow cryostat that uses helium gas as a coolant is employed to attain and maintain any specified temperature between 10 and 300 K. The helium gas coolant eliminates the vibrations that arise from boiling liquid helium and the temperature instabilities due to alternating heat-transfer mechanisms in the two-phase temperature regime (4.215 K). Figure 1 shows a schematic view of the liquid/gaseous helium transfer system. A liquid-gas mixture can be used for fast cooldown. The cold tip of the transfer tube is inserted coincident with the tilt axis of the specimen stage, and the end of the coolant flow tube is positioned without contact within the heat exchanger of the copper specimen block (Fig. 2).


1981 ◽  
Vol 11 ◽  
Author(s):  
M.H. Bradbury ◽  
D. Lever ◽  
D. Kinsey

One of the options being considered for the disposal of radioactive waste is deep burial in crystalline rocks such as granite. It is generally recognised that in such rocks groundwater flows mainly through the fracture networks so that these will be the “highways” for the return of radionuclides to the biosphere. The main factors retarding the radionuclide transport have been considered to be the slow water movement in the fissures over the long distances involved together with sorption both in man-made barriers surrounding the waste, and onto rock surfaces and degradation products in the fissures.


1967 ◽  
Vol 6 (47) ◽  
pp. 599-606 ◽  
Author(s):  
Hans Röthlisberger

A brief description of the resistivity method is given, stressing the points which are of particular importance when working on glaciers. The literature is briefly reviewed.


1991 ◽  
Vol 05 (24n25) ◽  
pp. 1635-1638
Author(s):  
S.M. M.R. NAQVI ◽  
A.A. QIDWAI ◽  
S.M. ZIA-UL-HAQUE ◽  
FIROZ AHMAD ◽  
S.D.H. RIZVI ◽  
...  

Bi1.7-Pb0.3-Sr2-Ca2-Cu3-Ox superconducting samples were prepared at 855°C, 862 C, 870 C, and 882 C sintering temperatures respectively. All samples were sintered for 120 hours. The samples were then quenched in liquid nitrogen. The electrical resistivity measurements showed that the samples sintered at 870° C had the best Tc. For these samples the Tc onset was around 120 K and the zero resistance was obtained at 108 K. X-ray diffraction studies showed that the samples were multiphased.


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