A New Polymer Cathode-Conducting Polymer Interconnected With Sulfur-Sulfur Bonds: Poly(2,2'-Dithiodianiline)

1997 ◽  
Vol 496 ◽  
Author(s):  
Katsuhiko Naoi ◽  
Ken-ichi Kawase ◽  
Mitsubiro Mori ◽  
Michiko Komiyama

AbstractPoly(2, 2'-Dithiodianiline)(Poly(DTDA)), a conducting polymer having disulfide bond in it, has been proposed as a new class of high energy storage material. DTDA has one S-S bond interconnected between two moieties of anilines. The structure of the poly(DTDA) was similar to that of polyaniline in addition that the S-S bond is preserved after electropolymerization of DTDA. The poly(DTDA) has some advantages because of its high theoretical energy density, faster kinetics and higher electrical conductivity than other organosulfur cathodes

2009 ◽  
Vol 210 (24) ◽  
pp. 2118-2124 ◽  
Author(s):  
Gengchao Wang ◽  
Xiaofeng Yang ◽  
Yanhua Sun ◽  
Hua Bao ◽  
Xingwei Li

2019 ◽  
Vol 317 ◽  
pp. 746-752 ◽  
Author(s):  
Milica M. Gvozdenović ◽  
Braninir Z. Jugović ◽  
Bojan M. Jokić ◽  
Enis S. Džunuzović ◽  
Braninimir N. Grgur

1999 ◽  
Vol 575 ◽  
Author(s):  
Y. Z. Su ◽  
W. S. Ma ◽  
K. C. Gong

ABSTRACTOrganic disulfide compounds has been proposed as a new class of high-energy storage material. Poly(2,2'-diaminobenzyloxydisulfide), a novel conducting polymer having O-S-S-O bond joined two moieties of anilines, is synthesized both chemically and electrochemically as a new positive storage material. It exhibits conductivity in the region of 10-3 S cm-1 by the fourprobe method and the O-S-S-0 bonds in it are confirmed by Fourie Transform Raman Spectroscopy(FT-RS) and Fourie Transform Infrared Spectroscopy(FT-IR). The poly(2,2'- diaminobenzyloxydisulfide) films are formed by electropolymerization from a AN/THF solution containing 0. IM LiClO4, 0. IM HCl and 0.05 M 2,2'-diaminobenzyloxydisulfide monomer on Pt electrode under continuous cycling between -0.30V and 1.20V vs Ag/AgCl(sat. KCI) at scanning rate 50mv s-1. The cyclic voltammetry shows its electrochemical behaviour is similar to polyaniline. The redox peak current of the cyclic voltammograms increase with increasing of the cyclic numbers.


2019 ◽  
Vol 21 (37) ◽  
pp. 20661-20671 ◽  
Author(s):  
Yingxin Chen ◽  
Yifeng Yue ◽  
Jie Liu ◽  
Jie Shu ◽  
Aiping Liu ◽  
...  

Hierarchical interfaces were successfully established in ferroelectric nanocomposite networks, resulting in high energy density and low loss for capacitor applications.


2020 ◽  
Vol 8 (26) ◽  
pp. 8962-8970 ◽  
Author(s):  
Abdullah Jan ◽  
Hanxing Liu ◽  
Hua Hao ◽  
Zhonghua Yao ◽  
Minghe Cao ◽  
...  

Relaxor-ferroelectric ceramics capacitors have been in the front line of investigations aimed at optimizing energy density due to their high Pmax, suppressed Pr, and high BDS levels, attributed to their highly dynamic polar nano-regions.


2021 ◽  
Vol 14 (2) ◽  
pp. 931-939
Author(s):  
Changkun Zhang ◽  
Zhihui Niu ◽  
Jiwoong Bae ◽  
Leyuan Zhang ◽  
Yu Zhao ◽  
...  

Polyeutectic electrolyte, as a new class of electrolytes, was proposed for various high-energy storage systems.


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