Covalent Silicon Bonding At Room Temperature In Ultrahigh Vacuum

1997 ◽  
Vol 483 ◽  
Author(s):  
Andreas Plöbl ◽  
Heinz Stenzel ◽  
Qin-Yi Tong ◽  
Martin Langenkamp ◽  
Cord Schmidthals ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Room Temperature ◽  
Ultrahigh Vacuum ◽  
Bonding Process ◽  
Ex Situ ◽  
Hydrogen Passivation ◽  
Bulk Silicon ◽  
Chemical Cleaning ◽  
Covalent Bonds ◽  
Subsequent Activation

AbstractOne possibility of a low temperature joining techniques relies on the bonding of atomically clean surfaces. Results on the application of this method to silicon direct bonding are being presented. Clean surfaces for bonding were prepared by ex situ chemical cleaning with ensuing hydrogen passivation and their subsequent activation by thermal desorption of the hydrogen in ultrahigh vacuum (UHV). In UHV at room temperature, the wafers were gently brought into contact to initiate the bonding process. Without any subsequent heat treatment, the adhesive strength thus achieved was equivalent to the cohesion of bulk silicon: covalent bonds join the two crystals.

Phase Transformations in Sol-Gel PZT Thin Films

2000 ◽  
Vol 623 ◽  
Author(s):  
D.P. Eakin ◽  
M.G. Norton ◽  
D.F. Bahr
Keyword(s):  
Thin Films ◽  
Heat Treatment ◽  
Room Temperature ◽  
Structural Changes ◽  
Sol Gel ◽  
Ex Situ ◽  
Ambient Conditions ◽  
Crystalline Films ◽  
In Situ Heating

AbstractThin films of PZT were deposited onto platinized and bare single crystal NaCl using spin coating and sol-gel precursors. These films were then analyzed using in situ heating in a transmission electron microscope. The results of in situ heating are compared with those of an ex situ heat treatment in a standard furnace, mimicking the heat treatment given to entire wafers of these materials for use in MEMS and ferroelectric applications. Films are shown to transform from amorphous to nanocrystalline over the course of days when held at room temperature. While chemical variations are found between films crystallized in ambient conditions and films crystallized in the vacuum conditions of the microscope, the resulting crystal structures appear to be insensitive to these differences. Significant changes in crystal structure are found at 500°C, primarily the change from largely amorphous to the beginnings of clearly crystalline films. Crystallization does occur over the course of weeks at room temperature in these films. Structural changes are more modest in these films when heated in the TEM then those observed on actual wafers. The presence of Pt significantly influences both the resulting structure and morphology in both in situ and ex situ heated films. Without Pt present, the films appear to form small, 10 nm grains consisting of both cubic and tetragonal phases, whereas in the case of the Pt larger, 100 nm grains of a tetragonal phase are formed.

scholarly journals Dual Electrochemical Treatments to Improve Properties of Ti6Al4V Alloy

Materials ◽  
2020 ◽  
Vol 13 (11) ◽  
pp. 2479
Author(s):  
Stefano Rossi ◽  
Luciana Volgare ◽  
Carine Perrin-Pellegrino ◽  
Carine Chassigneux ◽  
Erick Dousset ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Combined Treatment ◽  
Amorphous Film ◽  
Amorphous Layer ◽  
Good Alternative ◽  
Surface Treatments ◽  
Ex Situ ◽  
X Ray Diffraction ◽  
Transmission Electron ◽  
Fluid Environment

Surface treatments are considered as a good alternative to increase biocompatibility and the lifetime of Ti-based alloys used for implants in the human body. The present research reports the comparison of bare and modified Ti6Al4V substrates on hydrophilicity and corrosion resistance properties in body fluid environment at 37 °C. Several surface treatments were conducted separately to obtain either a porous oxide layer using nanostructuration (N) in ethylene glycol containing fluoride solution, or bulk oxide thin films through heat treatment at 450 °C for 3 h (HT), or electrochemical oxidation at 1 V for 3 h (EO), as well as combined treatments (N-HT and N-EO). In-situ X-ray diffraction and ex-situ transmission electron microscopy have shown that heat treatment gave first rise to the formation of a 30 nm thick amorphous layer which crystallized in rutile around 620 °C. Electrochemical oxidations gave rise to a 10 nm thick amorphous film on the top of the surface (EO) or below the amorphous nanotube layer (N-EO). Dual treated samples presented similar results with a more stable behavior for N-EO. Finally, for both corrosion and hydrophilicity points of view, the new combined treatment to get a total amorphous N-EO sample seems to be the best and even better than the partially crystallized N-HT sample.

On the existence of a stable, room temperature dihydride-terminated Ge(100) surface in ultrahigh vacuum

2008 ◽  
Vol 602 (12) ◽  
pp. 2055-2060 ◽  
Author(s):  
Grant Underwood ◽  
Lynette Keller Ballast ◽  
Alan Campion
Keyword(s):  
Room Temperature ◽  
Ultrahigh Vacuum

The Phase Analysis of Panzhihua Vanadic Titanomagnetite Ore before and after Heat Treatment

2013 ◽  
Vol 807-809 ◽  
pp. 2110-2114
Author(s):  
Shu Quan Wan ◽  
De Jun Lan ◽  
Hong Bo Han ◽  
Cai Long Zhou
Keyword(s):  
Heat Treatment ◽  
Phase Analysis ◽  
Room Temperature ◽  
Before And After

The phases of Panzhihua vanadic titanomagnetite ore were studied by using XRF and XRD. XRF results show that the original ore mainly contain the elements, Fe, Ti, Si, Ca, Al, S, Mg, P, Mn, V and etc. XRD results show that the main substances in original ore were Fe3O4 and FeTiO3, and the minor phases cannot be clearly studied by XRD. After heat treatment for 10h at 573K in atmospheric ambient, the phases of the ore have been slightly changed. And after heat treatment for 10h at 1073K in atmospheric ambient, then cooled for 48h to room temperature, the main phases of the ore have almost been changed to Fe2O3 and Fe2TiO5.

Influence of Heat Treatment on Microstructure and Mechanical Properties of Selective Laser Melted TiAl6V4 Alloy

2018 ◽  
Vol 284 ◽  
pp. 615-620 ◽  
Author(s):  
R.M. Baitimerov ◽  
P.A. Lykov ◽  
L.V. Radionova
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Selective Laser Melting ◽  
Room Temperature ◽  
Base Alloy ◽  
Tensile Tests ◽  
Heat Treatments ◽  
Laser Melting ◽  
Microstructure And Mechanical Properties ◽  
Treatment Procedures

TiAl6V4 titanium base alloy is widely used in aerospace and medical industries. Specimens for tensile tests from TiAl6V4 with porosity less than 0.5% was fabricated by selective laser melting (SLM). Specimens were treated using two heat treatment procedures, third batch of specimens was tested in as-fabricated statement after machining. Tensile tests were carried out at room temperature. Microstructure and mechanical properties of SLM fabricated TiAl6V4 after different heat treatments were investigated.

Strength of Commercial Aluminum Alloys after Equal Channel Angular Pressing and Post-ECAP Processing

2006 ◽  
Vol 114 ◽  
pp. 91-96 ◽  
Author(s):  
Maxim Yu. Murashkin ◽  
M.V. Markushev ◽  
Julia Ivanisenko ◽  
Ruslan Valiev
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Tensile Strength ◽  
Aluminum Alloys ◽  
Ultimate Tensile Strength ◽  
Equal Channel Angular Pressing ◽  
Room Temperature ◽  
Solution Treatment ◽  
Ecap Processing ◽  
Angular Pressing

The effects of equal channel angular pressing (ECAP), further heat treatment and rolling on the structure and room temperature mechanical properties of the commercial aluminum alloys 6061 (Al-0.9Mg-0.7Si) and 1560 (Al-6.5Mg-0.6Mn) were investigated. It has been shown that the strength of the alloys after ECAP is higher than that achieved after conventional processing. Prior ECAP solution treatment and post-ECAP ageing can additionally increase the strength of the 6061 alloy. Under optimal ageing conditions a yield strength (YS) of 434 MPa and am ultimate tensile strength (UTS) of 470 MPa were obtained for the alloy. Additional cold rolling leads to a YS and UTS of 475 and 500 MPa with 8% elongation. It was found that the post-ECAP isothermal rolling of the 1560 alloy resulted in the formation of a nano-fibred structure and a tensile strength (YS = 540 MPa and UTS = 635 MPa) that has never previously been observed in commercial non-heat treatable alloys.

Measurement of Copper in p-Type Silicon Using Charge-Carrier Lifetime Methods

2005 ◽  
Vol 108-109 ◽  
pp. 643-648 ◽  
Author(s):  
Marko Yli-Koski ◽  
Hele Savin ◽  
E. Saarnilehto ◽  
Antti Haarahiltunen ◽  
Juha Sinkkonen ◽  
...  
Keyword(s):  
Charge Carrier ◽  
Room Temperature ◽  
Carrier Lifetime ◽  
Detection Sensitivity ◽  
Bulk Silicon ◽  
Recombination Activity ◽  
P Type ◽  
Copper Detection ◽  
Charge Carrier Lifetime

We compare SPV technique with µ−PCD for the determination of recombination activity of copper precipitates in p-Si. The copper precipitates were formed in bulk silicon through illumination at room temperature. We observed that the recombination activities of copper precipitates measured with SPV are higher than the ones measured with µ−PCD technique. However, it seems that the copper detection sensitivity is about the same with SPV and µ−PCD techniques.

Fatigue Behavior of High Manganese TWIP Steels and of Low Alloy Q&P Steels for Car-Body Applications

2014 ◽  
Vol 783-786 ◽  
pp. 713-720
Author(s):  
Paolo Matteis ◽  
Giorgio Scavino ◽  
R. Sesana ◽  
F. D’Aiuto ◽  
Donato Firrao
Keyword(s):  
Heat Treatment ◽  
Room Temperature ◽  
Fatigue Behavior ◽  
Austenitic Steels ◽  
Fracture Mechanisms ◽  
High Manganese ◽  
Cold Forming ◽  
Austenitic Structure ◽  
Plasticity Effect ◽  
Twip Steels

The automotive TWIP steels are high-Mn austenitic steels, with a relevant C content, which exhibit a promising combination of strength and toughness, arising from the ductile austenitic structure, which is strengthened by C, and from the TWIP (TWinning Induced Plasticity) effect. The microstructure of the low-alloy Q&P steels consists of martensite and austenite and is obtained by the Quenching and Partitioning (Q&P) heat treatment, which consists of: austenitizing; quenching to the Tqtemperature, comprised between Msand Mf; soaking at the Tppartitioning temperature (Tpbeing equal to or slightly higher than Tq) to allow carbon to diffuse from martensite to austenite; and quenching to room temperature. The fatigue behavior of these steels is examined both in the as-fabricated condition and after pre-straining and welding operations, which are representative of the cold forming and assembling operations performed to fabricate the car-bodies. Moreover, the microscopic fracture mechanisms are assessed by means of fractographic examinations.

Effect of Hot Processing on Mircrostructure and Properties of Flat Billets of TA15 Titanium Alloy

2021 ◽  
Vol 1016 ◽  
pp. 906-910
Author(s):  
Xin Hua Min ◽  
Cheng Jin
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Titanium Alloy ◽  
High Temperature ◽  
Room Temperature ◽  
High Strength ◽  
Slow Cooling ◽  
Microstructure And Mechanical Properties ◽  
Ta15 Titanium Alloy ◽  
The Ideal

In this paper,effect of the different forging processes on the microstructure and mechanical properties of the flat flat billets of TA15 titanium alloy was investigated.The flat billiets of 80 mm×150 mm×L sizes of TA15 titanium alloy are produced by four different forging processes.Then the different microstrure and properties of the flat billiets were obtained by heat treatment of 800 °C~850 °C×1 h~4h.The results show that, adopting the first forging temperature at T1 °C、slow cooling and the second forging temperature at T2°C 、quick cooling, the primary αphases content is just 10%, and there are lots of thin aciculate phases on the base. This microstructure has both high strength at room temperature and high temperature, while the properties between the cross and lengthwise directions are just the same. So the hot processing of the first forging temperature at T1 °C、slow cooling and the second forging temperature at T2°C 、quick cooling is choosed as the ideal processing for production of aircraft frame parts.

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