Current Transport in W and WSIX Ohmic Contacts to Ingan and Inn

1997 ◽  
Vol 468 ◽  
Author(s):  
C. B. Vartuli ◽  
S. J. Pearton ◽  
C. R. Abernathy ◽  
J. D. MacKenzie ◽  
M. L. Lovejoy ◽  
...  
Keyword(s):  
Room Temperature ◽  
Ohmic Contacts ◽  
Conduction Mechanism ◽  
Specific Resistance ◽  
Thermionic Emission ◽  
Contact Structures ◽  
Specific Contact Resistance ◽  
Current Transport ◽  
Deposited Metal ◽  
Specific Contact

ABSTRACTThe temperature dependence of the specific contact resistance of W and WSi0.44 contacts on n+ In0.55Ga0.35N and InN was measured in the range -50 °C to 125 °C. The results were compared to theoretical values for different conduction mechanisms, to further elucidate the conduction mechanism in these contact structures. The data indicates the conduction mechanism is field emission for these contact schemes for all but as-deposited metal to InN where thermionic emission appears to be the dominant mechanism. The contacts were found to produce low specific resistance ohmic contacts to InGaN at room temperature, ϱc ∼ 10-7 Ω ·cm2 for W and ϱc of 4× 10-7 Ω ·cm for WSix. InN metallized with W produced ohmic contacts with ϱc ∼ 10-6 Ω ·cm and ϱc ∼ 10-6 Ω ·cm. for WSix at room temperature.

Ni-Al-Ti Ohmic Contacts with Preserved Form Factor and Few 10- 4 Ωcm2 Specific Resistance on 0.1-1 Ωcm p-Type 4H-SiC

2018 ◽  
Vol 924 ◽  
pp. 385-388 ◽  
Author(s):  
Roberta Nipoti ◽  
Maurizio Puzzanghera ◽  
Maria Concetta Canino ◽  
Giovanna Sozzi ◽  
Paolo Fedeli
Keyword(s):  
Form Factor ◽  
Contact Resistance ◽  
Contact Area ◽  
Room Temperature ◽  
Ohmic Contacts ◽  
Specific Resistance ◽  
Thickness Ratio ◽  
Specific Contact Resistance ◽  
Specific Contact ◽  
P Type

This study shows that a thin Ni film on Al/Ti/4H-SiC metal pads allows to preserve the pad form factor during a 1000 °C/2 min treatment, provided that the Al and Ti film thicknesses are sufficiently thin. Moreover, by reducing the Al to Ti thickness ratio, droplet formation in the contact area is avoided and a mirror-like appearance is obtained. This optimal contact morphology corresponds to a specific contact resistance of few 10-4Ωcm2at room temperature on p-type 4H-SiC with resistivity in the range 0.1 – 1 Ωcm.

Current Transport in Ti/Al/Ni/Au Ohmic Contacts to GaN and AlGaN

2007 ◽  
Vol 556-557 ◽  
pp. 1027-1030 ◽  
Author(s):  
Ferdinando Iucolano ◽  
Fabrizio Roccaforte ◽  
Filippo Giannazzo ◽  
A. Alberti ◽  
Vito Raineri
Keyword(s):  
Contact Resistance ◽  
Field Emission ◽  
Ohmic Contacts ◽  
Theoretical Models ◽  
Specific Contact Resistance ◽  
Strong Increase ◽  
Current Transport ◽  
Electrical Characteristics ◽  
Structural And Electrical Properties ◽  
Specific Contact

In this work, the structural and electrical properties of Ti/Al/Ni/Au contacts on n-type Gallium Nitride were studied. An ohmic behaviour was observed after annealing above 700°C. The structural analysis showed the formation of an interfacial TiN layer and different phases in the reacted layer (AlNi, AlAu4, Al2Au) upon annealing. The temperature dependence of the specific contact resistance demonstrated that the current transport occurs through thermoionic field emission in the contacts annealed at 600°C, and field emission after annealing at higher temperatures. By fitting the data with theoretical models, a reduction of the Schottky barrier from 1.21eV after annealing at 600°C to 0.81eV at 800°C was demonstrated, together with a strong increase of the carrier concentration at the interface. The reduction of the contact resistance upon annealing was discussed by correlating the structural and electrical characteristics of the contacts.

Current Transport Mechanisms in Au-Free Metallizations for CMOS Compatible GaN HEMT Technology

2020 ◽  
Vol 1004 ◽  
pp. 725-730
Author(s):  
Fabrizio Roccaforte ◽  
Monia Spera ◽  
Salvatore Di Franco ◽  
Raffaella Lo Nigro ◽  
Patrick Fiorenza ◽  
...  
Keyword(s):  
Barrier Height ◽  
Ohmic Contacts ◽  
Specific Contact Resistance ◽  
Current Transport ◽  
Large Area ◽  
Si Substrates ◽  
Ohmic Behavior ◽  
Specific Contact ◽  
Thermionic Field Emission

Gallium nitride (GaN) and its AlGaN/GaN heterostructures grown on large area Si substrates are promising systems to fabricate power devices inside the existing Si CMOS lines. For this purpose, however, Au-free metallizations are required to avoid cross contaminations. In this paper, the mechanisms of current transport in Au-free metallization on AlGaN/GaN heterostructures are studied, with a focus on non-recessed Ti/Al/Ti Ohmic contacts. In particular, an Ohmic behavior of Ti/Al/Ti stacks was observed after an annealing at moderate temperature (600°C). The values of the specific contact resistance ρc decreased from 1.6×104 Ω.cm2 to 7×105 Ω.cm2 with increasing the annealing time from 60 to 180s. The temperature dependence of ρc indicated that the current flow is ruled by a thermionic field emission (TFE) mechanism, with barrier height values of 0.58 eV and 0.52 eV, respectively. Finally, preliminary results on the forward and reverse bias characterization of Au-free tungsten carbide (WC) Schottky contacts are presented. This contact exhibited a barrier height value of 0.82 eV.

scholarly journals Ohmic contacts to Si-implanted and un-implanted n-type GaN

1995 ◽  
Vol 395 ◽  
Author(s):  
J. Brown ◽  
J Ramer ◽  
K. ZHeng ◽  
L.F. Lester ◽  
S.D. Hersee ◽  
...  
Keyword(s):  
Contact Resistance ◽  
Ohmic Contacts ◽  
Annealing Temperature ◽  
Contact Resistivity ◽  
Contact Structures ◽  
Specific Contact Resistance ◽  
Resistance Variation ◽  
Specific Contact ◽  
Metal Layers ◽  
Nitrogen Vacancies

ABSTRACTWe report on ohmic contacts to Si-implanted and un-implanted n-type GaN on sapphire. A ring shaped contact design avoids the need to isolate the contact structures by additional implantation or etching. Metal layers of Al and Ti/Al were investigated. On un-implanted GaN, post metalization annealing was performed in an RTA for 30 seconds in N2 at temperatures of 700, 800, and 900°C, A minimum specific contact resistance (rc) of 1.4×10−5 Ω-cm2 was measured for Ti/Al at an annealing temperature of 800°C. Although these values are reasonably low, variations of 95% in specific contact resistance were measured within a 500 µm distance on the wafer. These results are most likely caused by the presence of compensating hydrogen. Specific contact resistance variation was reduced from 95% to 10% by annealing at 900°C prior to metalization. On Si-implanted GaN, un-annealed ohmic contacts were formed with Ti/Al metalization. The implant activation anneal of 1120°C generates nitrogen vacancies that leave the surface heavily n-type, which makes un-annealed ohmic contacts with low contact resistivity possible.

TiW/TiWN/Pt Ohmic Contacts to n-Type 3C-SiC

2006 ◽  
Vol 911 ◽  
Author(s):  
Kirk Hofeling ◽  
Loren Rieth ◽  
Florian Solzbacher
Keyword(s):  
Contact Resistance ◽  
Room Temperature ◽  
Ohmic Contacts ◽  
Specific Contact Resistance ◽  
Test Duration ◽  
Capping Layer ◽  
Interface Reactions ◽  
Transmission Line Method ◽  
Specific Contact

AbstractTiW(40 nm)/TiWN(80 nm)/Pt(500nm) was investigated as a new high-temperature compatible contact stack to 3C-SiC for harsh environment applications. Performance of TiW/TiWN/Pt contacts deposited on unintentionally doped (8.85×1018 cm-3) 3C-SiC grown by LPCVD to a thickness of ~1μm on (100) Si are reported. The linear transmission line method was used to determine specific contact resistance (ρc) at room temperature and for long-term tests at 300 °C. As deposited contacts were Ohmic with a ρc range of 1×10-4 to 1×10-3 cm2. These contacts were annealed for five minutes in forming gas (8% H2 92% Ar), at temperatures from 450 to 950 °C and all retained Ohmic character. Annealing samples at 450, 550 and 950 °C decreased ρc while anneling between 650 and 850 °C generally increased ρc.Auger Electron Spectroscopy (AES) analysis was performed on a sample annealed at 750 °C. The as-received surface was composed of Si and O; after a brief sputter etch a characteristic Pt peak became visible and the O peak decreased substantially. Depth profiles detected Si throughout the Pt capping layer but not in the TiW layers. We suspect that Si diffuses from the SiC substrate into the Pt capping layer and surface Si also reacts with O2 to from an oxide. These reactions, in combination with incomplete SiC/TiW interface reactions, are suspected to cause the increase of ρc for samples annealed between 650 and 850 °C. Annealing at 950 °C gave the lowest contact resistance of 2.3×10-5. Long-term testing at 300 °C for 190 hours, in atmosphere, was performed on contacts annealed at 450 °C. When heated, the contacts initial ρc of 2.1×10-4 cm2 increased to ~4×10-3 cm2 which remained stable for the test duration. After long-term testing the sample ρc measured at room temperature decreased to 9.8×10-5 cm2.

Low Resistance Ohmic Contacts Formation and Mechanism of Current Transport Through p-GaN and p-AlGaN

2008 ◽  
Vol 1108 ◽  
Author(s):  
Indra Chary ◽  
Boris Borisov ◽  
Vladimir Kuryatkov ◽  
Yuriy Kudryavtsev ◽  
R Asomoza ◽  
...  
Keyword(s):  
Ohmic Contact ◽  
Ohmic Contacts ◽  
Annealing Temperature ◽  
Hole Concentration ◽  
Specific Contact Resistance ◽  
Current Transport ◽  
Bilayer Thickness ◽  
Aluminum Oxides ◽  
Mg Doping ◽  
Specific Contact

AbstractWe report the influence of surface treatment, annealing temperature and metal bilayer thickness on the specific contact resistance (ρc) of Au/Ni ohmic contacts to p-GaN and p-AlGaN. Ohmic contact on p-GaN with a hole concentration of 6.5 x 1017 cm-3, shows the lowest ρc of ˜9.2 x 10-6 Ω cm2, when GaN was treated in HCl:H2O (3:1) solution before metal deposition and annealed at 500°C for 10 minutes in 90% N2 and 0% O2 atmosphere. Similar procedure applied on p-AlxGa1-xN (x = 5-7%), with a hole concentration of 2.3 x 1017 cm-3, yields a ρc of 1.8 x 10-4 Ω cm2. An increase is observed in ρc when Mg doping exceeds 4 x 1019 cm-3 in both p-GaN and p-AlGaN. This is attributed to Mg self compensation. This increase is more pronounced in AlGaN which we attribute to the presence of residual native aluminum oxides.

Comparison of Ni/Au, Pd/Au, and Cr/Au Metallizations for Ohmic Contacts to p-GaN

1996 ◽  
Vol 449 ◽  
Author(s):  
J. T. Trexler ◽  
S. J. Pearton ◽  
P. H. Holloway ◽  
M. G. Mier ◽  
K. R. Evans ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Ohmic Contacts ◽  
Thermionic Emission ◽  
Specific Contact Resistance ◽  
Capping Layer ◽  
Dominant Conduction Mechanism ◽  
Current Voltage ◽  
Structural And Electronic Properties ◽  
Specific Contact ◽  
Thermionic Field Emission

ABSTRACTReactions between electron beam evaporated thin films of Ni/Au, Pd/Au, and Cr/Au on p-GaN with a carrier concentration of 9.8 × 1016 cm−3 were investigated in terms of their structural and electronic properties both as-deposited and following heat treatments up to 600°C (furnace anneals) and 900°C (RTA) in a flowing N2 ambient. Auger electron spectroscopy (AES) depth profiles were used to study the interfacial reactions between the contact metals and the p-GaN. The electrical properties were studied using room temperature current-voltage (1-V) measurements and the predominant conduction mechanisms in each contact scheme were determined from temperature dependent I-V measurements. The metallization schemes consisted of a 500 Å interfacial layer of Ni, Pd, or Cr followed by a 1000 Å capping layer of Au. All schemes were shown to be rectifying as-deposited with increased ohmic character upon heat treatment. The Cr/Au contacts became ohmic upon heating to 900°C for 15 seconds while the other schemes remained rectifying with lower breakdown voltages following heat treatment. The specific contact resistance of the Cr/Au contact was measured to be 4.3×10−1 Ωcm2. Both Ni and Cr have been shown to react with the underlying GaN above 400 °C while no evidence of a Pd:GaN reaction was seen. Pd forms a solid solution with the Au capping layer while both Ni and Cr tend to diffuse through the capping layer to the surface. All contacts were shown to have a combination of thermionic emission and thermionic field emission as their dominant conduction mechanism, depending on the magnitude of the applied reverse bias.

Temperature Behavior of Pt/Au Ohmic Contacts to p-GaN

1997 ◽  
Vol 468 ◽  
Author(s):  
D. J. King ◽  
L. Zhang ◽  
J. C. Ramer ◽  
S. D. Hersee ◽  
L. F. Lester
Keyword(s):  
Contact Resistance ◽  
Room Temperature ◽  
Ohmic Contacts ◽  
Characteristic Curve ◽  
Specific Contact Resistance ◽  
Metal Contacts ◽  
Dopant Activation ◽  
Specific Contact ◽  
Order Of Magnitude ◽  
Increasing Temperature

ABSTRACTOhmic contacts to Mg-doped p-GaN grown by MOCVD [1] are studied using a circular transmission line model (TLM) to avoid the need for isolation. For samples which use a p-dopant activation anneal before metallization, no appreciable difference in the specific contact resistance, rc, as a function of different capping options is observed. However, a lower rc is obtained when no pre-metallization anneal is employed, and the post-metallization anneal simultaneously activates the p-dopant and anneals the contact. This trend is shown for Pt/Au, Pt, Pd/Pt/Au, and Ni/Au contacts to p-GaN. The rc 's for these metal contacts are in the range of 1.4–7.6 × 10-3 ohm-cm2 at room temperature at a bias of 10mA. No particular metallization formula clearly yields a consistently superior contact. Instead, the temperature of the contact has the strongest influence.Detailed studies of the electrical properties of the Pt/Au contacts reveal that the I-V linearity improves significantly with increasing temperature. At room temperature, a slightly rectified I-V characteristic curve is obtained, while at 200°C and above, the I-V curve is linear. For all the p-GaN samples, it is also found that the sheet resistance decreases by an order of magnitude with increasing temperature from 25°C to 350°C. The specific contact resistance is also found to decrease by nearly an order of magnitude for a temperature increase of the same range. A minimum rc of 4.2 × 10-4 ohm-cm2 was obtained at a temperature of 350°C for a Pt/Au contact. This result is the lowest reported rc for ohmic contacts to p-GaN.

In-Based Ohmic Contacts to the Base Layer of GaAs-AlGaAs Heterojunction Bipolar Transistors

1990 ◽  
Vol 181 ◽  
Author(s):  
F. Ren ◽  
S. J. Pearton ◽  
W. S. Hobson ◽  
T. R. Fullowan ◽  
A. B. Emerson ◽  
...  
Keyword(s):  
Contact Resistance ◽  
Heterojunction Bipolar Transistors ◽  
Ohmic Contacts ◽  
Bipolar Transistors ◽  
Base Layer ◽  
Specific Contact Resistance ◽  
Current Transport ◽  
Specific Contact ◽  
P Type

ABSTRACTThe use of AuBe-In/Ag/Au p-ohmic contacts for the base layer of GaAs-AIGaAs heterojunction bipolar transistors (HBTs) is described. Annealing at 420°C for 20 sec produces a contact resistivity of 0.095 Ω mm and a specific contact resistance of l.5 × 10-7 Ω cm2, and the surface morphology of the contact is excellent. The role of the silver is as a diffusion barrier to prevent Au spiking into the base layer which could degrade the HBT performance. The presence of the In layer is highly desirable in order to reduce the contact resistance, probably by forming an InGaAs phase at the metal-GaAs interface. Beryllium acts as the p-type dopant, and the top Au layer is used to lower the contact sheet resistance. Current transport through the structure is dominated by tunneling through the barrier due to field emission in the highly doped base layer at p-type doping levels above ∼1019 cm−3

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