Examination of Dislocation Structures Near Crack TIP Region of B2 NiAl Alloys

1996 ◽  
Vol 460 ◽  
Author(s):  
B-C. Ng ◽  
B. Simkin ◽  
M. A. Crimp
Keyword(s):  
Thermal Treatment ◽  
Dislocation Density ◽  
Brittle Material ◽  
Contrast Imaging ◽  
Near Surface ◽  
Crystalline Defects ◽  
Crack Tips ◽  
Point Bend ◽  
Distribution Of Dislocations

ABSTRACTThe structure and distribution of dislocations in the region of crack tips and crack edges have been examined in single crystal stoichiometric B2 NiAl using electron channeling contrast imaging (ECCI). ECCI, which allows examination of near surface substructural crystalline defects in bulk specimens, has been carried out for undeformed as well as in-situ deformed 4-point bend specimens. Images of dislocations at crack tips and along the crack fracture surfaces have been studied. Observations have been correlated with variations in thermal treatment corresponding with brittle and toughened conditions. A higher dislocation density was observed over a larger region in front of crack tips for the toughened materials as compared to brittle material.

scholarly journals In situ high energy X-ray diffraction measurement of strain and dislocation density ahead of crack tips grown in hydrogen

2019 ◽  
Vol 180 ◽  
pp. 272-286 ◽  
Author(s):  
Matthew Connolly ◽  
May Martin ◽  
Peter Bradley ◽  
Damian Lauria ◽  
Andrew Slifka ◽  
...  
Keyword(s):  
Dislocation Density ◽  
High Energy ◽  
Diffraction Measurement ◽  
X Ray Diffraction ◽  
X Ray ◽  
Crack Tips

Postmortem and in situ TEM methods to study the mechanism of failure in controlled-morphology high-impact polystrene resin

1996 ◽  
Vol 54 ◽  
pp. 178-179
Author(s):  
R. C. Cieslinski ◽  
M. T. Dineen ◽  
J. L. Hahnfeld
Keyword(s):  
Poisson Ratio ◽  
Acrylonitrile Butadiene Styrene ◽  
High Impact ◽  
In Situ Tem ◽  
Styrene Copolymers ◽  
Controlled Morphology ◽  
Point Bend ◽  
Mechanism Of Failure ◽  
Impact Energies

Advanced Styrenic resins are being developed throughout the industry to bridge the properties gap between traditional HIPS (High Impact Polystyrene) and ABS (Acrylonitrile-Butadiene-Styrene copolymers) resins. These new resins have an unprecedented balance of high gloss and high impact energies. Dow Chemical's contribution to this area is based on a unique combination of rubber morphologies including labyrinth, onion skin, and core-shell rubber particles. This new resin, referred as a controlled morphology resin (CMR), was investigated to determine the toughening mechanism of this unique rubber morphology. This poster will summarize the initial studies of these resins using the double-notch four-point bend test of Su and Yee, tensile stage electron microscopy, and Poisson Ratio analysis of the fracture mechanism.

Electron Channelling Contrast Imaging of Dislocations

1990 ◽  
Vol 48 (1) ◽  
pp. 600-601
Author(s):  
J.T. Czernuszka ◽  
N.J. Long ◽  
P.B. Hirsch
Keyword(s):  
Field Emission ◽  
Secondary Electron ◽  
Surface Defects ◽  
Spot Size ◽  
Beam Divergence ◽  
Contrast Imaging ◽  
Scattered Electron ◽  
Near Surface ◽  
Filter System ◽  
Electron Channelling

In the 1970s there was considerable interest in the development of the electron channelling contrast imaging (ECCI) technique for imaging near surface defects in bulk (electron opaque) specimens. The predictions of the theories were realised experimentally by Morin et al., who used a field emission gun (FEG) operating at 40-50kV and an energy filter such that only electrons which had lost no more than a few 100V were detected. This paper presents the results of a set of preliminary experiments which show that an energy filter system is unneccessary to image and characterise the Burgers vectors of dislocations in bulk specimens. The examples in the paper indicatethe general versatility of the technique.A VG HB501 STEM with a FEG was operated at 100kV. A single tilt cartridge was used in the reflection position of the microscope. A retractable back-scattered electron detector was fitted into the secondary electron port and positioned to within a few millimetres of the specimen. The image was acquired using a Synoptics Synergy framestore and digital scan generator and subsequently processed using Semper 6. The beam divergence with the specimen in this position was 2.5 mrads with a spot size of approximately 4nm. Electron channelling patterns were used to orientate the sample.

scholarly journals North polar trough formation due to in-situ erosion as a source of young ice in mid-latitudinal mantles on Mars

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
J. Alexis P. Rodriguez ◽  
Kenneth L. Tanaka ◽  
Ali M. Bramson ◽  
Gregory J. Leonard ◽  
Victor R. Baker ◽  
...  
Keyword(s):  
Katabatic Wind ◽  
Spiral Pattern ◽  
Near Surface ◽  
Valuable Source ◽  
History Of ◽  
North Polar ◽  
Human Exploration ◽  
Erosional Event

AbstractThe clockwise spiral of troughs marking the Martian north polar plateau forms one of the planet’s youngest megastructures. One popular hypothesis posits that the spiral pattern resulted as troughs underwent poleward migration. Here, we show that the troughs are extensively segmented into enclosed depressions (or cells). Many cell interiors display concentric layers that connect pole- and equator-facing slopes, demonstrating in-situ trough erosion. The segmentation patterns indicate a history of gradual trough growth transversely to katabatic wind directions, whereby increases in trough intersections generated their spiral arrangement. The erosional event recorded in the truncated strata and trough segmentation may have supplied up to ~25% of the volume of the mid-latitude icy mantles. Topographically subtle undulations transition into troughs and have distributions that mimic and extend the troughs’ spiraling pattern, indicating that they probably represent buried trough sections. The retention of the spiral pattern in surface and subsurface troughs is consistent with the megastructure’s stabilization before its partial burial. A previously suggested warm paleoclimatic spike indicates that the erosion could have occurred as recently as ~50 Ka. Hence, if the removed ice was redeposited to form the mid-latitude mantles, they could provide a valuable source of near-surface, clean ice for future human exploration.

scholarly journals Strengthening Mechanisms of Magnesium-Lithium Based Alloys and Composites

2016 ◽  
Vol 2016 ◽  
pp. 1-11 ◽  
Author(s):  
C. O. Muga ◽  
Z. W. Zhang
Keyword(s):  
Thermal Treatment ◽  
Dislocation Density ◽  
Thermomechanical Processing ◽  
Precipitation Strengthening ◽  
Strengthening Mechanisms ◽  
Engineering Applications ◽  
The Past ◽  
Treatment Processes ◽  
Solution Strengthening ◽  
Suitable Processing

Mg-Li based alloys are widely applied in various engineering applications. The strength of these alloys is modified and enhanced by different strengthening mechanisms. The strengthening mechanisms of these alloys and their composites have been extensively studied during the past decades. Important mechanisms applied to strengthening the alloys include precipitation strengthening, solution strengthening, grain and subgrain strengthening, and dislocation density strengthening. Precipitation and solution strengthening mechanisms are strongly dependent on composition of the alloys and thermal treatment processes, whereas grain and subgrain and dislocation density strengthening mechanisms majorly depend on thermomechanical processing. In this paper, recent studies on conventional processes for the strengthening of Mg-Li based alloys are summarized as they are critical during the alloys design and processing. Main strengthening mechanisms are objectively reviewed, focusing on their advantages and drawbacks. These can contribute to enhancing, initiating, and improving future researches for alloys design and suitable processing selection.

scholarly journals Fracture in Bulk Amorphous Alloys

1998 ◽  
Vol 554 ◽  
Author(s):  
J. A. Horton ◽  
J. L. Wright ◽  
J. H. Schneibel
Keyword(s):  
Crack Propagation ◽  
Crack Growth ◽  
Shear Bands ◽  
Bulk Amorphous Alloy ◽  
In Situ Tem ◽  
X Ray Diffraction ◽  
Transmission Electron ◽  
Crack Tips ◽  
Temperature Fracture

AbstractThe fracture behavior of a Zr-based bulk amorphous alloy, Zr-10 Al-5 Ti-17.9 Cu-14.6Ni (at.%), was examined by transmission electron microscopy (TEM) and x-ray diffraction forany evidence of crystallization preceding crack propagation. No evidence for crystallizationwas found in shear bands in compression specimens or at the fracture surface in tensile specimens.In- situ TEM deformation experiments were performed to more closely examine actualcrack tip regions. During the in-situ deformation experiment, controlled crack growth occurredto the point where the specimen was approximately 20 μm thick at which point uncontrolledcrack growth occurred. No evidence of any crystallization was found at the crack tips or thecrack flanks. Subsequent scanning microscope examination showed that the uncontrolledcrack growth region exhibited ridges and veins that appeared to have resulted from melting. Performing the deformations, both bulk and in-situ TEM, at liquid nitrogen temperatures (LN2) resulted in an increase in the amount of controlled crack growth. The surface roughness of the bulk regions fractured at LN2 temperatures corresponded with the roughness of the crack propagation observed during the in-situ TEM experiment, suggesting that the smooth-appearing room temperature fracture surfaces may also be a result of localized melting.

A novel in-situ, lift-out, three-point bend technique to quantify the mechanical properties of an ex-service neutron irradiated inconel X-750 component

2018 ◽  
Vol 498 ◽  
pp. 149-158 ◽  
Author(s):  
C. Howard ◽  
C.D. Judge ◽  
D. Poff ◽  
S. Parker ◽  
M. Griffiths ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Point Bend

Nanoscale Mechanical Properties of In-Situ Tribofilms Generated from ZDDP and F-ZDDP with and without Antioxidants

2007 ◽  
Vol 7 (12) ◽  
pp. 4378-4390 ◽  
Author(s):  
Anuradha Somayaji ◽  
Ramoun Mourhatch ◽  
Pranesh B. Aswath
Keyword(s):  
Electron Microscopy ◽  
Wear Debris ◽  
Surface Region ◽  
Nucleation And Growth ◽  
Near Surface ◽  
Transmission Electron ◽  
Dialkyl Dithiophosphates ◽  
Wear Tests ◽  
Diphenyl Amine

Tribofilms with thickness ranging from 100–200 nm were developed in-situ during wear tests using a zinc dialkyl dithiophosphates (ZDDP) and fluorinated ZDDP (F-ZDDP). The influence of the antioxidant alkylated diphenyl amine on the formation and properties of these tribofilm is examined. Results indicate that the thickness of the tribofilms formed when F-ZDDP is used is always thicker than the tribofilm formed with ZDDP. In addition, in the presence of antioxidants the tribofilm thickness is increased. The hardness of these tribofilms in the absence of the antioxidants is significantly higher at the near surface region (0–30 nm) when compared to the films formed in the presence of antioxidant. Nanoscratch tests conducted to examine the abrasion resistance of the tribofilms also indicate that the tribofilms formed by F-ZDDP are more resistant to scratch compared to films formed by ZDDP. In the presence of antioxidant, tribofilms formed by F-ZDDP are significantly thicker while both films behave in a similar fashion in nanoscratch tests. Transmission electron microscopy of the wear debris formed during the tests were examined and results indicate the nucleation and growth of nanoparticles of Fe3O4 with an approximate size of 5–10 nm embedded within an otherwise amorphous tribofilm.

Phosphate biogeochemical barrier for uranium in situ immobilization in an aquifer nearby sludge repository

2021 ◽  
Author(s):  
Grigory Artemiev ◽  
Alexey Safonov ◽  
Nadezhda Popova
Keyword(s):  
Essential Elements ◽  
Ion Concentration ◽  
Soluble Form ◽  
High Concentration ◽  
Rapid Reduction ◽  
Near Surface ◽  
Nitrate Ions ◽  
Uranium Migration ◽  
Storage Facilities

<p>Uranium migration in the oxidized environment of near-surface groundwater is a typical problem of many radiochemical, ore mining and ore processing enterprises that have sludge storage facilities on their territory. Uranium migration, as a rule, occurs against a high salt background due to the composition of the sludge: primarily, nitrate and sulfate anions and calcium cations. One of the ways to prevent the uranium pollution is geochemical or engineering barriers. For uranium immobilization, it is necessary to create conditions for its reduction to a slightly soluble form of uraninite and further mineralization, for example, in the phosphate form. An important factor contributing to the rapid reduction of uranium is a in the redox potential decreasing and the removal of nitrate ions, which can be achieved through the activation of microflora. It should be added that phosphate itself is one of the essential elements for the development of microflora. This work was carried out in relation to the upper aquifer (7-12 m) near the sludge storage facilities of ChMZ, which is engaged in uranium processing and enrichment. One of the problems of this aquifer, in addition to the high concentration of nitrate ions (up to 15 g / l), is the high velocity of formation waters.<br>In laboratory conditions, the compositions of injection solutions were selected containing sources of organic matter to stimulate the microbiota development and phosphates for uranium mineralization. When developing the injection composition, special attention was paid to assessing the formation of calcite deposits in aquifer conditions to partially reduce the filtration parameters of the horizon and reduce the rate of movement of formation waters. This must be achieved to ensure the possibility of long-term deposition of uranium and removal of nitrate. The composition of the optimal solution was selected and in a series of model experiments the mineral phases containing the lowest hydrated form of the uranium-containing phosphate mineral meta-otenite were obtained.<br>In situ mineral phosphate barrier Formation field tests were carried out in water horizon conditions in a volume of 100m3 by injection of an organic and phosphates mixture. As a result, at the first stage of field work, a significant decreasing nitrate ion concentration, and reducing conditions formation coupled with the dissolved uranium concentration of decreasing were noted.</p>

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