Physical and Chemical Properties of CaCl2/H2O and LiBr/H2O Systems Confined to Nanopores of Silica Gels
Keyword(s):
ABSTRACTHere we present physical and chemical properties of CaCl2/H2O and LiBr/H2O systems confined to nanopores of silica gels. Sorption isobars, isosters and isotherms were measured at temperature 293 – 423K and vapor partial pressure 8–133 mbar. Specific heat of the systems was found as a function of temperature (300 – 400K) and sorbed water content (0 – 53 wt.%). Solidification/melting diagrams were measured over 170 – 320K temperature range at salt concentrations 0–50 wt.%. The results obtained evidenced a significant change in the thermodynamic properties of CaCl2/H2O and LiBr/H2O systems due to confinement to the silica gel micropores.
1966 ◽
Vol 24
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pp. 101-110
2016 ◽
Vol 29
(2)
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pp. 266-274
2018 ◽
Vol 3
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pp. 167-170