The Salton Sea Geothermal Field as a Natural Analog for the Near-Field in a Salt High-Level Nuclear Waste Repository

1984 ◽  
Vol 44 ◽  
Author(s):  
Wilfred A. Elders ◽  
Judith B. Moody
Keyword(s):  
Nuclear Waste ◽  
Near Field ◽  
Geothermal Field ◽  
Salton Sea ◽  
High Level Waste ◽  
Nuclear Waste Repository ◽  
Natural Analog ◽  
Naturally Occurring ◽  
Wide Range ◽  
High Level

AbstractThe Salton Sea Geothermal Field (SSGF), on the delta of the Colorado River in southern California, is being studied as a natural analog for the near-field environment of proposed nuclear waste repositories in salt. A combination of mineralogical and geochemical methods is being employed to develop a three dimensional picture of temperature, salinity, lithology, mineralogy, and chemistry of reactions between the reservoir rocks and the hot brines. Our aim is to obtain quantitative data on mineral stabilities and on mobilities of the naturally occurring radionuclides of concern in Commercial High-Level Waste (CHLW). These data will be used to validate the EQ3/6 geochemical code under development to model the salt near-field repository behavior.Maximum temperatures encountered in wells in the SSGF equal or exceed peak temperatures expected in a salt repository. Brines produced from these wells have major element chemistry similar to brines from candidate salt sites. Relative to the rocks, these brines are enriched in Na, Mn, Zn, Sr, Ra and Po, depleted in Ba, Si, Mg, Ti, and Al, and strongly depleted in U and Th. However the unaltered rocks contain only about 2–3 ppm of U and 4–12 ppm of Th, largely in detrital epidotes and zircons. Samples of hydrothermally altered rocks from a wide range of temperature and salinity show rather similar uniform low concentrations of these elements, even when authigenic illite, chlorite, epidote and feldspar are present. These observations suggest that U and Th are relatively immobile in these hot brines. However Ra, Po, Cs and Sr are relatively mobile. Work is continuing to document naturally occurring radionuclide partitioning between SSGF minerals and brine over a range of temperature, salinity, and lithology.

An Approach to Analysis of High Level waste Container Performance in an Unsaturated Repository Environment

1993 ◽  
Vol 333 ◽  
Author(s):  
John C. Walton ◽  
Narasi Sridhar ◽  
Gustavo Cragnolino ◽  
Tony Torng ◽  
Prasad Nair
Keyword(s):  
Dominant Role ◽  
Near Field ◽  
Temperature Fields ◽  
Localized Corrosion ◽  
High Level Waste ◽  
Quantitative Methodology ◽  
Waste Container ◽  
Wide Range ◽  
Engineered Barrier ◽  
High Level

ABSTRACTOne of the requirements for the performance of waste packages prescribed in 10CFR 60.113 is that the high level waste must be “substantially completely” contained for a minimum period of 300 to 1000 years. During this period, the radiation and thermal conditions in the engineered barrier system and the near-field environment are dominated by fission product decay. In the present U.S design of the engineered barrier system, the outer container plays a dominant role in maintaining radionuclide containment. A quantitative methodology for analyzing the performance of the container is described in this paper. This methodology enables prediction of the evolution of the waste package environment in terms of temperature fields, stability of liquid water on the container surface, and concentration of aggressive ions such as chloride. The initiation and propagation of localized corrosion is determined by the corrosion potential of the container material and critical potentials for localized corrosion. The coiTOsion potential is estimated from the kinetics of the anodic and cathodic reactions including oxygen diffusion through scale layers formed on the container surface. The methodology described is applicable to a wide range of metals, alloys and environmental conditions.

Crystal Chemistry of Natural Zirconolite: Implications for High-Level Waste Incorporation in Synroc

1997 ◽  
Vol 506 ◽  
Author(s):  
Reto Gierpé ◽  
C. Terry Williams ◽  
Gregory R. Lumpkin
Keyword(s):  
Statistical Study ◽  
Alpha Decay ◽  
High Level Waste ◽  
Rock Types ◽  
Naturally Occurring ◽  
Geological Conditions ◽  
Wide Range ◽  
Alteration Processes ◽  
High Level Nuclear Waste ◽  
High Level

ABSTRACTZirconolite, ideally CaZrTi2O7, is a relatively rare mineral crystallizing at different geological conditions and in a wide range of generally SiO2-poor rock types. Synthetic zirconolite is one of two major actinide (ACT) host phases in SYNROC, a very promising option for the disposal of high-level nuclear waste (HLW). The available samples of naturally occurring zirconolite cover an extensive range in ACT content, age and host rock type, and thus offer an ideal opportunity to study the relationships between alpha-decay doses, radiation damage, and geochemical alteration processes [1]. In this paper, we present results obtained from a statistical study of nearly 300 chemical analyses of natural zirconolite [2].

scholarly journals Thermal Conductivity of Korean Compacted Bentonite Buffer Materials for a Nuclear Waste Repository

Energies ◽  
2018 ◽  
Vol 11 (9) ◽  
pp. 2269 ◽  
Author(s):  
Seok Yoon ◽  
WanHyoung Cho ◽  
Changsoo Lee ◽  
Geon-Young Kim
Keyword(s):  
Thermal Conductivity ◽  
Near Field ◽  
High Level Waste ◽  
Nuclear Waste Repository ◽  
Spent Fuel ◽  
Decay Heat ◽  
Bentonite Buffer ◽  
Buffer Material ◽  
Overall Evaluation ◽  
High Level

Engineered barrier system (EBS) has been proposed for the disposal of high-level waste (HLW). An EBS is composed of a disposal canister with spent fuel, a buffer material, backfill material, and a near field rock mass. The buffer material is especially essential to guarantee the safe disposal of HLW, and plays the very important role of protecting the waste and canister against any external mechanical impact. The buffer material should also possess high thermal conductivity, to release as much decay heat as possible from the spent fuel. Its thermal conductivity is a crucial property since it determines the temperature retained from the decay heat of the spent fuel. Many studies have investigated the thermal conductivity of bentonite buffer materials and many types of soils. However, there has been little research or overall evaluation of the thermal conductivity of Korean Ca-type bentonite buffer materials. This paper investigated and analyzed the thermal conductivity of Korean Ca-type bentonite buffer materials produced in Gyeongju, and compared the results with various characteristics of Na-type bentonites, such as MX80 and Kunigel. Additionally, this paper suggests various predictive models to predict the thermal conductivity of Korean bentonite buffer materials considering various influential independent variables, and compared these with results for MX80 and Kunigel.

Hydro-geochemical processes in the emplacement cavern of a low and intermediate-level waste repository in an indurated clay-rock

2021 ◽  
Author(s):  
Vanessa Montoya ◽  
Jaime Garibay-Rodriguez ◽  
Olaf Kolditz
Keyword(s):  
Chemical Evolution ◽  
Nuclear Waste ◽  
Host Rock ◽  
Numerical Models ◽  
Intermediate Level ◽  
High Level Waste ◽  
Nuclear Waste Repository ◽  
Case Scenario ◽  
Damaged Zone ◽  
Waste Repository

<p>By 2080, Germany will have to store around 600 000 m<sup>3</sup> of low and intermediate-level nuclear waste (L-ILW) with negligible heat generation. This kind of waste is largely made up of used parts of nuclear power stations such as pumps, pipelines, filters, etc. placed in various types of waste containers made from either steel, cast iron, or reinforced concrete in different designs and sizes (i.e. cylindrical or box shaped). It is already decided that a total of 303 000 of the 600 000 m<sup>3</sup> L-ILW will be disposed in a final storage facility in the former iron ore mine Schacht Konrad which is under construction. However, it is still not clear where the L-ILW emplaced in in the old salt mine Asse (200 000 m<sup>3</sup>) will be stored in the future. The situation is particularly critical, as the waste have to be retrieved from the instable mine shafts partially flooded with groundwater, causing strong socio-political concerns as radioactive waste could contaminate the water nearby. For this reason, the new search for a nuclear waste repository for high-level waste (HLW), started in 2017, should also consider the possibility to accommodate the waste from Asse. Obviously, this is still subject to critics as this will make finding a final repository more difficult as storing HLW and L-ILW together requires different concepts and designs for each other and, above all, much more space.</p><p>In this context, in this contribution we have defined conceptual and numerical models to assess the hydro-chemical evolution of a L-ILW disposal cell in indurated clay rocks, involving the interaction of different components/materials and the expected hydraulic and/or chemical gradients over 100 000 years. The L-ILW disposal cell leverages a multi-barrier concept buried 400 m below the surface. The multi-barrier system is comprised of the waste matrix (i.e. backfilling the waste drums), the disposal container, the mortar backfill in the emplacement tunnel (where the disposal containers are located) and the clay host rock. The dimensions and design of the emplacement tunnel (e.g. 11 × 13 m) and disposal cells represent and consider some aspects taken into account in the designs of some European countries. In addition, tunnel walls reinforced with a shotcrete liner and the Excavation Damaged Zone is considered in the concept. The model is implemented in OpenGeoSys-6, an open-source version-controlled scientific software based on Finite Element Method which is capable of handling fully coupled hydro-chemical models by coupling OpenGeoSys to iPHREEQC. First calculation results, demonstrate that the most important processes affecting the near-field chemical evolution are i) the degradation of the concrete and cementitious grouts with porewater migrating inwards from the host rock and ii) the significant quantities of reactive and non-reactive gases (i.e. hydrogen, carbon dioxide and methane) that are generated as a result of: i) the anaerobic corrosion of metals present in the waste and containers and ii) the degradation of organic compounds by microbial and chemical processes. As a first approximation, some assumptions and simplifications have been considered, probably resulting in a wort case scenario.</p>

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