A Contribution to the Modelling of the Corrosion Process for HLW Glasses

1984 ◽  
Vol 44 ◽  
Author(s):  
R. Conradt ◽  
H. Roggendorf ◽  
H. Scholze

AbstractAn evaluation of a broad set of HLWg lass corrosion data implies that adequate corrosion models must also take into account kinetics slower than √t. Solubility limits may not give a sufficient explanation for these cases. Before all, the long term leach rates are not infinitely small. A proposal is made how “slow” kinetics can be included in a model.

2018 ◽  
Vol 2018 ◽  
pp. 1-10 ◽  
Author(s):  
Dan Su ◽  
Ye Xia ◽  
Robert Yuan

Corrosion is one of the key issues that affect the service life and hinders wide application of steel reinforcement. Moreover, corrosion is a long-term process and not visible for embedded reinforcement. Thus, this research aims at developing a self-powered smart sensor system with integrated innovative prediction module for forecasting corrosion process of embedded steel reinforcement. Vibration-based energy harvester is used to harvest energy for continuous corrosion data collection. Spatial interpolation module was developed to interpolate corrosion data at unmonitored locations. Dynamic prediction module is used to predict the long-term corrosion based on collected data. Utilizing this new sensor network, the corrosion process can be automated predicted and appropriate mitigation actions will be recommended accordingly.


2019 ◽  
Vol 66 (4) ◽  
pp. 403-411 ◽  
Author(s):  
Yuanjie Zhi ◽  
Dongmei Fu ◽  
Tao Yang ◽  
Dawei Zhang ◽  
Xiaogang Li ◽  
...  

PurposeThis study aims to achieve long-term prediction on a specific monotonic data series of atmospheric corrosion rate vs time.Design/methodology/approachThis paper presents a new method, used to the collected corrosion data of carbon steel provided by the China Gateway to Corrosion and Protection, that combines non-linear gray Bernoulli model (NGBM(1,1) with genetic algorithm to attain the purpose of this study.FindingsResults of the experiments showed that the present study’s method is more accurate than other algorithms. In particular, the mean absolute percentage error (MAPE) and the root mean square error (RMSE) of the proposed method in data sets are 9.15 per cent and 1.23 µm/a, respectively. Furthermore, this study illustrates that model parameter can be used to evaluate the similarity of curve tendency between two carbon steel data sets.Originality/valueCorrosion data are part of a typical small-sample data set, and these also belong to a gray system because corrosion has a clear outcome and an uncertainly occurrence mechanism. In this work, a new gray forecast model was proposed to achieve the goal of long-term prediction of carbon steel in China.


2006 ◽  
Vol 321-323 ◽  
pp. 545-548 ◽  
Author(s):  
Asa Prateepasen ◽  
Chalermkiat Jirarungsatean ◽  
Pongsak Tuengsook

In this paper acoustic emission (AE) was implemented to detect and study the corrosion on austenitic stainless steel grade AISI 304. Two tests were conducted at room temperature using an acidic 30% Chloride solution in passive tests procedure and 3% NaCl solution in electrochemical process. From the experimental works, it appeared that AE signals could be detected during corrosion. Data were studied in time and frequency domain to characterize and to find out the relation between AE parameter and corrosion. In addition the source of generated acoustic signals and corrosive mechanism in the different corrosive environment condition were discussed.


Materials ◽  
2021 ◽  
Vol 14 (20) ◽  
pp. 6183
Author(s):  
Jeyaprakash Natarajan ◽  
Che-Hua Yang ◽  
Sundara Subramanian Karuppasamy

316L steel is predominantly used in manufacturing the components of high-pressure boilers, heat exchangers, aerospace engines, oil and gas refineries, etc. Its notable percentage of chromium offers resistance against corrosion and is mostly implemented in harsh environments. However, long-term exposure to these components in such environments can reduce their corrosion resistance property. Particularly at high temperatures, the oxide film formed on this type of steel reacts with the chloride, sulfides, sulfates, fluorides and forms intermetallic compounds which affect its resistance, followed by failures and losses. This work is focused on investigating the hardness, microstructure and corrosion resistance of the laser cladded Colmonoy-6 particles on the 316L steel substrate. The cladded specimens were dissected into cubic shapes and the microstructure present in the cladded region was effectively analyzed using the FESEM along with the corresponding EDS mapping. For evaluating the hardness of the cladded samples, the nanoindentation technique was performed using the TI980 TriboIndenter and the values were measured. The potentiodynamic polarization curves were plotted for both the substrate and clad samples at 0, 18, 42 and 70 h for revealing the corrosion resistance behavior. In addition, the EIS analysis was carried out to further confirm the resistance offered by the samples. The surface roughness morphology was evaluated after the corrosion process using the laser microscope, and the roughness values were measured and compared with the substrate samples. The result showed that the cladded samples experience greater hardness, lower values of surface roughness and provide better corrosion resistance when compared with substrate samples. This is due to the deposition of precipitates of chromium-rich carbide and borides that enhances the above properties and forms a stable passive film that resists corrosion during the corrosion process.


2009 ◽  
pp. 43-43-18
Author(s):  
DO Spatig ◽  
WH Ailor
Keyword(s):  

CORROSION ◽  
10.5006/2706 ◽  
2018 ◽  
Vol 74 (6) ◽  
pp. 669-682 ◽  
Author(s):  
Yi-kun Cai ◽  
Yu Zhao ◽  
Xiao-bing Ma ◽  
Kun Zhou ◽  
Hao Wang

This paper deals with the prediction of long-term atmospheric corrosion in different field environments using the power-linear function. A method for the calculation of exponent n and stationary corrosion rate α in the power-linear function is proposed based on the 1- and 8-y corrosion loss results (C1 and C8) of the ISO CORRAG program. The response surface method and the artificial neural network methodology are used to obtain the accurate estimation of C1 and C8 in different locations using environmental variables. Considering the uncertainty of the model and the experimental data, the confidence intervals of n and α are also calculated. It is shown that the long-term predictions obtained by the proposed method coincide with the actual corrosion loss within ±30% relative error. The estimations for the range of the long-term corrosion loss are also reliable. The proposed method is helpful in extrapolating the knowledge of corrosion management to different field environments where corrosion data are not available.


2016 ◽  
Vol 6 (3) ◽  
pp. 365-374 ◽  
Author(s):  
Yuanjie Zhi ◽  
Dongmei Fu ◽  
Hanling Wang

Purpose The purpose of this paper is to present a new model which combines the non-equidistant GM(1,1) model with GCHM_WBO (generalized contra-harmonic mean (GCHM); weakening buffer operator (WBO)). The authors use the model to solve the deadlock that for a large number of non-equidistant corrosion rate, it is difficult to establish a reasonable prediction model and improve the prediction accuracy. Design/methodology/approach This research consists of three parts: non-equidistant GM(1,1) model, GCHM_WBO operator, and the optimization of morphing parameter (contained in GCHM, control the intensity of the weakening operator). The methodology is explained as follows. First, the authors built a non-equidistant GM(1,1) model with GCHM_WBO weakened data, of which morphing parameter was randomly selected. Next, the authors calculated the error between prediction data of model and the real data, and adjusted the morphing parameter according to the error and property of GCHM. Then, the authors generated a new non-equidistant GM(1,1) based on new morphing parameter, and repeated the previous step until the termination condition was satisfied. Finally, the model with appropriate morphing parameter was used to implement the prediction of new data. Findings This paper finds a property of GCHM, which is a monotonic increasing function of morphing parameter in some specific conditions. Based on the property and the fixed point axiom of WBO, an algorithm was designed to search an appropriate morphing parameter. The appropriate morphing parameter was implemented for the purpose of improving the accuracy of the model. The model was applied to predict the corrosion rate of six steels at Guangzhou experimental station. The results showed that the proposed method can get more accuracy in prediction capability compared to the models with the original data and AWBO weakened data. The method is applicable to long-term forecasts in case of data scarcity. Practical implications Corrosion will cause huge economic loss to a country; therefore, it is important to judge the remaining useful life of a material or equipment; the foundation for judgement of which is the prediction of material corrosion rate. However, the prediction of corrosion rate is very difficult because of corrosion data’s features, such as small sample size, non-equidistant, etc. The proposed method can be used to implement long-term forecast of corrosion data with only one sample and non-equidistant samples. Originality/value This paper presented a model which combines the non-equidistant GM(1,1) model with GCHM_WBO to handle the problem of long-term forecasting of corrosion data. In the modelling process, the proposed morphing parameter searched through algorithm can improve the prediction accuracy of the model. Therefore, the model can provide effective and reliable result when data are of a small sample size and non-equidistant.


2011 ◽  
Vol 208 (3) ◽  
pp. 439-454 ◽  
Author(s):  
Claudia R. Ruprecht ◽  
Anders Krarup ◽  
Lucy Reynell ◽  
Axel M. Mann ◽  
Oliver F. Brandenberg ◽  
...  

Interference with virus entry is known to be the principle mechanism of HIV neutralization by antibodies, including 2F5 and 4E10, which bind to the membrane-proximal external region (MPER) of the gp41 envelope protein. However, to date, the precise molecular events underlying neutralization by MPER-specific antibodies remain incompletely understood. In this study, we investigated the capacity of these antibodies to irrevocably sterilize HIV virions. Long-term effects of antibodies on virions can differ, rendering neutralization either reversible or irreversible. MPER-specific antibodies irreversibly neutralize virions, and this capacity is associated with induction of gp120 shedding. Both processes have similar thermodynamic properties and slow kinetics requiring several hours. Antibodies directed to the CD4 binding site, V3 loop, and the MPER can induce gp120 shedding, and shedding activity is detected with high frequency in plasma from patients infected with divergent genetic HIV-1 subtypes. Importantly, as we show in this study, induction of gp120 shedding is closely associated with MPER antibody inhibition, constituting either a primary event leading to virion neutralization or representing an immediate consequence thereof, and thus needs to be factored into the mechanistic processes underlying their activity.


1987 ◽  
Vol 112 ◽  
Author(s):  
G. P. Marsh

AbstractThe prediction of the long term corrosion of metal containers for nuclear waste under geological disposal conditions requires the extrapolation of corrosion data over several hundred years. There is a general trend to use either simulation or ‘worst case’ experiments as a means of materials selection, but neither really addresses the problem of long term extrapolation. It is proposed that such an extrapolation can only be done convincingly if it is based on a sound and generally accepted mechanistic understanding of the processes involved. If such knowledge does not exist the first step must be to acquire it through experimental mechanistic studies. Subsequently such knowledge should be formulated into mathematical models, which can be used to make long term predictions, and which can be validated by comparison with short term experimental results. The application of this combined mathematical modelling/experimental approach is illustrated for three corrosion processes which may affect carbon steel containers, namely general corrosion, localised attack and stress corrosion cracking.


eLife ◽  
2018 ◽  
Vol 7 ◽  
Author(s):  
Judy Lisette Martin ◽  
Erin Nicole Sanders ◽  
Paola Moreno-Roman ◽  
Leslie Ann Jaramillo Koyama ◽  
Shruthi Balachandra ◽  
...  

Organ renewal is governed by the dynamics of cell division, differentiation and loss. To study these dynamics in real time, we present a platform for extended live imaging of the adult Drosophila midgut, a premier genetic model for stem-cell-based organs. A window cut into a living animal allows the midgut to be imaged while intact and physiologically functioning. This approach prolongs imaging sessions to 12–16 hr and yields movies that document cell and tissue dynamics at vivid spatiotemporal resolution. By applying a pipeline for movie processing and analysis, we uncover new and intriguing cell behaviors: that mitotic stem cells dynamically re-orient, that daughter cells use slow kinetics of Notch activation to reach a fate-specifying threshold, and that enterocytes extrude via ratcheted constriction of a junctional ring. By enabling real-time study of midgut phenomena that were previously inaccessible, our platform opens a new realm for dynamic understanding of adult organ renewal.


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