scholarly journals Optical Properties of Multi-Component Cadmium-Silver Nanocluster Composites Formed in Silica by Sequential Ion Implantation

1996 ◽  
Vol 438 ◽  
Author(s):  
R. A. Zuhr ◽  
R. H. Magruder ◽  
T. S. Anderson

AbstractThe formation and optical properties of nanometer dimension metal colloid composites formed by the sequential implantation of Cd then Ag and by single element implantations of Cd and Ag in silica were characterized by transmission electron microscopy (TEM) and optical spectroscopy. A nominal dose of 6×1016 ions/cm2 as determined by current integration was used for both ion species. The doses used for the sequential implantations were a 1 to 1 ratio of Cd to Ag. Sequential implantations of Cd and Ag led to the formation of both multi-component metal nanoclusters and elemental nanoclusters. The electron diffraction measurements indicated that the polycrystalline particles of Ag5Cd8 and elemental Ag were formed. The optical response was consistent with results expected from effective medium theory.

2001 ◽  
Vol 666 ◽  
Author(s):  
Annette Hultåker ◽  
Jun Lu ◽  
Eva Olsson ◽  
Gunnar A. Niklasson ◽  
Claes-Göran Granqvist

ABSTRACTThin films of intermixed layers of In2O3:Sn (denoted ITO) and silver were made by reactive dc magnetron sputtering. The silver to indium atomic ratio was 0 ≤ x ≥ 0.09 Films with x = 0.01 showed increased luminous transmittance Tlum after annealing at 100 or 200°C, whereas x > 0.01 yielded lowered Tlum. The optical properties could be reconciled with the Maxwell-Garnett effective medium theory assuming that a well-defined portion of the silver was occluded as spheroidal particles. Films with x ≤ 0.06 had enhanced electrical conductivity after annealing at 200 or 300°C. Transmission electron microscopy displayed columnar features whose character depended on x.


2002 ◽  
Vol 715 ◽  
Author(s):  
Kyung Hoon Jun ◽  
Helmut Stiebig ◽  
Reinhard Carius

AbstractThe effect of the microstructure and bonded hydrogen on the optical properties of microcrystalline films (μc-Si:H) was investigated by Spectroscopic Ellipsometry (SE) and Photothermal Deflection Spectroscopy (PDS). On samples with a high crystalline volume fraction we studied the reason for a large deviation of absorption coefficient in the energy range between 1.6 eV and 3.2 eV from the value predicted by effective medium theory. This enhancement can be attributed to scattering by the inhomogeneity of μc-Si:H, which is investigated by the introduction of the dense medium radiative transfer formalism to an optical scattering simulation. Further, we suggest strain as a reason for the enhanced absorption in highly crystalline μc-Si:H.


Vacuum ◽  
1998 ◽  
Vol 50 (1-2) ◽  
pp. 49-51
Author(s):  
E Dobierzewska-Mozrzymas ◽  
P Biegański ◽  
E Pieciul ◽  
J Wójcik

1994 ◽  
Vol 50 (16) ◽  
pp. 12073-12077 ◽  
Author(s):  
Z. Q. Wang ◽  
D. Stroud ◽  
S. A. Dregia

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