Correlation of Molecular Structures and Properties on Diphenyl-Diacetylene Liquid Crystals

1996 ◽  
Vol 425 ◽  
Author(s):  
S. T. Wu ◽  
C. S. Hsu

AbstractEffects of molecular structures on the phase transition temperatures, dielectric anisotropy, elastic constant, and refractive indices of diphenyl-diacetylene liquid crystals are analyzed.

2012 ◽  
Vol 2012 ◽  
pp. 1-8 ◽  
Author(s):  
S. Sreehari Sastry ◽  
B. Gowri Sankara Rao ◽  
K. B. Mahalakshmi ◽  
K. Mallika ◽  
C. Nageswara Rao ◽  
...  

Phase transition temperatures of ferroelectric liquid crystals ((S)-(-)-2-methylbutyl 4′-(4″-n-alkanoyloxybenzoyloxy) biphenyl-4-carboxylates (where n=16 and 18)) are studied through two techniques of image analysis. One is a statistical method, applied to compute the statistical parameters from the textures of each sample and the other, computation of Legendre moments being applied as image moment analysis, both of which are considered as a function of temperature. The textures of the samples are recorded with the polarizing optical microscope (POM) attached to the hot stage and high resolution camera. The phase transition temperatures of samples are inferred by the abrupt changes in the computed parameter values. The results obtained from the present methodology are in good agreement with those published in earlier literature done by the different techniques, like differential scanning calorimetry (DSC).


2012 ◽  
Vol 2012 ◽  
pp. 1-9 ◽  
Author(s):  
S. Sreehari Sastry ◽  
T. Vindhya Kumari ◽  
C. Nageswara Rao ◽  
K. Mallika ◽  
S. Lakshminarayana ◽  
...  

This paper presents a method which combines the statistical analysis with texture structural analysis called Local Binary Gray Level Cooccurrence Matrix (LBGLCM) to investigate the phase transition temperatures of thermotropicp,n-alkyloxy benzoic acid (nOBA,n=4,6,8,10and 12) liquid crystals. Textures of the homeotropically aligned liquid crystal compounds are recorded as a function of temperature using polarizing optical microscope attached to the hot stage and high resolution camera. In this method, second-order statistical parameters (contrast, energy, homogeneity, and correlation) are extracted from the LBGLCM of the textures. The changes associatedwiththe values of extracted parameters as a function of temperature are a helpful process to identify the phases and phase transition temperatures of the samples. Results obtained from this method have validity and are in good agreement with the literature.


RSC Advances ◽  
2021 ◽  
Vol 11 (29) ◽  
pp. 17622-17629
Author(s):  
Ae Ran Lim

We studied the thermal behavior and structural dynamics of [NH3(CH2)3NH3]CdBr4 near phase transition temperatures.


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