Strategies for Conducting Polymer Solutions: Solvato-Controlled Oxidative Doping Using Metal Cations

1995 ◽  
Vol 413 ◽  
Author(s):  
M. Lebedev ◽  
S. Holdcroft
Keyword(s):  
Charge Transfer ◽  
Polymer Film ◽  
Conducting Polymer ◽  
Charge Transfer Complex ◽  
Conjugated Systems ◽  
Oxidative Doping ◽  
New Strategy ◽  
A Charge ◽  
Doped Polymer ◽  
Enhanced Stability

ABSTRACTSolutions of Ag(I) and poly(3-alkylthiophenes), which usually precipitate immediately upon contact, are stabilized with Ag(l)-coordinating ligands. Casting of polymer-Ag(I)-ligand solutions followed by evaporation of the ligand yields an electronically conducting polymer film. It is postulated that Ag(I) either undergoes nucleophillic addition to poly(3-alkylthiophenes), in a manner similar to which polythiophenes are protonated by acids, or forms a charge transfer complex with the polymer. The “doped” polymer exhibits enhanced stability over films oxidized using conventional oxidants. Ag(I)-doping of poly(3-alkylthiophenes) represents a new strategy for doping conjugated systems.

scholarly journals Multi-configurational Ehrenfest simulations of ultrafast nonadiabatic dynamics in a charge-transfer complex

2018 ◽  
Vol 149 (24) ◽  
pp. 244107 ◽  
Author(s):  
Tianji Ma ◽  
Matteo Bonfanti ◽  
Pierre Eisenbrandt ◽  
Rocco Martinazzo ◽  
Irene Burghardt
Keyword(s):  
Charge Transfer ◽  
Charge Transfer Complex ◽  
Nonadiabatic Dynamics ◽  
A Charge

The Reagent Diphenyldiselane/Iodine: No Phenylselenenyl Iodide but a Charge Transfer Complex with Cyclic Moieties

1988 ◽  
Vol 27 (3) ◽  
pp. 431-433 ◽  
Author(s):  
Silvia Kubiniok ◽  
Wolf-Walther du Mont ◽  
Siegfried Pohl ◽  
Wolfgang Saak
Keyword(s):  
Charge Transfer ◽  
Charge Transfer Complex ◽  
A Charge

Possible low-temperature phase transition of Langmuir–Blodgett films of a charge–transfer complex detected by ESR

1998 ◽  
Vol 327-329 ◽  
pp. 391-394
Author(s):  
Keiichi Ikegami ◽  
Shin-ichi Kuroda ◽  
Tomoyuki Akutagawa ◽  
Taro Konuma ◽  
Takayoshi Nakamura ◽  
...  
Keyword(s):  
Phase Transition ◽  
Charge Transfer ◽  
Low Temperature ◽  
Charge Transfer Complex ◽  
Temperature Phase ◽  
Langmuir Blodgett ◽  
Langmuir Blodgett Films ◽  
Temperature Phase Transition ◽  
A Charge ◽  
Low Temperature Phase

Boron-based binary Be6B102− cluster: three-layered aromatic sandwich, electronic transmutation, and dynamic structural fluxionality

2018 ◽  
Vol 20 (35) ◽  
pp. 22719-22729 ◽  
Author(s):  
Lin-Yan Feng ◽  
Jin-Chang Guo ◽  
Peng-Fei Li ◽  
Hua-Jin Zhai
Keyword(s):  
Charge Transfer ◽  
Charge Transfer Complex ◽  
Dual Mode ◽  
A Charge

A triple-ring sandwich Be6B102− cluster is a charge-transfer complex, which features four-fold π/σ aromaticity, electronic transmutation, and dual-mode dynamic fluxionality.

Flow Orientation in Langmuir-Blodgett Films of a Charge-Transfer Complex (TMTTF)3(C14TCNQ)2

1992 ◽  
Vol 31 (Part 1, No. 4) ◽  
pp. 1206-1212 ◽  
Author(s):  
Keiichi Ikegami ◽  
Shin-ichi Kuroda ◽  
Yuka Tabe ◽  
Kazuhiro Saito ◽  
Michio Sugi ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Charge Transfer Complex ◽  
Langmuir Blodgett ◽  
Langmuir Blodgett Films ◽  
A Charge
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