In-Plane Permittivity of Spin-Cast Polymer Films

1995 ◽  
Vol 411 ◽  
Author(s):  
Shari A. Weinberg ◽  
Sue Ann Bidstrup-Allen
Keyword(s):  
Refractive Index ◽  
Electrical Properties ◽  
Polymer Films ◽  
Three Dimensional ◽  
Polymeric Materials ◽  
Polymer Chains ◽  
Electronic Packages ◽  
Polyimide Films ◽  
Element Analysis ◽  
Permittivity Measurements

ABSTRACTPolymeric materials such as polyimides are used in a multitude of microelectronic applications including interlevel dielectrics for insulation. Polyimide films have shown a difference between the through-plane and in-plane refractive index measurements.(1,2,3) This anisotropy in optical properties has been attributed to in-plane orientation of polymer chains and implies anisotropy in electrical properties. Thus, it is necessary to measure the electrical properties in both the in-plane and through-plane directions to accurately design three-dimensional electronic packages. The purpose of this research is to develop an in-situ technique to measure the in-plane permittivity of these spin-coated polymer films. Using capacitance measurements obtained from interdigitated electrodes, through-plane permittivity measurements, and ANSYS finite element analysis software, the in-plane permittivity of a given material can be determined. Several polyimide systems including Du Pont PI-2611 (BPDA-PPD), Du Pont PI-2540 (PMDA-ODA), and Probimide 293 (BTDA-DAPI) from OCG Microelectronics, as well as Cyclotene 3022 (BCB) from Dow Chemical were investigated. Anisotropy in the permittivity was observed in the three polyimide films, but not in the BCB film. Results were compared with predictions using refractive index measurements and a modified form of Maxwell's equation.

Rheology of Adhesion

1972 ◽  
Vol 45 (6) ◽  
pp. 1604-1622 ◽  
Author(s):  
D. H. Kaelble
Keyword(s):  
Polymer Composites ◽  
Three Dimensional ◽  
Polymeric Materials ◽  
Intermolecular Forces ◽  
Adhesive Joints ◽  
Polymer Chains ◽  
System Response ◽  
Ample Evidence ◽  
Volume State ◽  
And Performance

Abstract This discussion has outlined a series of considerations which begin with engineering definitions of system response of adhesive joints and end with propositions involving molecular interactions at interfaces. Connecting these extreme aspects of the argument is the central subject of the micromechanics of bonding and fracture. Cavitation theory, as simply described by Equations (6a) and (7), illustrates the scale of microresponse in which both the thermodynamic and rheological aspects of adhesion phenomena achieve a parity when applied to cavities of radius r=0.1 to 10 μ. The discussion of the micromechanics of polymer fracture provides ample evidence that pure materials, polymer composites, and adhesive joints, need to be described in terms of their microdefects. The several mathematical models for crack propagation which are imposed upon fracture mechanics data tend to oversimplify the visualization of the true micromechanisms of fracture. The fuller development of micromechanics theory and experimental analysis promises to be an important area of current developments in the better understanding of macroscopic response of filled systems, fiber reinforced composites, and adhesively bonded structures. Recent developments in the several theories of intermolecular forces and the physical chemistry of bonding provide new impetus to the chemist to design optimized polymeric materials with finely adjusted balances of surface and bulk properties. The fuller visualization of adsorption-interdiffusion bonding as a process involving both the two-dimensional interface and the three-dimensional interphase defines bonding as both a thermodynamical and a rheological process. The microstages of bond formation are somewhat the reverse of the stages of microfracture listed earlier. The microdefects that commonly exist in polymeric materials and polymer composites tend to indicate that the viscoelastic constraints typical of polymer chains and networks play an important role in preventing equilibrium bonding in the simple thermodynamic sense as expressed by idealized liquid—liquid or liquid—solid interactions. The current development and application of a refined thermodynamical and rheological argument to both bonding and fracture processes stands as a central issue in directly correlating the molecular criteria of adhesion and performance of bonded systems. Any of the simple mathematical relations introduced in this discussion may be expressed with greater detail and precision by incorporating detailed statements concerning chemical composition, macromolecular structure, and free volume state of the polymeric adhesive.

Scanning-tunneling spectroscopy on conjugated polymer films

2003 ◽  
Vol 771 ◽  
Author(s):  
M. Kemerink ◽  
S.F. Alvarado ◽  
P.M. Koenraad ◽  
R.A.J. Janssen ◽  
H.W.M. Salemink ◽  
...  
Keyword(s):  
Polymer Films ◽  
Conjugated Polymer ◽  
Three Dimensional ◽  
Field Enhancement ◽  
Direct Consequence ◽  
Scanning Tunneling Spectroscopy ◽  
Tunneling Spectroscopy ◽  
Band Alignment ◽  
Scanning Tunneling ◽  
Order Of Magnitude

AbstractScanning-tunneling spectroscopy experiments have been performed on conjugated polymer films and have been compared to a three-dimensional numerical model for charge injection and transport. It is found that field enhancement near the tip apex leads to significant changes in the injected current, which can amount to more than an order of magnitude, and can even change the polarity of the dominant charge carrier. As a direct consequence, the single-particle band gap and band alignment of the organic material can be directly obtained from tip height-voltage (z-V) curves, provided that the tip has a sufficiently sharp apex.

Effects of occlusal scheme on All-on-Four abutments, screws and prostheses: A three-dimensional finite element study

2020 ◽  
Author(s):  
Nurullah Türker ◽  
Hümeyra Tercanlı Alkış ◽  
Steven J Sadowsky ◽  
Ulviye Şebnem Büyükkaplan
Keyword(s):  
Finite Element ◽  
Three Dimensional ◽  
Good Prognosis ◽  
Von Mises Stress ◽  
Element Analysis ◽  
Group Function ◽  
Occlusal Contact ◽  
Maximum Deformation ◽  
Contact Points ◽  
Von Mises

An ideal occlusal scheme plays an important role in a good prognosis of All-on-Four applications, as it does for other implant therapies, due to the potential impact of occlusal loads on implant prosthetic components. The aim of the present three-dimensional (3D) finite element analysis (FEA) study was to investigate the stresses on abutments, screws and prostheses that are generated by occlusal loads via different occlusal schemes in the All-on-Four concept. Three-dimensional models of the maxilla, mandible, implants, implant substructures and prostheses were designed according to the All-on-Four concept. Forces were applied from the occlusal contact points formed in maximum intercuspation and eccentric movements in canine guidance occlusion (CGO), group function occlusion (GFO) and lingualized occlusion (LO). The von Mises stress values for abutment and screws and deformation values for prostheses were obtained and results were evaluated comparatively. It was observed that the stresses on screws and abutments were more evenly distributed in GFO. Maximum deformation values for prosthesis were observed in the CFO model for lateral movement both in the maxilla and mandible. Within the limits of the present study, GFO may be suggested to reduce stresses on screws, abutments and prostheses in the All-on-Four concept.

Towards Predicting Relative Belt Edge Endurance With the Finite Element Method

1990 ◽  
Vol 18 (4) ◽  
pp. 216-235 ◽  
Author(s):  
J. De Eskinazi ◽  
K. Ishihara ◽  
H. Volk ◽  
T. C. Warholic
Keyword(s):  
Finite Element Method ◽  
Finite Element ◽  
Three Dimensional ◽  
The Finite Element Method ◽  
Shear Deformations ◽  
Element Analysis ◽  
Vertical Loading ◽  
Predicted Values ◽  
Element Method

Abstract The paper describes the intention of the authors to determine whether it is possible to predict relative belt edge endurance for radial passenger car tires using the finite element method. Three groups of tires with different belt edge configurations were tested on a fleet test in an attempt to validate predictions from the finite element results. A two-dimensional, axisymmetric finite element analysis was first used to determine if the results from such an analysis, with emphasis on the shear deformations between the belts, could be used to predict a relative ranking for belt edge endurance. It is shown that such an analysis can lead to erroneous conclusions. A three-dimensional analysis in which tires are modeled under free rotation and static vertical loading was performed next. This approach resulted in an improvement in the quality of the correlations. The differences in the predicted values of various stress analysis parameters for the three belt edge configurations are studied and their implication on predicting belt edge endurance is discussed.

Torsional Analysis of a Steel Cord-Rubber Tire Belt Structure

1996 ◽  
Vol 24 (4) ◽  
pp. 339-348 ◽  
Author(s):  
R. M. V. Pidaparti
Keyword(s):  
Finite Element ◽  
Finite Element Model ◽  
Composite Structures ◽  
Three Dimensional ◽  
Element Model ◽  
Torsional Stiffness ◽  
Element Analysis ◽  
Rubber Belt ◽  
Steel Cord ◽  
Torsional Analysis

Abstract A three-dimensional (3D) beam finite element model was developed to investigate the torsional stiffness of a twisted steel-reinforced cord-rubber belt structure. The present 3D beam element takes into account the coupled extension, bending, and twisting deformations characteristic of the complex behavior of cord-rubber composite structures. The extension-twisting coupling due to the twisted nature of the cords was also considered in the finite element model. The results of torsional stiffness obtained from the finite element analysis for twisted cords and the two-ply steel cord-rubber belt structure are compared to the experimental data and other alternate solutions available in the literature. The effects of cord orientation, anisotropy, and rubber core surrounding the twisted cords on the torsional stiffness properties are presented and discussed.

Finite Element Modeling for Steel Cord Analysis in Radial Tires

2013 ◽  
Vol 41 (1) ◽  
pp. 60-79 ◽  
Author(s):  
Wei Yintao ◽  
Luo Yiwen ◽  
Miao Yiming ◽  
Chai Delong ◽  
Feng Xijin
Keyword(s):  
Finite Element ◽  
High Efficiency ◽  
Force Measurement ◽  
Three Dimensional ◽  
Local Stress ◽  
Tension Force ◽  
Center Line ◽  
Element Analysis ◽  
Design Variables ◽  
Steel Cord

ABSTRACT: This article focuses on steel cord deformation and force investigation within heavy-duty radial tires. Typical bending deformation and tension force distributions of steel reinforcement within a truck bus radial (TBR) tire have been obtained, and they provide useful input for the local scale modeling of the steel cord. The three-dimensional carpet plots of the cord force distribution within a TBR tire are presented. The carcass-bending curvature is derived from the deformation of the carcass center line. A high-efficiency modeling approach for layered multistrand cord structures has been developed that uses cord design variables such as lay angle, lay length, and radius of the strand center line as input. Several types of steel cord have been modeled using the developed method as an example. The pure tension for two cords and the combined tension bending under various loading conditions relevant to tire deformation have been simulated by a finite element analysis (FEA). Good agreement has been found between experimental and FEA-determined tension force-displacement curves, and the characteristic structural and plastic deformation phases have been revealed by the FE simulation. Furthermore, some interesting local stress and deformation patterns under combined tension and bending are found that have not been previously reported. In addition, an experimental cord force measurement approach is included in this article.

Finite Element Analysis of Nonuniformity of Tires with Imperfections5

2007 ◽  
Vol 35 (3) ◽  
pp. 226-238 ◽  
Author(s):  
K. M. Jeong ◽  
K. W. Kim ◽  
H. G. Beom ◽  
J. U. Park
Keyword(s):  
Finite Element Analysis ◽  
Finite Element ◽  
Three Dimensional ◽  
Element Model ◽  
Radial Force ◽  
Element Analysis ◽  
The Finite Element Analysis ◽  
Dimensional Finite Element ◽  
Force Variation ◽  
Three Dimensional Finite Element

Abstract The effects of variations in stiffness and geometry on the nonuniformity of tires are investigated by using the finite element analysis. In order to evaluate tire uniformity, a three-dimensional finite element model of the tire with imperfections is developed. This paper considers how imperfections, such as variations in stiffness or geometry and run-out, contribute to detrimental effects on tire nonuniformity. It is found that the radial force variation of a tire with imperfections depends strongly on the geometrical variations of the tire.

Optical and Electrical Properties of Organic Conducting Polymers

2014 ◽  
Vol 8 (1) ◽  
pp. 1457-1463
Author(s):  
Salah Abdulla Hasoon
Keyword(s):  
Electrical Properties ◽  
Conjugated Polymer ◽  
Polymeric Materials ◽  
Quantum Mechanical ◽  
Optical And Electrical Properties ◽  
Electrically Conducting ◽  
Temperature Ranges ◽  
Lithium Tetrafluoroborate ◽  
Absorbance Peak ◽  
Polymerization Method

Novel electrically conducting polymeric materials are prepared in this work. Polythiophene (PT) and poly (3-Methelthiophene) (P3MT) films were prepared by electro-polymerization method using cyclic voltammetry in acetonitrile as a solvent and lithium tetrafluoroborate as the electrolyte on a gold electrode. Electrical properties of P3MT have been examined in different environments using UV-Vis absorption spectroscopy and quantum mechanical ab initio calculations, The observed absorption peaks at 314 and 415 nm, were attributed to the n-π* and π-π* transitions, respectively in the conjugated polymer chain, in contrast, the observed absorbance peak at 649 nm, is responsible for electric conduction. The temperature dependence of the conductivity can be fitted to the Arrhenius and the VTF equations in different temperature ranges.

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