Microstructural Stability of Stressed Lamellar Eutectics

1995 ◽  
Vol 398 ◽  
Author(s):  
N. Sridhar ◽  
J.M. Rickman ◽  
D.J. Srolovitz
Keyword(s):  
Elevated Temperatures ◽  
Operating Conditions ◽  
Microstructural Stability ◽  
Lamellar Eutectic ◽  
Stability Diagrams ◽  
Flat Interface ◽  
Surrounding Matrix ◽  
Critical Wavelength ◽  
The Matrix ◽  
Enhance Mass

ABSTRACTAt elevated temperatures, stresses enhance mass transport at the microstructural scale and under certain conditions, lead to microstructural instabilities. Using a linear stability analysis, we examine the effect of stresses on the morphological stability of plate-like phases and lamellar eutectic composites. These stresses can be either due to misfit strains and/or due to externally applied loads. We find that for misfitting plates, the nominally flat plate-matrix interface is unstable with respect to the growth of perturbations with wavelengths greater than a critical wavelength, provided that the reinforcing plates are elastically suffer than the surrounding matrix. On the other hand, for stresses generated by externally applied loads, the flat interface is always unstable as long as the plate modulus and the matrix modulus are not identical. In addition, the analysis reveals that misfit strains can either counteract or enhance the destabilizing influence of applied loads depending on the elastic properties of the plate and the matrix. Finally, we have developed stability diagrams that identify material properties and operating conditions required to maintain a stable interface in these lamellar eutectic composites.

Buckling of Microfibers

1967 ◽  
Vol 34 (4) ◽  
pp. 1011-1016 ◽  
Author(s):  
M. A. Sadowsky ◽  
S. L. Pu ◽  
M. A. Hussain
Keyword(s):  
Elevated Temperatures ◽  
Thermal Characteristics ◽  
Compressive Force ◽  
Theory Of Elasticity ◽  
Primary Objective ◽  
Infinite Length ◽  
Volume Percentage ◽  
Initial Strength ◽  
Surrounding Matrix ◽  
The Matrix

Most composites are fabricated at elevated temperatures and cooled to room temperature. The difference in coefficients of thermal expansion of the fiber and matrix may cause buckling of the slender-shaped microfibers. This would greatly reduce the initial strength of the composites. The primary objective of this paper is to explain qualitatively the basic phenomenon of buckled microfibers in a composite and to present some numerical results in certain ranges of elastic parameters. Our analysis is based on assumptions that (a) the volume percentage of fibers is small so that the mutual interference of fibers is negligible and the matrix surrounding a fiber may be considered as infinitely large; (b) the diameter of the fiber is very small in comparison to its length so that the fiber may be treated as a linear fiber with infinite length; (c) the constituents are homogeneous and isotropic and the classical linear theory of elasticity may be applied; and, (d) in the process of cooling, the fiber is subjected to compression but not twisting moment by the surrounding matrix. The analysis leads to a relation between the pertinent elastic and thermal characteristics of the matrix and microfiber and the compressive force along the axis of the microfiber at the critical moment of incipient buckling. With the knowledge of that relation, it is now possible to know in advance whether or not buckling is to be expected and to avoid such manufacturing methods in which a threat of having buckled microfibers is present.

High-Temperature Instability of A Cr2Nb-Nb(Cr) Microlaminate Composite

1996 ◽  
Vol 54 ◽  
pp. 374-375
Author(s):  
M. Larsen ◽  
R.G. Rowe ◽  
D.W. Skelly
Keyword(s):  
Heat Treatment ◽  
Solid Solution ◽  
High Temperature ◽  
Elevated Temperatures ◽  
Aircraft Engine ◽  
Lattice Parameter ◽  
Microstructural Stability ◽  
Elevated Temperature Strength ◽  
Cross Sectional ◽  
Bcc Structure

Microlaminate composites consisting of alternating layers of a high temperature intermetallic compound for elevated temperature strength and a ductile refractory metal for toughening may have uses in aircraft engine turbines. Microstructural stability at elevated temperatures is a crucial requirement for these composites. A microlaminate composite consisting of alternating layers of Cr2Nb and Nb(Cr) was produced by vapor phase deposition. The stability of the layers at elevated temperatures was investigated by cross-sectional TEM.The as-deposited composite consists of layers of a Nb(Cr) solid solution with a composition in atomic percent of 91% Nb and 9% Cr. It has a bcc structure with highly elongated grains. Alternating with this Nb(Cr) layer is the Cr2Nb layer. However, this layer has deposited as a fine grain Cr(Nb) solid solution with a metastable bcc structure and a lattice parameter about half way between that of pure Nb and pure Cr. The atomic composition of this layer is 60% Cr and 40% Nb. The interface between the layers in the as-deposited condition appears very flat (figure 1). After a two hour, 1200 °C heat treatment, the metastable Cr(Nb) layer transforms to the Cr2Nb phase with the C15 cubic structure. Grain coarsening occurs in the Nb(Cr) layer and the interface between the layers roughen. The roughening of the interface is a prelude to an instability of the interface at higher heat treatment temperatures with perturbations of the Cr2Nb grains penetrating into the Nb(Cr) layer.

ANALYSIS OF PROTEOGLYCAN GENE EXPRESSION IN CONNECTIVE TISSUES BY SEMI-QUANTITATIVE RT-PCR

2001 ◽  
Vol 05 (02) ◽  
pp. 79-88
Author(s):  
K. Dobra ◽  
A. Hjerpe
Keyword(s):  
Rt Pcr ◽  
Connective Tissues ◽  
Surrounding Matrix ◽  
Cell Proliferation And Differentiation ◽  
Extracellular Matrix Components ◽  
Proliferation And Differentiation ◽  
The Matrix ◽  
Quantitative Changes ◽  
Regulatory Functions ◽  
Multiple Samples

Proteoglycans (PGs) are cell-membrane and extracellular matrix components with a wide variety of different functions. In the matrix, they are mainly of structural importance, although some of them have been ascribed specific regulatory functions, such as in the assembly of collagen fibers. PGs on the cell surface act as essential modulators of specific ligand-binding reactions, involving interactions between adjacent cells and between cells and surrounding matrix. Through these interactions they participate in different processes, including cell proliferation and differentiation. Qualitative and quantitative changes in PG expression can therefore be associated with various physiological and pathological conditions. We have optimized the conditions for semi-quantitative evaluation of proteoglycan expression by RT-PCR reaction, using glyceraldehyde-3-phosphate dehydrogenase (GAPDH) as reference gene. The relative fluorescence of analyte to reference amplimers can — within certain limits — be used to estimate the amount of target RNA and allows direct comparison of multiple samples. The profile of PG expression obtained in this way can be used to extend our current understanding of the possible functions that can be associated with these complex molecules.

Small Lead and Indium Inclusions in Aluminium

1991 ◽  
Vol 235 ◽  
Author(s):  
E. Johnson ◽  
K. Hjemsted ◽  
B. Schmidt ◽  
K. K. Bourdelle ◽  
A. Johansen ◽  
...  
Keyword(s):  
Melting Point ◽  
Elevated Temperatures ◽  
Supersaturated Solution ◽  
In Situ Tem ◽  
Initial Growth ◽  
Heating And Cooling ◽  
Moiré Fringes ◽  
The Matrix ◽  
Spontaneous Phase

ABSTRACTIon implantation of lead or indium into aluminium results in spontaneous phase separation and formation of lead or indium precipitates. The precipitates grow in topotactical alignment with the matrix, giving TEM images characterized by moiré fringes. The size and density of the precipitates increase with increasing fluence until coalescence begins to occur. Implantations at elevated temperatures lead to formation of larger precipitates with well developed facets. This is particularly significant for implantations above the bulk melting point of the implanted species. Melting and solidification have been followed by in-situ TEM heating and cooling experiments. Superheating up to ∼ 50 K above the bulk melting point has been observed, and the largest inclusions melt first. Melting is associated with only partial loss of facetting of the largest inclusions. Initial growth of the inclusions occurs by trapping of atoms retained in supersaturated solution. Further growth occurs by coalescence of neighbouring inclusions in the liquid phase. Solidification is accompanied by a strong undercooling ∼ 30 K below the bulk melting point, where the smallest inclusions solidify first. Solidification is characterized by spontaneous restoration of the facets and the topotactical alignment.

Microstructural Stability and Lattice Misfit Characterisations of Nimonic 263

2012 ◽  
Author(s):  
Quanshun Luo ◽  
Kuangnan Chi ◽  
Shuxin Li ◽  
Pete Barnard
Keyword(s):  
Grain Boundary ◽  
Morphological Evolution ◽  
Lattice Misfit ◽  
Initial Growth ◽  
Microstructural Stability ◽  
Gaussian Peak ◽  
Hardening Treatment ◽  
The Matrix ◽  
Matrix Lattice ◽  
Average Size

Nimonic 263 has been selected as a candidate header/piping material of advanced ultra-supercritical (A-USC) boilers for the next generation of fossil fuel power plant. Experimental assessments on the microstructural stability of this material are presented in this paper. Microstructural evolution has been quantified by high resolution field emission SEM and TEM. Electron diffraction and the combined XRD and Gaussian peak-fitting have been applied to investigate the coherency and lattice misfit between the gamma prime (γ′) precipitates and the gamma (γ) matrix. The micro structure subjected to solution and hardening treatment consists of γ-matrix and a network of carbide precipitates along the grain boundaries. Large quantities of fine γ′-Ni3(Ti,Al) precipitates were observed, with an average size of 17 nm and coherent with the matrix lattice. The overall misfit has been quantified to be 0.28%. After long term aging at 700 and 725 °C for various periods up to 20,000 hours, γ′ was still the predominant precipitate and mostly coherent with the matrix. A few needle-shape η-Ni3Ti intermetallic precipitates were found in the grain boundary regions. The γ′ size has grown progressively to 78 nm, accompanied by the γ′-γ constrained misfit increasing to 0.50%. Moreover, the M23C6-type grain boundary carbides were found to have experienced morphological evolution, including the nucleation of Widmanstatten-type needles and their initial growth towards the matrix.

scholarly journals High-Resolution Microstructure Characterization of Additively Manufactured X5CrNiCuNb17-4 Maraging Steel during Ex and in Situ Thermal Treatment

2021 ◽  
Author(s):  
Mihaela Albu ◽  
Bernd Panzirsch ◽  
Hartmuth Schröttner ◽  
Stefan Mitsche ◽  
Klaus Reichmann ◽  
...  
Keyword(s):  
Maraging Steel ◽  
Elevated Temperatures ◽  
Scanning Transmission Electron Microscope ◽  
Transmission Electron ◽  
Scanning Transmission ◽  
The Matrix ◽  
Powder Particles ◽  
In Situ Heating ◽  
Heating Up

Powder and SLM additively manufactured parts of X5CrNiCuNb17-4 maraging steel were systematically investigated by electron microscopy to understand the relationship between the properties of the powder grains and the microstructure of the printed parts. We prove that satellites, irregularities and superficial oxidation of powder particles can be transformed into an advantage through the formation of nanoscale (AlMnSiTiCr)-oxides in the matrix during the printing process. The nano-oxides showed extensive stability in terms of size, spherical morphology, chemical composition and crystallographic disorder upon in situ heating up to 950°C in the scanning transmission electron microscope. Their presence thus indicates a potential for oxide-dispersive strengthening of this steel, which may be beneficial for creep resistance at elevated temperatures. The nucleation of copper clusters and their evolution into nanoparticles as well as the precipitation of Ni and Cr particles upon in situ heating have as well been systematically documented.

Coupling of Rotor-Gear-Casing Vibrations During Extreme Operating Events

1992 ◽  
Vol 114 (4) ◽  
pp. 464-471 ◽  
Author(s):  
F. K. Choy ◽  
J. Padovan ◽  
Y. F. Ruan
Keyword(s):  
Element Model ◽  
Operating Conditions ◽  
Transient Vibration ◽  
Rotor Systems ◽  
Power Plant Equipment ◽  
Modal Synthesis ◽  
Operating Environments ◽  
Rotor Bearing ◽  
The Matrix ◽  
Plant Equipment

During extreme operating environments (i.e., seismic events, base motion-induced vibrations, etc.), the coupled vibrations developed between the rotors, bearings, gears and enclosing structure of gear-driven rotating equipment can be quite substantial. Generally, such large vibrational amplitudes may lead to failures in both the rotor-gearing system and/or the casing structure. This paper simulates the dynamic behavior of rotor-bearing-gear system resulting from motion of the enclosed structure. The modal synthesis approach is used in this study to synthesize the dynamics of the rotor systems with the vibrations of their casing structure in modal coordinates. Modal characteristics of the rotor-bearing-gear systems are evaluated using the matrix transfer technique, while the modal parameters for the casing structure are developed through a finite element model using NASTRAN. The modal accelerations calculated are integrated through a numerical algorithm to generate modal transient vibration analysis. Vibration results are examined in both time and frequency domains to develop representations for the coupled dynamics generated during extreme operating conditions. Typical three-rotor bull gear-driven power plant equipment (compressors, pumps, etc.) is used as an example to demonstrate the procedure developed.

Effect of vulcanization time on crosslink density and aging performance of natural rubber composites

2020 ◽  
Vol 62 (8) ◽  
pp. 858-862
Author(s):  
Ece Unur Yilmaz ◽  
Ahu Kor Dayioglu ◽  
Seda Balaban
Keyword(s):  
Natural Rubber ◽  
Crosslink Density ◽  
Elevated Temperatures ◽  
Mechanical Performance ◽  
Operating Conditions ◽  
Rubber Composites ◽  
Rubber Mixture ◽  
Natural Rubber Composites ◽  
Different Temperatures ◽  
Auto Parts

Abstract Natural rubber composites are widely used in the automotive industry because of their improved viscoelastic characteristics that are mostly governed by crosslink density. However, rubber parts suffer deterioration of performance over long service lives. Therefore, optimization of crosslink density and prediction of changes in physico-mechanical properties over time at elevated temperatures is extremely important for the production of safe auto parts. In this work, the effect of vulcanization time on crosslink density and thus the performance and lifetime of natural rubberbased auto parts was investigated. The natural rubber mixture prepared in this context was vulcanized for 3, 5, 10 and 15 minutes at a constant temperature of 160 °C. The crosslink density of each vulcanizite was determined by equilibrium swelling tests and the Flory-Rehner equation. The maximum crosslink density (10.75 × 10-5 mol × cm-3) and the minimum permanent compression set values (10 % at 70 °C and 25 % at 100 °C) were recorded for the sample vulcanized for 10 minutes (v10). Aging behavior of the samples were investigated by stress relaxation tests performed at 85 °C, 100 °C and 120 °C. The service lives of the vulcanizites at different temperatures were predicted by linear Arrhenius fits of degradation times. The sample vulcanized for 10 minutes (v10) was shown to exhibit a service life of 2282 hours at 70 °C in air and the optimum physico-mechanical performance under real operating conditions. The performance and lifetime prediction procedure used in this work could be employed in an early design of rubber components for specific applications.

Characterization of Aluminosilicate Formation on the Surface of a Crystalline Silicotitanate Ion Exchanger

2001 ◽  
Vol 7 (S2) ◽  
pp. 498-499
Author(s):  
J. S. Young ◽  
Y. Su ◽  
L. Li ◽  
M. L. Balmer
Keyword(s):  
Elevated Temperatures ◽  
Operating Conditions ◽  
Department Of Energy ◽  
Ion Exchanger ◽  
Savannah River ◽  
Crystalline Silicotitanate ◽  
High Level ◽  
River Site ◽  
Aluminosilicate Coating

Millions of gallons of high-level radioactive waste are contained in underground tanks at U. S. Department of Energy sites such as Hanford and Savannah River. Most of the radioactivity is due to 137Cs and 90Sr, which must be extracted in order to concentrate the waste. An ion exchanger, crystalline silicotitanate IONSIV® IE911, is being considered for separation of Cs at the Savannah River Site (SRS). While the performance of this ion exchanger has been well characterized under normal operating conditions, Cs removal at slightly elevated temperatures, such as those that may occur in a process upset, is not clear. Our recent study indicates that during exposure to SRS simulant at 55°C and 80°C, an aluminosilicate coating formed on the exchanger surface. There was concern that the coating would affect its ion exchange properties. A LEO 982 field emission scanning electron microscope (FESEM) and an Oxford ISIS energy dispersive x-ray spectrometer (EDS) were used to characterize the coating.

An elastic harmonic inclusion near a rigid harmonic inclusion loaded by a couple

2019 ◽  
Vol 84 (3) ◽  
pp. 555-566
Author(s):  
Xu Wang ◽  
Liang Chen ◽  
Peter Schiavone
Keyword(s):  
Rigid Inclusion ◽  
Elastic Inclusion ◽  
Complex Loading ◽  
Solution Procedure ◽  
External Loading ◽  
Surrounding Matrix ◽  
The Matrix ◽  
Mapping Techniques ◽  
Loading Parameter ◽  
Harmonic Inclusion

AbstractWe use conformal mapping techniques to solve the inverse problem concerned with an elastic non-elliptical harmonic inclusion in the vicinity of a rigid non-elliptical harmonic inclusion loaded by a couple when the surrounding matrix is subjected to remote uniform stresses. Both a size-independent complex loading parameter and a size-dependent real loading parameter are introduced as part of the solution procedure. The stress field inside the elastic inclusion is uniform and hydrostatic; the interfacial normal and tangential stresses as well as the hoop stress on the matrix side are uniform along each one of the two inclusion–matrix interfaces. The tangential stress along the interface of the elastic inclusion (free of external loading) vanishes, whereas that along the interface of the rigid inclusion (loaded by the couple) does not. A novel method is proposed to determine the area of the rigid inclusion.

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