scholarly journals Application of Automated Image Analysis to the Study of Cement Paste Microstructure

1994 ◽  
Vol 370 ◽  
Author(s):  
David Darwin ◽  
Mohamed Nagib Abou-Zeid

AbstractDigital acquisition and analysis of backscattered electron images provide powerful tools for the study of cement-based materials. The techniques can provide useful information on hydration phases, size distributions of unhydrated particles and voids, effects of changes in the watercementitious material ratio and the use of mineral admixtures, and the distribution of microcracks. The results of automated analyses of cement pastes with different water-cement ratios and pastes containing silica fume are presented. The analyses demonstrate that microstructural data vary significantly from image to image, requiring multiple images to limit the effects of scatter. The analyses also indicate that, although the pastes exhibit different degrees of hydration, the size distributions of the unhydrated cement particles are nearly identical. In contrast, the size distribution of larger voids differs significantly as a function of water-cementitious material ratio and with the use of silica fume as a partial replacement for cement. The calcium hydroxide content obtained based on image analysis exceeds but generally parallels that obtained with thermogravimetric analysis. The majority of microcracks in both nonloaded and loaded specimens occur through or adjacent to the lowest density hydration phase.

2012 ◽  
Vol 19 (2) ◽  
pp. 199-207 ◽  
Author(s):  
Chinlai Lee ◽  
Maochieh Chi ◽  
Ran Huang

AbstractThe influence of water/cementitious material ratio, silica fume, and fly ash as partial Portland cement replacement materials on the properties, pore structure, and durability of cement-based composites was evaluated by conducting compressive strength test, mercury intrusion porosimetry test, water absorption, rapid chloride penetration test, and scanning electron microscopy (SEM). Water/cementitious material ratio, and replacement percentage of silica fume and fly ash have significant effects on the pore structure and durability of cement-based composites. Composites with silica fume or fly ash have a denser structure than the control composite on SEM micrographs. Silica fume has about 5–10 times as much effect as fly ash, according to results of multiple linear regression analyses of testing data.


2019 ◽  
Vol 9 (9) ◽  
pp. 1049-1054
Author(s):  
Yunxia Lun ◽  
Fangfang Zheng

This study is aimed at exploring the effect of steel slag powder (SSP), fly ash (FA), and silica fume (SF) on the mechanical properties and durability of cement mortar. SSP, SF, and FA were used as partial replacement of the Ordinary Portland cement (OPC). It was showed that the compressive and bending strength of steel slag powder were slightly lower than that of OPC. An increase in the SSP content caused a decrease in strength. However, the growth rate of compressive strength of SSP2 (20% replacement by the weight of OPC) at the curing ages of 90 days was about 8% higher than that of OPC, and the durability of SSP2 was better than that of OPC. The combination of mineral admixtures improved the later strength, water impermeability, and sulfate resistance compared with OPC and SSP2. The compressive strength of SSPFA (SSP and SF) at 90 days reached 70.3 MPa. The results of X-ray diffraction patterns and scanning electron microscopy indicated that SSP played a synergistic role with FA or SF to improve the performance of cement mortar.


2012 ◽  
Vol 535-537 ◽  
pp. 1735-1738 ◽  
Author(s):  
Yan Li ◽  
Dao Sheng Sun ◽  
Xiu Sheng Wu ◽  
Ai Guo Wang ◽  
Wei Xu ◽  
...  

This paper reports the drying shrinkage and compressive strength results of cement pastes with fly ash and silica fume. In this study, Portland cement (PC) was used as the basic cementitious material. Fly ash (FA) and silica fume (SF) were used as cement replacement materials at levels of 0%, 5%, 10%, and 15% , 40%, 35%, 25%, and 15% by weight of the total cementitious material, respectively. The water/cement (PC + FA + SF) ratios (w/c) was 0.28 by weight. The samples produced from fresh pastes were demoulded after a day; then they were cured at 20 ±1°C with 50 ± 3% relative humidity (RH) until the samples were used for drying shrinkage and compressive strength measurement at various ages. The results show that drying shrinkage and compressive strength increase with increasing SF content, and the optimum composition of blended cement pastes is the cement paste with 30% fly ash and 10% silica fume, which possesses lower drying shrinkage values than that of plain cement paste and higher early age strength than that of blended cement pastes with fly ash. Furthermore, a linear relationship is established between compressive strength and drying shrinkage. By comparing the development of compressive strength and the drying shrinkage deformations, it appears possible to predict the drying shrinkage according to the acquired compressive strength.


Vestnik MGSU ◽  
2019 ◽  
pp. 102-117 ◽  
Author(s):  
Duc Vinh Quang Nguyen ◽  
Olga V. Aleksandrova ◽  
Yuriy M. Bazhenov

Introduction. This study focuses on the use of silica fume partially replacing cement with 0, 5, 7.5, 10, 12.5 and 30 % constant replacement of fly ash by weight of cement in concrete. Concrete is probably the most extensively used construction material in the world. But the conventional concrete is losing its uses with time and high-performance concrete (HPC) is taking that place. HPC has superior mechanical properties and durability to normal strength concrete. Because of, the microstructure of HPC is more homogeneous than that of normal concrete (NC) due to the physical and chemical contribution of the mineral admixtures as well as it is less porous due to reduced w/c ratio with the addition of a superplasticizer. The inclusion of additives helped in improving the properties of concrete mixes due to the additional reduction in porosity of cement paste and improving the particle packing in the interfacial transition zone (between cement paste and the aggregates).In this experimental investigation the behavior of HPC with silica fume and fly ash with and without quartz powder were studied. The water-binder ratio was kept 0.3 and 20 % quartz flour as partial replacement of fine aggregate for all cases. Materials and methods. Used materials in Vietnam, as follow, Sulfate-resisting Portland cement - PCSR40 (type V) of company Luks Cement (Vietnam) Limited was used in the work. Crushed granite of fraction 9.5…20 mm - as coarse aggregate, Natural sand from Huong river of 0.15…2.5 mm fraction with the fineness modulus of about 3.0 and quartz powder with an average particle size of 5…10 μm were used as fillers; Sika® Viscocrete®-151 is a superplasticizer based on a blend of 3rd generation PCE polymers was used as a plasticizing admixture. The flg ash from Pha Lai thermal power plant and Sika silica Sikacrete® PP1 (particle size < 0.1 μm) was used as a mineral active admixture. The study of strength and technological properties of high-performance concrete was performed by using standard methods. Results. Established by icate that, the workability and strength increase at a certain level and after that, they decline with further increase in the replacement level of silica fume is 12.5 %, on the basis of 30 % FA replacement, the incorporation of 10 % SF showed equivalent or higher mechanical properties and durability compared to the reference samples. Conclusions. HPC consists of mineral admixtures such as silica fume and fly ash use combine quartz powder and superplasticizer helped in improving the strength and durability of concrete mixes due to the additional reduction in porosity of cement paste and an improved interface between it and the aggregate. With 30 % fly ash is optimum dosage used to replacement of cement, incorporation 10 % SF (by weight) and combine of partial replacement of fine aggregate by 20 % quartz powder. On the other hand, a few mathematical equations can be used to derive the durability properties of concrete based on its compressive strength.


2011 ◽  
Vol 374-377 ◽  
pp. 1446-1450
Author(s):  
Hui Xu ◽  
An Qi Lu

This paper studies on the relative denseness of fresh cement pastes compounded with multi-cementitious materials and the performances of their harden concretes. Results show that with the dense packing of several ultra-fine particles, higher the relative denseness of different cementitious material system, higher the compressive strength and lower the air permeability of the harden concrete. The multi-cementitious material compounded by 37% cement、20% fly ash、40% pulverized slag and 3% silica fume has the higher relative denseness of fresh cement paste, and its compressive strength and air permeation of harden concrete composite is also improved.


Concrete is one of the most suitable materials in the world which are used for construction. It becomes more versatile because of his suitability in almost all situations. Reinforced structures are subject to corrosion by various means. Carbonation is one of these means that causes corrosion of reinforced concrete structures. The service life of the structures has been reduced due to the deterioration of the structures because of the corrosion of the reinforced concrete due to carbonation. This paper focuses on the effect of carbonation on the mechanical properties of concrete composed of mineral admixtures, such as ground granulated blast furnace slag and silica fume, by partial replacement of the cement. In this experiment, silica fume replaced cement in 5%, 10%, 15% and ground granulated blast furnace slag replaced the cement in 10%, 20%, 30%. Samples such as cubes, cylinders and prisms were casted and cured. Certain number of these specimens were also placed in carbonation chamber and tested for compressive strength, tensile strength and flexural strength. Normal concrete samples are also tested and the results are compared.


2018 ◽  
Vol 64 (1) ◽  
pp. 117-131 ◽  
Author(s):  
K.V.S.Gopala Krishna Sastry ◽  
A. Ravitheja ◽  
T.Chandra Sekhara Reddy

Abstract Foundry sand waste can be utilized for the preparation of concrete as a partial replacement of sand. The strength properties of M25 grade concrete are studied with different percentages of replacement of fine aggregates by foundry sand at 0%, 10%, 20%, 30%, 40%, and 50%. The optimum percentage of foundry sand replacement in the concrete corresponding to maximum strength will be identified. Keeping this optimum percentage of foundry sand replacement as a constant, a cement replacement study with mineral admixtures such as silica fume (5%, 7.5%, 10%) and fly ash (10%, 15%, 20%,) is carried out separately. The maximum increase in strength properties as compared to conventional concrete was achieved at 40% foundry sand replacement. Test results indicated that a 40% replacement of foundry sand with silica fume showed better performance than that of fly ash. The maximum increase in strengths was observed in a mix consisting of 40% foundry sand and 10% silica fume. SEM analysis of the concrete specimens also reveals that a mix with 40% foundry sand and 10% silica fume obtained the highest strength properties compared to all other mixes due to the creation of more C-H-S gel formations and fewer pores.


Abstract. Cement being a major contributor to carbon emission needs a revolution in its production or modification to the existing cement. One such way to reduce cement usage is to replace the cementitious compound with a suitable material that does not alter the original purpose of cement in concrete. The sugarcane bagasse ashes (SCBA), which are ashes from biomass burning, are found to act as supplementary cementitious material. Moreover, studies were conducted to relate the strength and durability of concrete by the percentage of replacement of sugarcane bagasse ash to cement. The studies revealed that the SCBA imparts more strength to cement at 10% replacement when compared to 20% replacement. However, this study is intended to use 20% of SCBA replacement in cement by adding silica fume. Concrete being mainly reinforced with steel has the problem of corrosion. To overcome the problem of corrosion as well as to reduce the use of cement and to attain the compressive strength of 10% replacement of SCBA. This experiment is intended to analyze the behavior of concrete up to 20% replacement of SCBA with silica fume at different concentrations such as 0%,5%,10%,15%.


2016 ◽  
Vol 692 ◽  
pp. 74-81 ◽  
Author(s):  
J.R. Thirumal ◽  
R. Harish

Self – compacting concrete (SCC) is a high – performance concrete that can flow under its own weight to completely fill the form work and self-consolidation without any mechanical vibration. Green concrete is defined as a concrete which uses waste material as at least one of its components, or its production process does not lead to environmental destruction. Such concrete can accelerate the placement, reduce the labor requirements needed for consolidation, finishing and eliminate environmental pollution. One alternative to reduce the cost of self-compacting concrete is the use of mineral admixtures such as silica fume, ground granulated blast furnace slag and fly ash, which is finely, divided materials added to concrete during mixture procedure .When mineral admixtures replace a part of the Portland cement, the cost of self-compacting concrete will be reduced especially if the mineral admixtures are waste or industrial by-product. The various tests for compressive, tensile and flexural strength are determined for various specimens with certain percentages ( 10 % ,30 % ) of replacement like silica fume, fly ash and combination of both fly ash and silica fume. Admixture combination of fly ash and silica fume replacing 30 % results in maximum compressive strength. Admixture of fly ash replacing 10 % results in maximum tensile and flexural strength. In order to make SCC effective, trials can be made with partial replacement of combining silica fume and fly ash to achieve the higher compressive strength. Minimum replacement of fly ash can be investigated to achieve higher tensile and flexural strength .With respect to the above combination of replacement SCC can be dealt with its several specializations to make it effective.


Scanning ◽  
2006 ◽  
Vol 22 (6) ◽  
pp. 337-344 ◽  
Author(s):  
Haviva M. Goldman ◽  
Aron Blayvas ◽  
Alan Boyde ◽  
Peter G. T. Howell ◽  
John G. Clement ◽  
...  

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