The Carbon-Lithium Negative Electrode for Lithium-Ion Batteries in Polymer Electrolyte

1994 ◽  
Vol 369 ◽  
Author(s):  
R. Yazami ◽  
M. Deschamps
Keyword(s):  
Lithium Ion Batteries ◽  
Polymer Electrolyte ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Carbon Surface ◽  
Carbonaceous Materials ◽  
Lithium Storage ◽  
Negative Electrodes ◽  
Rate Capacity

AbstractSeveral types of carbonaceous materials are evaluated as negative electrodes for lithium storage in polymer electrolyte based cells operated at 100ºC. The corresponding faradaic efficiencies of the spherical cycle and the achieved reversible first capacity and rate capacity will be given. A meso carbon yielded a higher capacity than the theoretical 372 mAh/g. This is tentatively explained by the necessary enhancement of the carbon/polymer interfacial properties through the formation of C-Li-O bonding at the carbon surface and by the possible formation of multilayers of lithium on the external a,b planes of disordered carbons. The formation of the passivating layer on the carbon surface will be described.A lithium-ion type battery using coke and LiNiO2 as the negative and positive leads and POE-LiCIO4 was operated at 100ºC and cycled galvanostatically. Good reversible capacity was attained with the LiNiO2 electrode.

Ultrafast lithium storage in TiO2–bronze nanowires/N-doped graphene nanocomposites

2015 ◽  
Vol 3 (8) ◽  
pp. 4180-4187 ◽  
Author(s):  
Xiao Yan ◽  
Yanjuan Li ◽  
Malin Li ◽  
Yongcheng Jin ◽  
Fei Du ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Power ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Lithium Storage ◽  
Graphene Nanocomposites ◽  
High Reversible Capacity ◽  
Doped Graphene ◽  
Rate Capacity ◽  
Graphene Nanocomposite

A TiO2–bronze/N-doped graphene nanocomposite was prepared by a facile method. The material exhibits outstanding rate capacity. A high reversible capacity of 101.6 mA h g−1 is obtained at the 100C rate, indicating its great potential for use in high power lithium ion batteries.

Novel Co3O4/Carbon Nanofiber Composite Electrode with High Li-Storage Capacity for Lithium Ion Batteries

2011 ◽  
Vol 197-198 ◽  
pp. 1113-1116 ◽  
Author(s):  
Wen Li Yao ◽  
Jin Qing Chen ◽  
An Yun Li ◽  
Xin Bing Chen
Keyword(s):  
Composite Materials ◽  
Lithium Ion Batteries ◽  
Electrode Materials ◽  
Storage Capacity ◽  
Carbon Nanofiber ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycling Performance ◽  
Li Storage

The platelike Co3O4/carbon nanofiber (CNF) composite materials were synthesized by the calcination of β-Co(OH)2/CNF precursor prepared by a surfactant-free hydrothermal method. As negative electrode materials for lithium-ion batteries, the platelike Co3O4/CNF composites can deliver a high reversible capacity of 900 mAh g-1 for a life extending over hundreds of cycles at a current density of 100 mA g-1. The high Li-storage capacity and excellent cycling performance for Co3O4/CNF composite materials may mainly attribute to the beneficial effect of the CNFs addition on enhancing structural stability and electrical conductivity of Co3O4 platelets.

Synergistic effect between flake graphite and small-sized graphene in lithium storage

2021 ◽  
pp. 2150031
Author(s):  
Hai Li ◽  
Chunxiang Lu
Keyword(s):  
Synergistic Effect ◽  
Lithium Ion Batteries ◽  
Individual Component ◽  
Specific Capacity ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Flake Graphite ◽  
Effective Strategy ◽  
Lithium Storage

As anode material for lithium-ion batteries, graphite has the disadvantage of relatively low specific capacity. In this work, a simple yet effective strategy to overcome the disadvantages by using a composite of flake graphite (FG) and small-sized graphene (SG) has been developed. The FG/SG composite prepared by dispersing FG and SG (90:10 w/w) in ethanol and drying delivers much higher specific capacity than that of individual component except for improved rate capability. More surprisingly, FG/SG composite delivers higher reversible capacity than its theoretical value calculated according to the theoretical capacities of graphite and graphene. Therefore, a synergistic effect between FG and SG in lithium storage is clearly discovered. To explain it, we propose a model that abundant nanoscopic cavities were formed due to physical adhesion between FG and SG and could accommodate extra lithium.

scholarly journals A mechanistic study of mesoporous TiO2 nanoparticle negative electrode materials with varying crystallinity for lithium ion batteries

2020 ◽  
Vol 8 (6) ◽  
pp. 3333-3343 ◽  
Author(s):  
Changjian Deng ◽  
Miu Lun Lau ◽  
Chunrong Ma ◽  
Paige Skinner ◽  
Yuzi Liu ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Power Density ◽  
Electrode Materials ◽  
Negative Electrode ◽  
Lithium Ion ◽  
High Energy ◽  
Mesoporous Tio2 ◽  
Mechanistic Study ◽  
Negative Electrodes ◽  
Negative Electrode Materials

Nanoscale oxide-based negative electrodes are of great interest for lithium ion batteries due to their high energy/power density, and enhanced safety. The crystallinity effect of mesoporous TiO2 nanoparticle electrode was investigated in this work.

scholarly journals Carbon nanotube-wrapped Fe2O3 anode with improved performance for lithium-ion batteries

2017 ◽  
Vol 8 ◽  
pp. 649-656 ◽  
Author(s):  
Guoliang Gao ◽  
Yan Jin ◽  
Qun Zeng ◽  
Deyu Wang ◽  
Cai Shen
Keyword(s):  
Hydrothermal Synthesis ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
Electronic Conductivity ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Practical Application ◽  
Lithium Storage ◽  
Improved Performance ◽  
A Current

Metall oxides have been proven to be potential candidates for the anode material of lithium-ion batteries (LIBs) because they offer high theoretical capacities, and are environmentally friendly and widely available. However, the low electronic conductivity and severe irreversible lithium storage have hindered a practical application. Herein, we employed ethanolamine as precursor to prepare Fe2O3/COOH-MWCNT composites through a simple hydrothermal synthesis. When these composites were used as electrode material in lithium-ion batteries, a reversible capacity of 711.2 mAh·g−1 at a current density of 500 mA·g−1 after 400 cycles was obtained. The result indicated that Fe2O3/COOH-MWCNT composite is a potential anode material for lithium-ion batteries.

Morella-rubra-like metal–organic-framework-derived multilayered Co3O4/NiO/C hybrids as high-performance anodes for lithium storage

2017 ◽  
Vol 5 (46) ◽  
pp. 24269-24274 ◽  
Author(s):  
Yongzhe Wang ◽  
Mingguang Kong ◽  
Ziwei Liu ◽  
Chucheng Lin ◽  
Yi Zeng
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Metal Organic Framework ◽  
High Capacity ◽  
Lithium Ion ◽  
Lithium Storage ◽  
Metal Organic ◽  
Rate Capacity ◽  
Organic Framework

Multilayered Co3O4/NiO/C electrodes with a ball-in-ball hollow morphology are employed in lithium-ion batteries and deliver an excellent rate capacity of 421 mA h g−1 at 4 A g−1 and a high capacity of 776 mA h g−1 over 1000 cycles at 1 A g−1.

Bi2S3/C nanorods as efficient anode materials for lithium-ion batteries

2019 ◽  
Vol 48 (5) ◽  
pp. 1906-1914 ◽  
Author(s):  
Wenwen Chai ◽  
Fan Yang ◽  
Weihao Yin ◽  
Shunzhang You ◽  
Ke Wang ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Electrode Material ◽  
Anode Materials ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Average Diameter ◽  
Synthesis Process ◽  
Lithium Storage ◽  
High Theoretical Capacity ◽  
Negative Electrode Material

Bi2S3 is a promising negative electrode material for lithium storage owing to its high theoretical capacity. During the Bi2S3/C synthesis process, the carbonization of H3BTC prevents aggregation of Bi2S3 particles, with an average diameter of 60 nm.

MnO2/Graphene Nanocomposite for Use in High Performance Lithium-Ion Batteries

2013 ◽  
Vol 709 ◽  
pp. 157-160 ◽  
Author(s):  
Xiao Yi Zhu ◽  
Jian Jiang Li ◽  
Xi Lin She ◽  
Lin Hua Xia
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Graphene Nanosheets ◽  
Synergetic Effect ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Lithium Storage ◽  
Hydrothermal Route ◽  
Graphene Nanocomposites ◽  
Mno2 Nanoparticles

A facile hydrothermal route has been developed to prepare MnO2/graphene nanocomposites and MnO2 nanoparticles are uniformly anchored on graphene nanosheets. The composite were studied as the anode material for lithium-ion batteries. The surface of graphene is modified by MnO2 nanoparticles which are 10-30 nm in size and homogeneously anchor on graphene sheets. The composite exhibits superior lithium battery performance with higher reversible capacity and better cycling performance. The reversible capacity is up to 781.5 mAh g-1 at a current of 100 mA g-1 and maintains 96% after 50 cycles. The enhanced lithium storage performance is due to the synergetic effect of graphene and MnO2.

Porous Fe3O4 hollow spheres with chlorine-doped-carbon coating as superior anode materials for lithium ion batteries

RSC Advances ◽  
2015 ◽  
Vol 5 (65) ◽  
pp. 52993-52997 ◽  
Author(s):  
Hongbo Geng ◽  
Shuangshuang Li ◽  
Yue Pan ◽  
Yonggang Yang ◽  
Junwei Zheng ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Carbon Coating ◽  
Hollow Spheres ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Lithium Storage ◽  
High Reversible Capacity ◽  
Storage Performance

The PH-Fe3O4@C/Cl spheres were successfully fabricated through a novel and controllable route, which could deliver superior lithium storage performance in terms of high reversible capacity, stable cycling and rate performances.

Highly stable GeOx@C core–shell fibrous anodes for improved capacity in lithium-ion batteries

2015 ◽  
Vol 3 (39) ◽  
pp. 19907-19912 ◽  
Author(s):  
Meng Li ◽  
Dan Zhou ◽  
Wei-Li Song ◽  
Xiaogang Li ◽  
Li-Zhen Fan
Keyword(s):  
Lithium Ion Batteries ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Core Shell ◽  
Lithium Storage ◽  
Storage Performance ◽  
Facile Fabrication ◽  
Hollow Carbon ◽  
Fiber Electrode

We demonstrate a facile fabrication in which encapsulation of GeOx nanoparticles into hollow carbon shells is achieved through co-axial electrospinning. The resultant GeOx@C core–shell fiber electrode exhibits excellent lithium storage performance, with stable reversible capacity and excellent rate capability.

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