Local Field Effects Near Surfaces of Small Systems

1994 ◽  
Vol 366 ◽  
Author(s):  
David Beaglehole

ABSTRACTThe interaction of light with a system of molecules depends upon the polarisation induced by an external electric field, which depends not only upon the external field but also upon the local fields due to neighboring polarised molecules. These local fields result in the traditional Clausius-Mossotti (CM) dielectric constant for a molecule deeply imbedded in a medium. Near the surface the local fields are altered, and the dielectric constant becomes anisotropic and dependent upon depth into the medium. The local fields are shape dependent in small systems and differ substantially from the CM value.A self-consistent computer calculation of the local fields has been implemented, and these effects will be shown using molecule positions and polarisabilities typical of liquids and crystals. The shape dependence of small systems, the reflection of light from liquids with fluctuating surfaces, and the effect of supporting substrates will be described.

Geophysics ◽  
1981 ◽  
Vol 46 (5) ◽  
pp. 781-795 ◽  
Author(s):  
P. N. Sen ◽  
C. Scala ◽  
M. H. Cohen

We develop a theory for dielectric response of water‐saturated rocks based on a realistic model of the pore space. The absence of a percolation threshold manifest in Archie’s law, porecasts, electron‐micrographs, and general theories of formation of detrital sedimentary rocks indicates that the pore spaces within such rocks remain interconnected to very low values of the porosity ϕ. In the simplest geometric model for which the conducting paths remain interconnected, each grain is envisioned to be coated with water. The dielectric constant of the assembly of water‐coated grains is obtained by a self‐consistent effective medium theory. In the dc limit, this gives Maxwell’s relation for conductivity σ of the rock [Formula: see text], where [Formula: see text] is the conductivity of water. In order to include the local environmental effects around a grain, a self‐similar model is generated by envisioning that each rock grain itself is coated with a skin made of other coated spheres; the coating at each level consists of other coated spheres. The self‐consistent complex dielectric constant [Formula: see text] is given in this model in terms of that of water [Formula: see text] and of rock [Formula: see text], by [Formula: see text] for spherical particles. This gives, in the dc limit, [Formula: see text]. For nonspherical particles, the exponent m in Archie’s law [Formula: see text] is greater than 3/2 for the plate‐like grains or cylinders with axis perpendicular to the external field and smaller than 3/2 for plates or cylindrical particles with axis parallel to the external field. Artificial rocks with a wide range of porosities were made from glass beads. We present data on the glass bead rocks for dc conductivity and the dielectric constant at 1.1 GHz. The data follow the conductivity and the dielectric responses given by the self‐similar model. The present theory fails to explain the salinity dependence of [Formula: see text] at lower frequencies.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Carlos A. M. André ◽  
João Dias

Abstract We consider smooth representations of the unit group G = A × G=\mathcal{A}^{\times} of a finite-dimensional split basic algebra 𝒜 over a non-Archimedean local field. In particular, we prove a version of Gutkin’s conjecture, namely, we prove that every irreducible smooth representation of 𝐺 is compactly induced by a one-dimensional representation of the unit group of some subalgebra of 𝒜. We also discuss admissibility and unitarisability of smooth representations of 𝐺.


Author(s):  
Yehia Bahei-El-Din ◽  
Amany Micheal

In a truly multiscale analysis of multilayered composites, the underlying phenomena are represented and their effect on the overall behavior is determined considering the interaction between the different phases and between the laminas. The analysis gets more involved when multiple phenomena are considered since in this case not only the direct effects play a role but also the coupled effects contribute to the distribution of the local fields and the overall response. In a fibrous composite laminate reinforced with piezoelectric filaments, for example, passing an electric field in the fibers generates stresses and strains which propagate through the composite medium due to constraints that exist both at the micromechanical, ply level, and the macromechanical, laminate level. Pyroelectricity is another coupling phenomenon in which a temperature change is caused by an electric field, and hence leads to changes in the stress and strain fields throughout the composite medium. The above phenomena have been considered by the authors in a unified, transformation field analysis (TFA) approach in which stresses and strains which cannot be removed by mechanical unloading are treated as transformation fields. Due to mutual constraints of the phases and the bonded plies, local transformations generate stresses at the micro and macro levels, which are computed by means of influence functions which depend on material geometry and properties. Treatment of damage follows the same scheme but the transformation fields are instead determined such that the local stresses in the affected phase are removed. In the present paper, implementation of the TFA approach in a general purpose finite element code is described. This expands the multiscale analysis outlined above to composite structures where complex geometries can be modeled and the effect of local phenomena can be considered. This naturally comes at a much larger cost of the computations compared to finite element analysis with homogenized models but the benefit of obtaining a more realistic response is clear. Moreover, the availability of high performance computing and parallel processing overcomes the computation time barrier. In the present paper however, simple examples of laminated structures are given as proof of concept in which the results are compared to those of standalone routines. Since the TFA approach centers on treating the composite medium as elastic with induced local transformations, implementation in the finite element framework does not require generation of an overall instantaneous stiffness matrix, which saves tremendously on the computation time. Instead, overall transformation strains, or stresses, are computed through a multiscale model, which is implemented as a user routine, and treated in the general finite element solution as nonmechanical strains in the same way thermal strains are treated.


1946 ◽  
Vol 19 (4) ◽  
pp. 1085-1087
Author(s):  
Pierre Girard ◽  
Paul Abadie

Abstract The spectra which were studied lie within the region of hertzian frequencies, and can be represented either by dispersion curves showing the dielectric constant of the substance as a function of the frequency (or wave length λ), or by absorption curves showing the loss angle as a function of this frequency. These two types of curves represent the same phenomenon, i.e., orientation of the dipolar molecules in the alternating electric field, in accordance with the theory of Debye. The spectra and their interpretation depend chiefly on whether the molecules are crystalloid with relatively small and similar dimensions, or are colloidal, with large and unequal dimensions. In the first case, the spectra gives evidence chiefly on the form of the molecules and their structural features. Dilution in a nonpolar solvent shows for certain dipolar compounds, e.g., alcohol, considerable deformations, which differ according to the solvent. In the case of colloids, e.g., rubber, which has a permanent moment, the spectra and the meaning of these spectra are far different. In this case the spectra indicate that the absorption and dispersion values in the hertzian region are closely related to the micellar constitution, i.e., to the different types of micelles, to their size, and to the proportion of each type.


2016 ◽  
Vol 06 (03) ◽  
pp. 1650019 ◽  
Author(s):  
V. M. Ishchuk ◽  
D. V. Kuzenko

The paper presents results of experimental study of the dielectric constant relaxation during aging process in Pb(Zr,Ti)O3based solid solutions (PZT) after action of external DC electric field. The said process is a long-term one and is described by the logarithmic function of time. Reversible and nonreversible relaxation process takes place depending on the field intensity. The relaxation rate depends on the field strength also, and the said dependence has nonlinear and nonmonotonic form, if external field leads to domain disordering. The oxygen vacancies-based model for description of the long-term relaxation processes is suggested. The model takes into account the oxygen vacancies on the sample's surface ends, their conversion into [Formula: see text]- and [Formula: see text]-centers under external effects and subsequent relaxation of these centers into the simple oxygen vacancies after the action termination. [Formula: see text]-centers formation leads to the violation of the original sample's electroneutrality, and generate intrinsic DC electric field into the sample. Relaxation of [Formula: see text]-centers is accompanied by the reduction of the electric field, induced by them, and relaxation of the dielectric constant, as consequent effect.


Author(s):  
Y Su ◽  
G.J Weng

Most key elements of ferroelectric properties are defined through the hysteresis loops. For a ferroelectric ceramic, its loop is contributed collectively by its constituent grains, each having its own hysteresis loop when the ceramic polycrystal is under a cyclic electric field. In this paper, we propose a polycrystal hysteresis model so that the hysteresis loop of a ceramic can be calculated from the loops of its constituent grains. In this model a micromechanics-based thermodynamic approach is developed to determine the hysteresis behaviour of the constituent grains, and a self-consistent scheme is introduced to translate these behaviours to the polycrystal level. This theory differs from the classical phenomenological ones in that it is a micromechanics-based thermodynamic approach and it can provide the evolution of new domain concentration among the constituent grains. It also differs from some recent micromechanics studies in its secant form of self-consistent formulation and in its application of irreversible thermodynamics to derive the kinetic equation of domain growth. To put this two-level micromechanics theory in perspective, it is applied to a ceramic PLZT 8/65/35, to calculate its hysteresis loop between the electric displacement and the electric field ( D versus E ), and the butterfly-shaped longitudinal strain versus the electric field relation ( ϵ versus E ). The calculated results are found to be in good quantitative agreement with the test data. The corresponding evolution of new domain concentration c 1 and the individual hysteresis loops of several selected grains—along with those of the overall polycrystal—are also illustrated.


Author(s):  
Л.С. Камзина ◽  
G. Li

The temperature dependences of the dielectric parameters were studied, as well as the changes in the dielectric constant with time in ceramic 33PbYb1 / 2Nb1 / 2O3-22PbZrO3-45 PbTiO3 samples in electric fields (0 <E <8 kV / cm). It is shown that in the phase existing below the temperature of the morphotropic phase transition, in addition to the rhombohedral and tetragonal phases, a small fraction of the relaxor pseudocubic phase is present. It was found that, unlike other relaxors, the dielectric constant practically does not change with time when an electric field is applied in the phase below the temperature of the morphotropic phase transition. Possible reasons for this behavior are discussed.


Author(s):  
M.H.A. Wahab ◽  
N. A. M. Jamail ◽  
E. Sulaiman ◽  
Q.E. Kamarudin ◽  
N.A. Othman ◽  
...  

<p>Nowadays, XLPE cable has been widely used because it has better resistance than other cables. XLPE insulation has unique features including a high dielectric strength and high insulation resistance. A lot of researches based on hardware and software have been conducted to prove the effectiveness of XLPE cable such as AC and DC applications and Space Charge Distribution measurement under HVDC at High Temperature. This research focused on analysis of space charge and electric field on XLPE cable with effect of non-uniform contamination layer by using Quickfield Software. Non-uniform contaminations have been applied along XLPE cable using Arsenic Tribromide (AsBr3), Boron Bromide (BBr3), Ethylene Dichloride (CH2C1), Formic Acid (CH1O2), Formamide (CH3NO) and Alcohol element. Presence of these contamination elements represent of underground contamination. The size and layer of the contamination were non-uniform type. From the results, it is shown that lower dielectric constant of contamination will affect more on charge of XLPE insulation. As a conclusion, it can be seen lower dielectric constant value of contamination element greatly affecting the performance of XLPE insulation. Furthermore, size of contamination also influences the content of charge in contamination where the bigger the contamination size, the more charge contained in the contamination.</p>


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