Multiphoton Ionization Mass Spectroscopy of Fullerenes in Methane Diffusion Flames
Keyword(s):
On Line
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ABSTRACTMultiphoton ionization time-of-flight mass spectrosocopy is used as an on-line technique to investigate polycyclic aromatic hydrocarbons (PAH) and fullerenes in atmospheric pressure flames. We have recorded height profiles of neutral PAH and fullerenes in methane/argon diffusion flames. Fullerenes ranging from C32 to at least C150 are found in a region where PAH concentration starts to decrease. Uniformity of the profiles indicates that the fullerenes do not grow from smaller to larger ones. The influence of the amount of argon additive is discussed.
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