scholarly journals Densification of Salt-Occluded Zeolite a Powders to a Leach-Resistant Monolith

1993 ◽  
Vol 333 ◽  
Author(s):  
Michele A. Lewis ◽  
Donald F. Fischer ◽  
Christopher D. Murphy
Keyword(s):  
Fast Reactor ◽  
Fission Products ◽  
Glass Frit ◽  
Deionized Water ◽  
Zeolite A ◽  
Spent Fuel ◽  
Release Rates ◽  
Geologic Disposal ◽  
Radiation Resistant ◽  
Salt Waste

ABSTRACTPyrochemical processing of spent fuel from the Integral Fast Reactor (IFR) yields a salt waste of LiCI-KCI that contains approximately 6 wt% fission products, primarily as CsCI and SrCl2. Past work has shown that zeolite A will preferentially sorb cesium and strontium and will encapsulate the salt waste in a leach-resistant, radiation-resistant aluminosilicate matrix. However, a method is still needed to convert the salt-occluded zeolite powders into a monolith suitable for geologic disposal. We are thus investigating a method that forms bonded zeolite by hot pressing a mixture of glass frit and sait-occluded zeolite powders at 990 K (717°C) and 28 MPa. The leach resistance of the bonded zeolite was measured in static leach tests run for 28 days in 363 K (90°C) deionized water. Normalized release rates of all elements in the bonded zeolite were low, <1 g/m2d. Thus, the bonded zeolite may be a suitable waste form for IFR salt waste.

scholarly journals Leach Resistance Properties and Release Processes for Salt-Occluded Zeolite A

1992 ◽  
Vol 294 ◽  
Author(s):  
M. A. Lewis ◽  
D. F. Fischer ◽  
J. J. Laidler
Keyword(s):  
Alkali Metal ◽  
Alkali Metal Cation ◽  
Fission Products ◽  
Waste Form ◽  
Zeolite A ◽  
Spent Fuel ◽  
Release Process ◽  
Initial Release ◽  
Pyrometallurgical Processing ◽  
Release Processes

ABSTRACTThe pyrometallurgical processing of spent fuel from the Integral Fast Reactor (IFR) results in a waste of LiCI-KCI-NaCI salt containing approximately 10 wt% fission products, primarily CsCI and SrCI2. For disposal, this waste must be immobilized in a form that it is leach resistant. A salt-occluded zeolite has been identified as a potential waste form for the salt. Its leach resistance properties were investigated using powdered samples. The results were that strontium was not released and cesium had a low release, 0.056 g/m2 for the 56 day leach test. The initial release (within 7 days) of alkali metal cations was rapid and subsequent releases were much smaller. The releases of aluminum and silicon were 0.036 and 0.028 g/m2, respectively, and were constant. Neither alkali metal cation hydrolysis nor exchange between cations in the leachate and those in the zeolite was significant. Only sodium release followed t0.5 kinetics. Selected dissolution of the occluded salt was the primary release process. These results confirm that salt-occluded zeolite has promise as the waste form for IFR pyroprocess salt.

scholarly journals Converting Maturing Nuclear Sites to Integrated Power Production Islands

2011 ◽  
Vol 2011 ◽  
pp. 1-10
Author(s):  
Charles W. Solbrig
Keyword(s):  
Fast Reactor ◽  
Nuclear Power ◽  
Fission Products ◽  
Power Production ◽  
Spent Fuel ◽  
Fast Reactors ◽  
The Us ◽  
Spent Fuel Pool ◽  
Fuel Reprocessing ◽  
Nuclear Power Production

Nuclear islands, which are integrated power production sites, could effectively sequester and safeguard the US stockpile of plutonium. A nuclear island, an evolution of the integral fast reactor, utilizes all the Transuranics (Pu plus minor actinides) produced in power production, and it eliminates all spent fuel shipments to and from the site. This latter attribute requires that fuel reprocessing occur on each site and that fast reactors be built on-site to utilize the TRU. All commercial spent fuel shipments could be eliminated by converting all LWR nuclear power sites to nuclear islands. Existing LWR sites have the added advantage of already possessing a license to produce nuclear power. Each could contribute to an increase in the nuclear power production by adding one or more fast reactors. Both the TRU and the depleted uranium obtained in reprocessing would be used on-site for fast fuel manufacture. Only fission products would be shipped to a repository for storage. The nuclear island concept could be used to alleviate the strain of LWR plant sites currently approaching or exceeding their spent fuel pool storage capacity. Fast reactor breeding ratio could be designed to convert existing sites to all fast reactors, or keep the majority thermal.

Materials Characteristics and Dissolution Behavior of Spent Nuclear Fuel

MRS Bulletin ◽  
1994 ◽  
Vol 19 (12) ◽  
pp. 24-27 ◽  
Author(s):  
L.H. Johnson ◽  
L.O. Werme
Keyword(s):  
Nuclear Fuel ◽  
Nuclear Waste ◽  
Nuclear Power ◽  
Spent Nuclear Fuel ◽  
Fission Products ◽  
Waste Form ◽  
Dissolution Behavior ◽  
Spent Fuel ◽  
Power Stations ◽  
Geologic Disposal

The geologic disposal of spent nuclear fuel is currently under consideration in many countries. Most of this fuel is in the form of assemblies of zirconium-alloy-clad rods containing enriched (1–4% 235U) or natural (0.71% 235U) uranium oxide pellets. Approximately 135,000 Mg are presently in temporary storage facilities throughout the world in nations with commercial nuclear power stations.Safe geologic disposal of nuclear waste could be achieved using a combination of a natural barrier (the host rock of the repository) and engineered barriers, which would include a low-solubility waste form, long-lived containers, and clay- and cement-based barriers surrounding the waste containers and sealing the excavations.A requirement in evaluating the safety of disposal of nuclear waste is a knowledge of the kinetics and mechanism of dissolution of the waste form in groundwater and the solubility of the waste form constituents. In the case of spent nuclear fuel, this means developing an understanding of fuel microstructure, its impact on release of contained fission products, and the dissolution behavior of spent fuel and of UO2, the principal constituent of the fuel.

Salt waste treatment from a LiCl-KCl based pyrochemical spent fuel treatment process

2008 ◽  
Vol 96 (4-5) ◽  
Author(s):  
Mike T. Harrison ◽  
Howard E. Simms ◽  
Angela Jackson ◽  
Robert G. Lewin
Keyword(s):  
Alkali Metals ◽  
Treatment Process ◽  
Spent Nuclear Fuel ◽  
Waste Treatment ◽  
Electrochemical Techniques ◽  
Fission Products ◽  
High Level Waste ◽  
Spent Fuel ◽  
High Level ◽  
Salt Waste

Spent nuclear fuel may be treated using molten salt electrochemical techniques to separate fission products and actinide metals. Salt waste arising from the electrorefining process contains alkali metals, alkaline-earth and rare earth fission products, along with residual actinides. The removal of fission product elements has been investigated using zeolite ion exchange and phosphate precipitation, which allow the salt electrolyte to be recycled back into the main electrorefining vessel. Recycling the salt minimizes the volume of high level waste (HLW) generated and yields the fission products in a form more amenable to immobilization in a final disposal matrix. Several sets of experiments have been completed, all of which have significant implications for the use of these techniques on an industrial scale, as well as their ability to clean up the salt, and potentially produce robust and durable waste forms.

scholarly journals Study on CANDLE Burning Fast Reactor with Initial Core Using Plutonium from LWR Spent Fuel

2017 ◽  
Vol 131 ◽  
pp. 15-20 ◽  
Author(s):  
Hiroki Osato ◽  
Jun Nishiyama ◽  
Toru Obara
Keyword(s):  
Fast Reactor ◽  
Spent Fuel

The Effect of Waste Package Components on Radionuclides Released from Spent Fuel Under Hydrothermal Conditions

1987 ◽  
Vol 112 ◽  
Author(s):  
Shirley A. Rawson ◽  
William L. Neal ◽  
James R. Burnell
Keyword(s):  
Low Carbon Steel ◽  
Fission Products ◽  
Nuclear Waste Repository ◽  
Low Carbon ◽  
Spent Fuel ◽  
Hydrothermal Conditions ◽  
Waste Package ◽  
Dissolved Species ◽  
Radionuclide Release ◽  
Time Invariant

AbstractThe Basalt Waste Isolation Project has conducted a series of hydrothermal experiments to characterize waste/barrier/rock interactions as a part of its study of the Columbia River basalts as a potential medium for a nuclear waste repository. Hydrothermal tests of 3–15 months duration were performed with light water reactor spent fuel and simulated groundwater, in combination with candidate container materials (low-carbon steel or copper) and/or basalt, in order to evaluate the effect of waste package materials on spent fuel radionuclide release behavior. Solutions were filtered through 400 and 1.8 nm filters to distinguish colloidal from dissolved species. In all experiments, 14C, 129I, and 137Cs occurred only as dissolved species, whereas the actinides occurred in 400 nm filtrates primarily as spent fuel particles. Actinide concentrations in 1.8 nm filtrates were below detection in steel-bearing experiments. In the system spent fuel + copper, apparent time-invariant concentrations of 14C and 137Cs were obtained, but in the spent fuel + steel system, the concentrations of 14C and 137Cs increased gradually throughout the experiments. In experiments containing basalt or steel + basalt, 137Cs concentrations decreased with time. In tests with copper + basalt, 14C and 129I concentrations attained time-invariant values and 137Cs concentrations decreased. Concentrations for the actinides and fission products measured in these experiments were below those calculated from Federal regulations governing radionuclide release.

scholarly journals RADIONUCLIDE CHARACTERISTICS OF RDE SPENT FUELS

2018 ◽  
Vol 20 (2) ◽  
pp. 69 ◽  
Author(s):  
Ihda Husnayani ◽  
Pande Made Udiyani
Keyword(s):  
Thermal Power ◽  
Neutron Production ◽  
Cooling Time ◽  
Spent Fuel ◽  
Release Rates ◽  
Radiation Dose Rate ◽  
The Core ◽  
Spent Fuel Storage ◽  
Fuel Storage

Reaktor Daya Eksperimental (RDE) is a 10 MWth pebble-bed High Temperature Gas-cooled Reactor that is planned to be constructed by National Nuclear Energy Agency of Indonesia (BATAN) in Puspiptek complex, Tangerang Selatan. RDE utilizes low enriched UO2 fuel coated by TRISO layers and loaded into the core by means of multipass loading scheme. Determination of radionuclide characteristics of RDE spent fuel; such as activity, thermal power, neutron and photon release rates; are very important because those characteristics are crucial to be used as a base for evaluating the safety of spent fuel handling system and storage tank. This study is aimed to investigate the radionuclide characteristics of RDE spent fuel at the end of cycle and during the first 5 years cooling time in spent fuel storage. The method used to investigate the radionuclide characteristics is burnup calculation using ORIGEN2.1 code. In performing the ORIGEN2.1 calculation, one pebble fuel was assumed to be irradiated in the core for 5 cycles and then decayed for 5 years. At the end of the fifth cycle, it is obtained that the total activity, thermal power, neutron production, and photon release rates from all radionuclides inside one spent fuel are approximately 105.68 curies, 0.41 watts, 2.65 x 103 neutrons/second, and 1.79 x 104 photons/second, respectively. The results for the radionuclides characteristics during the first 5 years cooling time in the spent fuel storage show that the radioactivity characteristics from all radionuclides are rapidly decreasing at the first year and then slowly decreasing at the second until the fifth year of cooling time. The results obtained in this study can provide data for safety evaluation of fuel handling and spent fuel storage, such as the calculation of sourceterm, radiation dose rate, and the determination of radiation shielding.Keywords: RDE, spent fuel, radionuclide activity, thermal power, neutron production, photon releaserates KARAKTERISTIK RADIONUKLIDA DI DALAM BAHAN BAKAR RDE. Reaktor Daya Eksperimental (RDE) adalah reaktor tipe Reaktor Temperatur Tinggi Berpendingin Gas dengan daya termal 10MW yang akan dibangun oleh BadanTenagaNuklirNasional (BATAN) di kawasanPuspiptek, Tangerang Selatan. RDE menggunakan bahan bakar UO2 yang dilapisi dengan lapisan TRISO dan dimasukkan ke dalam teras RDE menurut skema multipass (5 siklus). Penentuan karakteristik radionuklida di dalam bahan bakar RDE; seperti aktivitas, daya termal, laju produksi neutron dan pelepasan foton; adalah sangat penting karena informasi karakteristik ini diperlukan sebagai dasar untuk melakukan evaluasi keselamatan system penanganan dan penyimpanan bahan bakar bekas. Penelitian ini bertujuan untuk menganalisis karakteristik radionuklida bahanbakar RDE setelah 5 siklus dan pada 5 tahun pertama pendinginan ditempat penyimpanan bahan bakar bekas. Metode yang digunakan dalam menghitung karakteristik radionuklida adalah menggunakan program ORIGEN2.1. Satu bola bahan bakar RDE diasumsikan diiradiasi selama 5 siklus dan kemudian meluruh selama 5 tahun. Pada akhir siklus, diperoleh hasil aktivitas total, daya termal, laju produksi neutron dan pelepasan foton dari seluruh radionuklida di dalam satu bola bahan bakar RDE sebesar 105,68 curies, 0,41 watts, 2,65 x 103 neutron/detik, dan 1,79 x 104 foton/detik. Hasil untuk karakteristik radionuklida selama 5 tahun penyimpanan menunjukkan bahwa karakteristik radioktivitas radionuklida menurun dengan cepat pada tahun pertama dan kemudian menurun lebih lambat pada tahun kedua hingga tahun kelima. Hasil perhitungan karakteristik radionuklida dari penelitian ini dapat digunakan sebagai basis untuk analisis keselamatan penanganan dan penyimpanan bahan bakarbekas RDE.Kata kunci:RDE, bahan bakar bekas, aktivitas radionuklida, daya termal, produksi neutron, laju foton

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