Second Harmonic Generation of Bacteriorhodopsin and its Application for Three-Dimensional Optical Memory

1993 ◽  
Vol 330 ◽  
Author(s):  
Zhongping Chen ◽  
A. Lewis ◽  
J. Kumart ◽  
S. Tripathy ◽  
K. Marxt ◽  
...  

ABSTRACTA novel three-dimensional optical memory system based on a light transducing protein, bacteriorhodopsin, is investigated. The system uses the nonlinear optical properties of bacteriorhodopsin to accomplish reading and writing operations. A nondestructive method of reading information in three-dimensional optical memory that uses second harmonic generation is demonstrated. This method has the advantage of fast speed, is nondestructive, and has the potential for parallel access.

2016 ◽  
Vol 45 (18) ◽  
pp. 7627-7633 ◽  
Author(s):  
Molin Zhou ◽  
Chao Li ◽  
Xiaoshuang Li ◽  
Jiyong Yao ◽  
Yicheng Wu

New selenides K2Sn2ZnSe6, Na2Ge2ZnSe6, and Na2In2GeSe6 exhibit diverse structures and Na2In2GeSe6 possesses a moderate second harmonic generation response.


Crystals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 381
Author(s):  
Qiaoling Chen ◽  
Min Luo ◽  
Chensheng Lin

A new nonlinear optical crystals fluoride carbonate, Na4Yb(CO3)3F, has been synthesized by mild hydrothermal method. The Na4Yb(CO3)3F crystallizes in the noncentrosymmetric space group Cc (no. 9) with the lattice parameters a = 8.018(3), b = 15.929(5), c = 13.950(5) Å and β = 101.425(6)°. The compound Na4Yb(CO3)3F has a high density of [CO3] groups. The structure can be described as one-dimensional [Na5Yb(CO3)2F2] chains connected by [CO3] groups, forming an intricate three-dimensional (3D) framework. Other Na+ and Yb3+ cations are located in the cavities of 3D network. The powder second harmonic generation (SHG) measurement shows that Na4Yb(CO3)3F features a large SHG response, about 4.3 times that of KH2PO4 (KDP), and is a phase-matchable material. In addition, its UV-Vis-NIR diffuse reflectance spectral data indicate that Na4Yb(CO3)3F has a large optical gap about 4.72 eV, which corresponds to the UV cut-off edge of 263 nm.


The second harmonic generation (SHG) from alternate-layer Langmuir-Blodgett (LB) films of stilbazolium dyes and 4, 4'-dioctadecyl-3, 5, 3', 5'-tetramethyldipyrryl-methene hydrobromide increases as I 2ω(N) = l 2ω(1) N 2 for N ≥ 2 bilayers, but the equivalent monolayer signal ( I 2ω(1) ) is significantly less than the intensity from LB monolayers of the corresponding dye on glass. This is attributed, in part, to the different molecular tilts and, in part, to the position of the anion which influences the charge distribution within the chromophore. For alternate-layer films of E-N-octadecyl-4-[2-(4-dimethylaminophenyl)ethenyl]pyridinium octadecylsulphate (dye I) the second-order susceptibility and chromophore tilt angle are χ (2) zzz = 45 pm V -1 and ϕ = 30° respectively, whereas the methoxy congener, E-N-octadecyl-4-[2-(4-methoxyphenyl)ethenyl]pyridinium octadecylsulphate (dye II), has χ (2) zzz = 11 Pm V -1 and ϕ = 35°. The nonlinear optical properties of such films are dependent upon the compatibility of the dye and spacer.


2011 ◽  
Vol 105 (1) ◽  
pp. 149-162 ◽  
Author(s):  
M. Gentile ◽  
M. Hentschel ◽  
R. Taubert ◽  
H. Guo ◽  
H. Giessen ◽  
...  

2000 ◽  
Vol 33 (2) ◽  
pp. 380-386 ◽  
Author(s):  
H. Hellwig ◽  
S. Rühle ◽  
P. Held ◽  
L. Bohatý

Linear and nonlinear optical properties of the four isomorphic orthorhombic (point groupmm2) potassium rare earth nitrates K2[RE(NO3)5(H2O)2], with RE = La, Ce, Pr or Nd, have been investigated. Refractive indices in a wavelength range from 0.35 to 2.5 µm and the transmission spectra between 0.25 to 3.0 µm were measured. Using the Maker fringe technique, the d_{ijk}^{\rm\, SHG} coefficients of second-harmonic generation for a fundamental of the Nd–YAP laser (λ = 1079.5 nm) were determined for all four compounds. The d_{ijk}^{\rm\, SHG} coefficients of all four substances are about three times larger than those of KDP, as was first published by Ebberset al.[IEEE J. Quantum Electron.(1993),29, 497–507] for K2[La(NO3)5(H2O)2]. These nitrates are promising materials for application to nonlinear optics (e.g.second-harmonic generation of Nd laser radiation). The nonlinear optical properties of these compounds seem to have their origin mainly in the nitrate groups, as indicated by a simple model (summing the molecular hyperpolarizabilities of the NO3group). Neglecting local field effects, the hyperpolarizability of the NO3group was calculated as β222= 2.52 × 10−40 m4 V−1.


2004 ◽  
Vol 13 (03n04) ◽  
pp. 355-358 ◽  
Author(s):  
JUN KAWAMATA ◽  
SHOICHIRO HIRAKAWA ◽  
SEIJI TANI ◽  
YUICHIRO OGATA ◽  
AKIHIKO YAMAGISHI

We have prepared hybrid Langmuir–Blodgett (LB) films consisting of a clay single layer and a non-amphiphilic polar molecule, 2,5-bis(p-dimethylaminocinnamylidene)-cyclopentanone. LB films deposited on solid substrates were characterized by means of UV-vis absorption spectroscopy and optical second-harmonic generation (SHG) measurements.


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