Thermodynamic Predictions of Phase Stability and Crystallization Temperature of Silicon-Based Amorphous Alloys

1993 ◽  
Vol 297 ◽  
Author(s):  
J.R.A. Carlsson ◽  
X.H. Li ◽  
S.F. Gong ◽  
H.T.G. Hentzell

A thermodynamic calculation of Si-X alloys has been carried out, where X is any element from group III or V. Free-energy diagrams for those systems have been established. A comparison between thermodynamic predictions and experimental results is carried out for the Si-B and the Si-Sb alloys. It is found that the agreement between theory and experimental results for the free- energy diagrams and for the crystallization temperature predictions are good. The model and the different features for the various elements are described in detail.

1997 ◽  
Vol 36 (10) ◽  
pp. 109-115 ◽  
Author(s):  
Choon-Yee Hoh ◽  
Ralf Cord-Ruwisch

For modeling of biological processes that operate close to the dynamic equilibrium (eg. anaerobic processes), it is critical to prevent the prediction of positive reaction rates when the reaction has already reached dynamic equilibrium. Traditional Michaelis-Menten based models were found to violate the laws of thermodynamics as they predicted positive reaction rates for reactions that were endergonic due to high endproduct concentrations. The inclusion of empirical “product inhibition factors” as suggested by previous work could not prevent this problem. This paper compares the predictions of the Michaelis-Menten Model (with and without product inhibition factors) and the Equilibrium Based Model (which has a thermodynamic term introduced into its rate equation) with experimental results of reactions in anaerobic bacterial environments. In contrast to the Michaelis-Menten based models that used traditional inhibition factors, the Equilibrium Based Model correctly predicted the nature and the degree of inhibition due to endproduct accumulation. Moreover, this model also correctly predicted when reaction rates must be zero due to the free energy change of the conversion reaction being zero. With these added advantages, the Equilibrium Based Model thus seemed to provide a scientifically correct and more realistic basis for a variety of models that describe anaerobic biosystems.


1979 ◽  
Vol 46 (4) ◽  
pp. 944-945 ◽  
Author(s):  
M. Shahinpoor ◽  
G. Ahmadi

We employ the continuum theory of granular materials due to Goodman and Cowin and some experimental results due to P. G. Nutting to arrive at a functional from for the free energy of granular materials in static equilibrium. The results obtained indicate the dominance of gravitational effect, modify and enlarge the results previously obtained by J. T. Jenkins.


1999 ◽  
Vol 4 (1) ◽  
Author(s):  
SHEILA CANEVESE RAHAL ◽  
MANOEL ÁLVARO GUIMARÃES ◽  
JOSÉ VICENTE FORTES ◽  
HÉLIO LANGONI ◽  
PEDRO HELIO LUCCHIARI

"Linhas de pesca"* em diâmetros de 0,15mm; 0,20mm; 0,25mm; 0,30mm foram divididas em quatro grupos, contendo dez amostras de cada diâmetro: grupo I - controle; grupo II - linhas colocadas em frasco com pastilhas de formalina; grupo III - um ciclo de autoclavagem (30 minutos à 121 C, seguido por 10 minutos de secagem à 37 C em estufa); grupo IV - dois ciclos de autoclavagens. Foram avaliadas quanto: comprimento, calibre, resistência no nó e alongamento. Comparativamente foram examinados fios de náilon cirúrgico nas numerações 0, 1-0, 2-0, 3-0, 4-0 e 5-0 (10 amostras de cada um). Pelos resultados da análise estastística, verificou-se que a esterilização pelo calor úmido exerceu um efeito adverso na resistência da "linha de pesca". Por outro lado não houve diferenças na resistência, calibre e alongamento da "linha de pesca" entre o primeiro e segundo ciclo de autoclavagem. As “linhas” mantidas em pastilhas de formalina mantiveram na sua maioria suas características originais de resistência, comprimento, diâmetro e alongamento quando comparada ao grupo controle, entretanto, cabe lembrar que o formaldeído é considerado irritante para pele e membrana mucosa. Foi possível concluir que a "linha de pesca" apresenta características semelhantes ao fio cirúrgico, podendo ser mantida em pastilhas de formalina ou esterilizada em autoclave, lembrando que a autoclavagem altera algumas de suas propriedades físicas. Abstract A comparative study has been carried out between fishing lines and nylon thread in regard to their applicability as surgical thread. Four groups of 10 fishing lines in each of the following diameters = 0.15, 0.20, 0.25 and 0.30 mm = were subjected to the following treatments: group I, control; group II sterilized with formalin tablets; group III, autoclaved 30 minutes at 121oC; group IV, autoclaved twice 30 minutes at 121oC. The following parameters were then considered: length, caliber, resistance at the knot, and elongation. Ten samples of each surgical 0, 1.0, 2.0, 3.0, 4.0 and 5.0 nylon threads were used in comparatively similar experiments as the ones carried out with the fishing lines. According to the statistical analyses of the experimental results, it has been found that the sterilization by means of the humid heat exerts an adverse effect on the resistance of the fishing line. However, no differences were found between the effect displayed by two cycles sterilization compared with the fishing lines subjected to only one cycle. The threads maintained in formalin kept the majority of their original properties of resistance, length, diameter and elongation when compared with the control group. It is known, however that formaldehyde is an irritant chemical towards the skin and the mucous membranes. It was possible to conclude: a. fishing lines display characteristics similar to that ones of the nylon surgical thread; b. they can be maintained in formalin solution; c. autoclave sterilization alters some of their physical properties.


2019 ◽  
Vol 11 (10) ◽  
pp. 1179 ◽  
Author(s):  
Wei Ma ◽  
Qingquan Li

Automatic ground filtering is an essential step for Digital Elevation Model (DEM) generation, which has significant application value. However, extraction and classification of ground points from the Light Detection and Ranging (LiDAR) data, especially in multitudinous terrain situations, is a challenging task because it is difficult to determine the set of optimal parameters for removing various non-ground features. In this paper, a new ground filtering technique based on an improved Ball Pivot Algorithm (BPA) is proposed. At the beginning, the LiDAR point cloud dataset was divided into different subsets based on the 2D regular grid. The lowest point in each grid was selected as the seed point to build a single-layer surface. After that, the improved BPA was executed to remove points on the higher location. Then, the rest of the points were calculated and selected as a new seed point according to the spatial relationship with the initial surface. Finally, non-ground points were filtered by means of improved BPA traversing all the grids. Our experimental results on the Benchmark dataset provided by the International Society for Photogrammetry and Remote Sensing (ISPRS) Working Group III/3 showed high accuracy (with a mean kappa coefficient over 80%) in terms of completeness, correctness, and quality for DEM generation. The experimental results demonstrated the proposed method is robust to various terrain situations, as it is more effective and feasible for ground filtering.


2003 ◽  
Vol 782 ◽  
Author(s):  
Shirley C. Tsai ◽  
Yu L. Song ◽  
Yuan F. Chou ◽  
Terry K. Tseng ◽  
W. J. Chen ◽  
...  

ABSTARCTThis paper presents the experimental results of impedance analysis and longitudinal vibration measurement of micro-fabricated 0.5 MHz silicon-based ultrasonic nozzles. Each nozzle is made of a piezoelectric drive section and a silicon-resonator consisting of multiple Fourier horns each with half wavelength design and twice amplitude magnification. The experimental results verified the simulation prediction of one pure longitudinal vibration mode at the resonant frequency in excellent agreement with the design value. Furthermore, at the resonant frequency, the measured longitudinal vibration amplitude gain at the nozzle tip increases as the number of Fourier horns (n) increases in good agreement with the theoretical value of 2n. Using this design, very high vibration amplitude at the nozzle tip can be achieved with no reduction in the tip cross sectional area. Therefore, the required electric drive power should be drastically reduced, decreasing the likelihood of transducer failure in ultrasonic atomization.


1987 ◽  
Vol 36 (4) ◽  
pp. 483
Author(s):  
CHE GUANG-CAN ◽  
SHEN BAO-GEN ◽  
ZHAO JIAN-GAO ◽  
ZHAN WEN-SHAN ◽  
LIANG JING-KUI

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