Cement Viscosity As A Function Of Concentration

1992 ◽  
Vol 289 ◽  
Author(s):  
Leslie J. Struble ◽  
Guo-Kuang Sun

AbstractThe Krieger-Dougherty equation allows calculation of viscosity as a function of volume fraction for suspensions of noninteracting particles. For model suspensions (of spherical, monosized particles), it has been shown to provide excellent agreement between calculated and measured viscosities. In the present study, this equation was applied to portland cement pastes, also with good correlations between calculated and measured viscosities. Because cement has a broad particle size distribution and its particles are angular and elongated, the two constants in this equation (the maximum volume fraction and the intrinsic viscosity) were estimated using nonlinear optimization techniques. The equation provides an excellent fit to measured viscosity data. However, the nature of the equation makes the estimation somewhat difficult, and the solutions are not well-defined.

2013 ◽  
Vol 58 (4) ◽  
pp. 1323-1326 ◽  
Author(s):  
A. Idźkowska ◽  
M. Szafran

Abstract In present work the influence of particle size distribution on the dilatant effect of shear thickening fluid was investigated. As a ceramic powder a mixture of silicas 200 and 7 nm in ratio 95:5, 90:10, 85:15, 80:20, 75:25, 50:50 was used. A dispersing agent was poly (propylene glycol) of a molecular weight of 425 g/mol. The as prepared slurries were examined on a rotational rheometer Kinexus Pro with a plate-plate measuring system at room temperature, where the viscosity as a function of shear rate was investigated. The measurement showed that by partially replacing greater particle size by smaller one, it is possible to shift the onset of shear thickening to the higher value of shear rate, however, the decreases of dilatant effect is observed. The influence of particle size distribution on a maximum volume fraction also was investigated. The maximum volume fraction which was passible to obtain was 35 vol%.


2015 ◽  
Vol 824 ◽  
pp. 71-76
Author(s):  
Markéta Kočová ◽  
Jaroslav Pokorný ◽  
Milena Pavlíková ◽  
Zbyšek Pavlík

Physical and mechanical behaviour of cement pastes with partial Portland cement replacement by fine milled waste glass is researched in the presented paper. The tested pastes contain milled borosilicate glass in amount of 5, 10, 20, and 30 mass% of cement. The chemical composition of borosilicate glass and used Portland cement is accessed by XRF (X-Ray Fluorescence) analysis. For the milled glass, pozzolanic activity and particle size distribution are measured. Here, modified Chapelle test is used for evaluation of pozzolanic activity. Particle size distribution is measured on laser diffraction principle. Basic physical properties and mechanical properties are determined for samples cured 28 and 90 days in water in order to evaluate the kinetics of hydration process. The obtained results revealed the possible applicability of the tested borosilicate glass in the composition of cement-based composite materials.


2014 ◽  
Vol 1000 ◽  
pp. 39-42
Author(s):  
Martin Boháč ◽  
Tomáš Opravil ◽  
Eva Bartoníčková ◽  
Františka Frajkorová ◽  
Martin Palou

Viscoelastic properties of Portland cement-metakaolin fresh pastes were measured using rotational rheometer. In mixtures 10 % of Portland cement was replaced by various fractions of metakaolin with different particle size distribution. The role of the fineness of metakaolin was revealed characterizing flow, adhesion and creep of the fresh pastes.


2005 ◽  
Vol 105 ◽  
pp. 133-138 ◽  
Author(s):  
Pierre Barbéris ◽  
Frank Montheillet ◽  
Cédric Chauvy

The elastic energy of a set of the twelve variants generated during the b ® a transformation of zirconium, with volume fractions fi, i=1..12, is derived with simplifying assumptions and the conditions on the fi to reach the energy minimum are established analytically. The minimum number of variants needed to reach this minimum is shown to be 6, and in this case, the variants have very specific volume fractions. Another result is that the maximum volume fraction of any variant is 1/3.


2012 ◽  
Vol 16 (5) ◽  
pp. 1391-1394 ◽  
Author(s):  
Kun Zhou

A new Monte Carlo method termed Comb-like frame Monte Carlo is developed to simulate the soot dynamics. Detailed stochastic error analysis is provided. Comb-like frame Monte Carlo is coupled with the gas phase solver Chemkin II to simulate soot formation in a 1-D premixed burner stabilized flame. The simulated soot number density, volume fraction, and particle size distribution all agree well with the measurement available in literature. The origin of the bimodal distribution of particle size distribution is revealed with quantitative proof.


2016 ◽  
Vol 848 ◽  
pp. 593-606 ◽  
Author(s):  
Jiang Li Ning ◽  
Yun Li Feng ◽  
Jie Li

The Hall-Petch relation in a spheroidized steel with bimodal cementite particle size distribution has been investigated in this study, with an emphasis on considering the effect of the large particles at ferrite grain boundaries and triple junctions. A medium carbon steel was processed by variable thermomechanical procedures to achieve spheroidized structures with different combinations of microstructrual parameters, but all exhibiting a bimodal particle size distribution, in which large intergranular particles and small intragranular particles coexisted in the ferrite matrix. A quantitative relationship between the Hall-Petch parameter ky and the volume fraction of the intergranular cementite particles is presented, by considering a composite model. The contribution of the large intergranular particles to grain boundary strengthening wa substantiated by the increment of the ky parameter, since the average orientation factor of the composite, is increased. After correction of the ky parameters based on the constants from literatures, the predicted stresses show good agreement with the experimental stresses. A linear fit between the experimental stresses and the reciprocal square root of grain sizes is performed, the slope constant ky derived agrees to within 11 % of the corrected ky parameters based on the constants from literatures.


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