Preparation of Quantum-Size Semiconductor-Doped Ormosils and their Optical Properties

1992 ◽  
Vol 272 ◽  
Author(s):  
Chia-Yen Li ◽  
Matthew Wilson ◽  
Nancy Haegel ◽  
John. D. Mackenzie ◽  
Edward T. Knobbe ◽  
...  

ABSTRACTAn Organically-modified silicate (Ormosil) which contains 28 wt% polydimethylsiloxane and 72 wt% silica has been used as a matrix to fabricate CdS-doped glassy nanocomposites by using the sol-gel method. Samples were prepared both in bulk and film forms. High semiconductor concentrations, up to 20 wt% CdS could be obtained and the semiconductor microcrystallites were formed at temperatures much lower than that of the purely inorganic glass matrix. Preparation methods of these CdS-doped Ormosils are described. Optical behaviors of these nanocomposites under normal and intense photon influx were studied.

2021 ◽  
pp. 138582
Author(s):  
Qiang Lu ◽  
Zhiqiang Wei ◽  
Xiaojuan Wu ◽  
Shangpan Huang ◽  
Meijie Ding ◽  
...  

2014 ◽  
Vol 23 (4) ◽  
pp. 047805 ◽  
Author(s):  
Meng-Meng Cao ◽  
Xiao-Ru Zhao ◽  
Li-Bing Duan ◽  
Jin-Ru Liu ◽  
Meng-Meng Guan ◽  
...  

2015 ◽  
Vol 645 ◽  
pp. 529-534 ◽  
Author(s):  
Libing Duan ◽  
Xiaoru Zhao ◽  
Yajun Wang ◽  
Hao Shen ◽  
Wangchang Geng ◽  
...  

2011 ◽  
Vol 11 (5) ◽  
pp. 1243-1248 ◽  
Author(s):  
K.J. Chen ◽  
F.Y. Hung ◽  
S.J. Chang ◽  
S.J. Young ◽  
Z.S. Hu

2008 ◽  
Vol 517 (3) ◽  
pp. 1032-1036 ◽  
Author(s):  
Chien-Yie Tsay ◽  
Hua-Chi Cheng ◽  
Yen-Ting Tung ◽  
Wei-Hsing Tuan ◽  
Chung-Kwei Lin

2021 ◽  
Author(s):  
Yanchun Zhang ◽  
Aimin Sun ◽  
Zhaxi Suonan

Abstract Different complexing agents were used to prepare Ni-Mg-Zn ferrite with the composition formula Ni0.2Mg0.2Zn0.6Fe2O4 via sol-gel method, which included citric acid, oxalic acid, egg white and EDTA. The Ni0.2Mg0.2Zn0.6Fe2O4 ferrite with no complexing agent was also prepared as a comparison. The chemical phases of samples were analyzed by the X-ray diffraction (XRD), which indicated that samples had spinel phase structure. The lattice constants of samples are in the range of 8.3980 ~ 8.4089 Å. The composition and structure were further studied by fourier transform infrared spectroscopy (FTIR). There were two typical characteristic bands related to the stretching vibrations of spinel ferrite in FTIR spectra. Scanning electron microscope (SEM) micrographs and transmission electron microscope (TEM) images showed that the particles have the shape of spherical cube. Energy dispersive spectrometer (EDS) analyzed the elements and ingredients of samples, which included Ni, Mg, Zn, Fe and O. X-ray photoelectron spectroscopy (XPS) is used to examine further the elemental composition and chemical state of sample prepared with EDTA as complexing agent. The optical properties of samples were investigated by photoluminescence spectra and UV-Vis spectroscopy. Vibrating sample magnetometer (VSM) was used to characterize magnetic properties, hysteresis loops revealed the ferrimagnetism behavior of prepared samples.


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